Electrical Transport — Electrochemical deposition and thermoelectric characterisation of a semiconducting 2-D metal-organic framework thin film

4 measurement groups · 11 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Cu3(HHTP)2 pressed pellet · Pellet

Four probes A-D placed on pellet

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Pressed pellet I-V contact behaviour	linear response / good ohmic contact	—	—	Qualitative Qualitative	7 · Thermoelectric measurements of Cu3(HHTP)2 pressed pellets · Figure S6

Cu3(HHTP)2 pressed pellet · Pellet

Ambient conditions; conductivity measured versus 301-316 K; Hall effect carrier concentration

Temperature: 301-316
Atmosphere: ambient
Geometry: pressed pellet
Context: pristine Cu3(HHTP)2 pellet
Measurement source: 8 · Thermoelectric measurements of Cu3(HHTP)2 pressed pellets · Figure 3b; Table S4

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Pressed pellet activation-energy band gap	2.68 eV	2.68 eV	—	Text Exact Reported	8 · Thermoelectric measurements of Cu3(HHTP)2 pressed pellets · Figure S7
Bulk carrier concentration of pressed pellet	2.2 x 10^17 cm-3	2.2e+23 m-3	—	Text Rounded Reported	8 · Thermoelectric measurements of Cu3(HHTP)2 pressed pellets · Table S4
Electrical conductivity of pressed pellet at 301 K	3.80 x 10-3 S cm-1 at 301 K	0.38 S m-1	standard error from three repeat measurements in Fig. 3; numeric uncertainty not reported	Text Exact Reported	8 · Thermoelectric measurements of Cu3(HHTP)2 pressed pellets · Figure 3b; Table S4
Pressed pellet conductivity-temperature trend	conductivity increases upon increasing temperature from 301 to 316 K	—	—	Qualitative Qualitative	8 · Thermoelectric measurements of Cu3(HHTP)2 pressed pellets · Figure 3b

PMMA-transferred Cu3(HHTP)2 thin film · Thin Film

Electrical contacts between PMMA transferred Cu3(HHTP)2 thin films and instrument probes

Geometry: transferred film four-probe contact configuration
Context: PMMA-supported Cu3(HHTP)2 film
Measurement source: 14 · Thermoelectric measurements of electrodeposited Cu3(HHTP)2 films · Figure S6

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
PMMA-transferred film I-V behaviour	linear I-V curve indicating Ohmic behaviour	—	—	Qualitative Qualitative	14 · Thermoelectric measurements of electrodeposited Cu3(HHTP)2 films · Figure S6

PMMA-transferred Cu3(HHTP)2 thin film · Thin Film

Conductivity versus temperature; Hall carrier concentration

Temperature: 301-328 approx.
Atmosphere: ambient
Geometry: PMMA-transferred thin film
Context: PMMA-supported Cu3(HHTP)2 film
Measurement source: 16 · Thermoelectric measurements of electrodeposited Cu3(HHTP)2 films · Figure 9b; Table S4

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Thin film activation-energy band gap	2.61 eV	2.61 eV	—	Caption Exact Reported	14 · Figure S7 · Figure S7
Carrier concentration of PMMA-transferred film	4.97 x 10^16 cm-3	4.97e+22 m-3	—	Text Exact Reported	16 · Thermoelectric measurements of electrodeposited Cu3(HHTP)2 films · Table S4
Electrical conductivity of PMMA-transferred film at 301 K	2.28 x 10-3 S cm-1 at 301 K	0.228 S m-1	standard error calculated from five repeats in Figure 9; numeric uncertainty not reported	Text Exact Reported	16 · Thermoelectric measurements of electrodeposited Cu3(HHTP)2 films · Figure 9b; Table S4
PMMA-transferred film conductivity-temperature trend	electrical conductivity increases with temperature	—	—	Qualitative Qualitative	16 · Thermoelectric measurements of electrodeposited Cu3(HHTP)2 films · Figure 9b
In-plane thermal conductivity	not determined for films or pellets	—	—	Text Qualitative	15 · Thermoelectric measurements of electrodeposited Cu3(HHTP)2 films