Electrical Transport — Superior Charge Transport in Ni-Diamine Conductive MOFs

6 measurement groups · 14 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Air-exposed Cu3(HITT)2 · Unknown

Cu3(HITT)2 devices exposed to ambient atmosphere for up to 50 days; Figure 5a and S31/S32.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
conductivity after 50 days air exposureMarked as a best value within this paper	7.1 × 10−6 S cm−1	—	—	Text Rounded Reported	20504 · Results and discussion · Figures 5a, S31 and S32
initial conductivity before ageing	2.9 × 10−2 S cm−1	—	—	Text Rounded Reported	20504 · Results and discussion · Figures 5a, S31 and S32
conductivity modulation magnitude	nearly 4 orders of magnitude	—	—	Text Approximate	20504 · Results and discussion · Figures 5a, S31 and S32
late-time conductivity plateau	approximately 10−6 S cm−1	—	—	Text Approximate	20504 · Results and discussion · Figures 5a, S31 and S32

Air-exposed Ni3(HITT)2 control · Unknown

Ni3(HITT)2 air-exposure control for a similar duration to Cu3(HITT)2.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
air-exposed conductivity upper boundMarked as a best value within this paper	4-4.5 S cm−1	—	—	Text Range	20504 · Results and discussion · Figure 5a
air-exposed conductivity lower bound	4-4.5 S cm−1	—	—	Text Range	20504 · Results and discussion · Figure 5a

Pressed pellet four-probe device of pristine Cu3(HITT)2 · Pellet

Pressed polycrystalline pellet; measured at ambient/room temperature in four-contact geometry.

Temperature: 296
Atmosphere: ambient
Geometry: pressed pellet, four-contact probe
Context: pristine
Measurement source: 20503 · Results and discussion · Figures 3 and S29; Table S1

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
room-temperature conductivity average	sigma_average = 0.029 S cm−1	—	—	Text Rounded Reported	20503 · Results and discussion · Figures 3 and S29
room-temperature conductivity maximumMarked as a best value within this paper	0.05 S cm−1	—	—	Text Rounded Reported	20503 · Results and discussion · Figures 3 and S29

Pressed pellet four-probe device of Ni3(HITT)2 · Pellet

Pressed polycrystalline pellet; measured at 298 K in main text / 296 K in SI methods, ambient atmosphere, dark-covered probe station.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
room-temperature conductivity average	sigma_average = 3.45 S cm−1	—	—	Text Rounded Reported	20503 · Results and discussion · Figure S29
room-temperature conductivity maximumMarked as a best value within this paper	up to 4.5 S cm−1 at 298 K	—	—	Text Rounded Reported	20503 · Results and discussion · Figure S29

Pressed pellet four-probe device of pristine Cu3(HITT)2 · Pellet

PPMS DynaCool Electrical Transport Option; two heating/cooling cycles between 300 K and 100 or 200 K at 5 K/min; resistance every 1 K.

Temperature: 200-300
Atmosphere: not specified
Geometry: four-contact probe cell
Context: pristine
Measurement source: 4 · Variable temperature electrical conductivity · Figure 3a

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Arrhenius activation energy, 200-300 KMarked as a best value within this paper	163 meV	—	—	Text Rounded Reported	20503 · Results and discussion · Figure 3a

Pressed pellet four-probe device of Ni3(HITT)2 · Pellet

PPMS DynaCool Electrical Transport Option; two heating/cooling cycles between 300 K and 100 or 200 K at 5 K/min; resistance every 1 K.

Temperature: 100-300
Atmosphere: not specified
Geometry: four-contact probe cell
Context: pristine
Measurement source: 4 · Variable temperature electrical conductivity · Figure 3a

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Arrhenius activation energy, 200-300 K	43 meV	—	—	Text Rounded Reported	20503 · Results and discussion · Figure 3a
Arrhenius activation energy, 100-150 KMarked as a best value within this paper	31 meV	—	—	Text Rounded Reported	20503 · Results and discussion · Figure 3a
Mott VRH dimensionality	d = 3	—	—	Text Exact Reported	20503 · Results and discussion · Figure 3a inset