Electrical Transport — Electrically Conductive 3D Metal-Organic Framework Featuring π-Acidic Hexaazatriphenylene Hexacarbonitrile Ligands with Anion-πInteraction and Efficient Charge-Transport Capabilities

3 measurement groups · 10 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

two-probe current-voltage conductivity

Electrical conductivity

In-situ pressed HATHCN ligand pellet · Pellet

Free HATHCN in-situ pressed pellets measured at 293 K under the same two-probe pressed-pellet method as the MOF.

Temperature: 293
Atmosphere: ambient
Geometry: two-probe pressed pellet
Context: molecular ligand control
Measurement source: S-7 · Figure S11 · Figure S11

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Free HATHCN electrical conductivity	3(1) × 10-10 S/cm	—	(1) × 10-10 S/cm	Text Exact Reported	p007 · Electrical Conductivity · Figure S11
Conductivity contrast versus MOF	million-fold lower electrical conductivity	—	—	Text Approximate	p007 · Electrical Conductivity · Figure S11

two-probe current-voltage conductivity

Electrical conductivity

In-situ pressed [Ag2(HATHCN)(CF3SO3)2]n pellet · Pellet

In-situ pressed pellets measured under ambient conditions at 293 K; two Ag-coated stainless-steel electrodes in Teflon tube; resistance from I-V slope; sigma = L/(R A), A = 0.057 cm2.

Temperature: 293
Atmosphere: ambient
Geometry: two-probe pressed pellet
Context: pristine framework
Measurement source: S-3/S-4 · Electrical Conductivity Measurements · Figure 4a

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Average electrical conductivity	ca. 5(2) × 10-4 S/cm	—	(2) × 10-4 S/cm	Text Approximate	p007 · Electrical Conductivity · Figure 4a
Highest recorded electrical conductivityMarked as a best value within this paper	7.3 × 10-4 S/cm at 293 K	—	—	Text Exact Reported	p007 · Electrical Conductivity · Figure 4a
I-V response	linear current-voltage relationship	—	—	Text Qualitative	p007 · Electrical Conductivity · Figure 4a
Pressed-pellet electrode area	A = 0.057 cm2	—	—	Text Exact Reported	S-4 · Electrical Conductivity Measurements
Material mass per pellet	ca. 2.5 mg	—	—	Text Approximate	S-3 · Electrical Conductivity Measurements
Pellet pressing pressure	200 MPa	—	—	Text Exact Reported	S-3 · Electrical Conductivity Measurements

temperature-dependent two-probe I-V and Arrhenius analysis

Electrical conductivity

In-situ pressed [Ag2(HATHCN)(CF3SO3)2]n pellet · Pellet

Variable-temperature I-V measurements shown for 293 K initial, 303 K, 313 K, 323 K, 333 K, and returned 293 K; Arrhenius plot used to determine activation energy.

Temperature: 293-333
Atmosphere: ambient
Geometry: two-probe pressed pellet
Context: pristine framework
Measurement source: p007/p016 · Electrical Conductivity · Figure 4b and Figure S10

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Thermal activation energy	Ea = 0.2 eV	—	—	Text Exact Reported	p007 · Electrical Conductivity · Figure 4b
Temperatures shown in variable-temperature I-V	293, 303, 313, 323, 333, and returned 293 K	—	—	Figure Axis Exact Reported	S-7 · Figure S10 · Figure S10