Measurement evidence
Electrically Conductive 3D Metal-Organic Framework Featuring π-Acidic Hexaazatriphenylene Hexacarbonitrile Ligands with Anion-πInteraction and Efficient Charge-Transport Capabilities · Yadav A., Panda D.K., Zhang S. et al. · ACS Applied Materials and Interfaces · 2020 · 40613-40619
Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.
AgOTf cyclic-voltammetry control · Unknown
AgOTf control measured to identify Ag+ reduction response in the same CV context.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| AgOTf CV response | only a cathodic peak corresponding to Ag+ reduction | — | — | Text Qualitative | p005 · Redox and Optical Properties · Figure S9 |
[Ag2(HATHCN)(CF3SO3)2]n paste on glassy carbon electrode · Electrode
MOF/MeNO2 paste on glassy carbon working electrode; Ag/AgCl reference, Pt-mesh counter electrode, 0.1 M Bu4NPF6 in MeNO2.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| MOF cathodic Ag+ reduction peak | +0.53 V vs Ag/AgCl | — | — | Text Exact Reported | p005 · Redox and Optical Properties · Figure S9 |
| MOF HATHCN radical-anion process potential | ca. -0.19 V vs Ag/AgCl | — | — | Text Approximate | p005 · Redox and Optical Properties · Figure S9 |
Free HATHCN ligand powder/crystals · Powder
Free HATHCN control measured in the same CV context: glassy carbon working electrode, Ag/AgCl reference, Pt-mesh counter electrode, 0.1 M Bu4NPF6 in MeNO2.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| Free HATHCN reversible reduction potential | -0.17 V vs Ag/AgCl | — | — | Text Exact Reported | p005 · Redox and Optical Properties · Figure S9 |