cMOF Evidence Base

Synthesis evidence

Electrically Conductive 3D Metal-Organic Framework Featuring π-Acidic Hexaazatriphenylene Hexacarbonitrile Ligands with Anion-πInteraction and Efficient Charge-Transport Capabilities

Yadav A., Panda D.K., Zhang S. et al. · ACS Applied Materials and Interfaces · 2020 · 40613-40619

2 structured synthesis routes

Completeness describes how fully the route could be reconstructed from the main article and supporting information.

Complete recipeSource: Both

Route 1: Other

S-2 · Ligand and MOF Synthesis

Metal precursorsAgOTf (silver triflate), 40.12 mg, 0.16 mmol
Linker precursorsHATHCN, 20 mg, 0.052 mmol
SolventsMeNO2: 2 mL for HATHCN solution and 3 mL for AgOTf solution
AdditivesNone reported
Atmosphereambient / not specified; undisturbed solution at room temperature
Temperatureroom temperature; activation at 100 C
Time48 h reaction; 6 h vacuum activation
Substrate orientationnot applicable
Oxidant / reductantNo external oxidant/reductant; TfO- counteranions participate in partial charge transfer after framework formation.
Work-upOrange crystals precipitated; washed thoroughly with MeNO2.
ActivationDried under vacuum, heated at 100 C under vacuum for 6 h to obtain evacuated bulk material.
Scalability contextSmall-batch crystallisation; isolated yield 18.5 mg, 74%.
Show 3 structured reagent records
RoleReagentAmount / concentrationSource
LinkerHATHCN20 mg; 0.052 mmol · in MeNO2 (2 mL)S-2 · Ligand and MOF Synthesis
Metal SourceAgOTf40.12 mg; 0.16 mmol · in MeNO2 (3 mL)S-2 · Ligand and MOF Synthesis
SolventMeNO25 mL totalS-2 · Ligand and MOF Synthesis
Partial recipeSource: SI

Route 2: Other

S-2 · Ligand and MOF Synthesis

Metal precursorsNone
Linker precursorshexaketocyclohexane; diaminomaleonitrile
SolventsMeCN for slow evaporation crystallisation; reaction solvent not specified in provided SI because synthesis follows literature protocol.
Atmospherenot reported
Temperaturenot reported
Timenot reported
Work-upSXRD-quality crystals obtained by slow evaporation of solvent from MeCN solution.
Activationnot reported
Scalability contextNo scale or yield given for ligand synthesis in this paper; referred to literature protocol S1.
Show 3 structured reagent records
RoleReagentAmount / concentrationSource
LinkerhexaketocyclohexaneNot specifiedS-2 · Ligand and MOF Synthesis
LinkerdiaminomaleonitrileNot specifiedS-2 · Ligand and MOF Synthesis
SolventMeCNslow evaporation solution for crystalsS-2 · Ligand and MOF Synthesis