Porosity — Electrically Conductive 3D Metal-Organic Framework Featuring π-Acidic Hexaazatriphenylene Hexacarbonitrile Ligands with Anion-πInteraction and Efficient Charge-Transport Capabilities

Measurement evidence

Porosity

Electrically Conductive 3D Metal-Organic Framework Featuring π-Acidic Hexaazatriphenylene Hexacarbonitrile Ligands with Anion-πInteraction and Efficient Charge-Transport Capabilities · Yadav A., Panda D.K., Zhang S. et al. · ACS Applied Materials and Interfaces · 2020 · 40613-40619

2 measurement groups · 6 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

N2 sorption / BET

Gas sorption and porosity

Evacuated [Ag2(HATHCN)(CF3SO3)2]n bulk material · Powder

Activated MOF heated at 100 C under vacuum for 6 h; N2 sorption isotherms measured at 77 K on Quantachrome Autosorb iQ.

Temperature: 77
Atmosphere: N2
Geometry: powder
Context: pristine framework
Measurement source: S-2 · General Materials and Methods · Figure S7

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
BET surface area	11.42 m2/g	—	—	Text Exact Reported	p005 · Thermogravimetric and Porosity Analyses · Figure S7
Pore volume	1.47 × 10-2 cm3/g	—	—	Text Exact Reported	p005 · Thermogravimetric and Porosity Analyses · Figure S7
Solvent-accessible volume	18%	—	—	Text Exact Reported	p005 · Thermogravimetric and Porosity Analyses · Figure S8
PLATON/SQUEEZE void electron count	1054 electrons per unit corresponding to 16 MeNO2 molecules per unit	—	—	Text Exact Reported	p005 · Thermogravimetric and Porosity Analyses

thermogravimetric analysis

Thermogravimetric analysis

Evacuated [Ag2(HATHCN)(CF3SO3)2]n bulk material · Powder

TGA under N2 atmosphere using SDT Q600; pristine MOF thermal/solvent-loss profile.

Atmosphere: N2
Geometry: powder
Context: pristine framework
Measurement source: S-2 · General Materials and Methods · Figure S6

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Thermal plateau upper temperature	stable plateau until 300 C	—	—	Text Rounded Reported	p005 · Thermogravimetric and Porosity Analyses · Figure S6
Initial solvent-loss weight loss	ca. 10% weight at 120 C	—	—	Text Approximate	p005 · Thermogravimetric and Porosity Analyses · Figure S6