Shang S., Du C., Liu Y. et al. · Nature Communications · 2022 · 7599
Open a family to keep every result attached to its sample, method and conditions.
Paraphrased for this database from the authors’ stated interpretations — never quoted verbatim — and kept separate from reported measurements.
In aqueous 3 M KOH, DDA-Cu composite electrodes show double-layer capacitive behaviour with high Cg, high Cs and good cycling stability.
Caveat: Electrode contains carbon black and PTFE, so values are application-composite performance.
10 · Supplementary Fig. 19 text · Supplementary Fig. 19 · Linked to 4 structured results
DDA-Cu is stable over 24 h in several solvents, boiling water and base, but is decomposed/largely loses crystallinity in 1 M HCl.
Caveat: Limited to the tested 24 h soaking conditions.
5 · Supplementary Fig. 9 text · Supplementary Fig. 9 · Linked to 2 structured results
DDA-Cu is a crystalline one-dimensional conductive MOF built from DDA ligands and bimetallic Cu2+ nodes, forming nanoribbon layers.
Caveat: Atomic coordinates are available in SI Table 1, but no local CIF file was supplied.
2 · Results - Synthesis and characterization · Fig. 1 · Linked to 4 structured results
DDA-Cu is a highly conductive n-type MOF based on Hall and Mott-Schottky measurements.
Caveat: Measured on film/device samples rather than free powder.
13 · Supplementary Fig. 22 text · Supplementary Fig. 22; Table 6 · Linked to 4 structured results
The optoelectronic response is attributed to photogenerated carriers rather than light-induced heating.
Caveat: Thermal check is device-level and does not fully quantify intrinsic photocarrier kinetics.
16 · Supplementary Fig. 27 text · Supplementary Fig. 27 · Linked to 3 structured results
High conductivity is attributed to efficient charge transport along DDA-Cu chains and the pi-pi stacking direction.
Caveat: DFT calculations use a perfect-crystal model; authors caution that defects/doping/oxidation may change applicability.
7 · Discussion · Fig. 4e · Linked to 3 structured results
Names and aliases are kept exactly within the paper’s own identity model.
| Material | Composition | Structure context | Source |
|---|---|---|---|
| DDA-Cu | C14H6N2O4Cu2double Cu ions / bimetallic Cu2+ sites · 1,5-diamino-4,8-dihydroxy-9,10-anthraceneedione (DDA) | 1D · Pristine1D DDA-Cu MOF nanoribbon layers with extended pi-d conjugated nanoribbon plane and out-of-plane pi-pi stacking; P2/m cell a=11.8 A, b=7.9 A, c=3.2 A, alpha=beta=90.0 deg, gamma=87.7 deg. | 1-2 · Abstract and Results · Fig. 1 |
Sample form, processing state and composition status define the context for measurements.
| Sample | Form and role | Processing and geometry | Source |
|---|---|---|---|
| DDA-Cu MOF crystals / bulk precipitateresearch_0009__mat__mat_dda_cu | Powder · Target Sample · Pristine Framework | blue-black precipitate dried in vacuum oven at 90 C for 12 h; needle-like crystalsnone · not applicable | 7 · Methods - Synthesis of DDA-Cu MOF crystals |
| DDA-Cu composite electrode on nickel foamresearch_0009__mat__mat_dda_cu | Electrode · Composite Sample · Composite | DDA-Cu crystals/PTFE/conductive carbon black 7:1:2, ground, coated, dried at 90 C for 8 h1 x 1 cm nickel foam · not reported; active material about 4 mg per electrode | 8 · Methods - Electrochemical measurement |
| DDA-Cu MOF filmresearch_0009__mat__mat_dda_cu | Thin Film · Target Sample · Pristine Framework | large-area liquid-liquid interface filmtransferable to sapphire, Si/SiO2 and PET · ~8 nm after 12 h; ~245 nm after 72 h; 25 nm film used for GIWAXS | 4 · Results - Synthesis and characterization · Fig. 3; Supplementary Fig. 12 |
| DDA-Cu film two-terminal device on Si/SiO2research_0009__mat__mat_dda_cu | Thin Film · Target Sample · Pristine Framework | 12 h growth film transferred to SiO2/Si; I-V measured in N2 at room temperatureSiO2/Si, 300 nm SiO2, interdigital Au electrodes · about 8 nm DDA-Cu film; 30 nm Au electrodes; l=50 um, d=1400 um | 8 · Methods - Electronic device · Supplementary Fig. 16 |
| DDA-Cu flexible optoelectronic synapse on PETresearch_0009__mat__mat_dda_cu | Thin Film · Target Sample · Pristine Framework | DDA-Cu film transferred on PET substrate for flexible devicesPET · not separately reported | 8 · Methods - Electronic device · Fig. 5b |
| ideal DDA-Cu crystal modelresearch_0009__mat__mat_dda_cu | Model · Model System · Model | perfect-crystal computational modelnone · not applicable | 7 · Methods - Computation method |