Wu A.-Q., Wang W.-Q., Zhan H.-B. et al. · Nano Research · 2021 · 438-443
Open a family to keep every result attached to its sample, method and conditions.
Paraphrased for this database from the authors’ stated interpretations — never quoted verbatim — and kept separate from reported measurements.
HITP doping modulates chemiresistive sensitivity and selectivity, reversing relative sensitivity toward NH3 and benzene and giving over 220% benzene/NH3 selectivity improvement.
Caveat: Detailed gas-sensor operating conditions come from SI, not the main text.
p003 / article p.440 · Results and discussion · Fig. 3(d) · Linked to 3 structured results
The exact mechanism for the sensing performance of Cu-HHTP/HITP and related EC-MOFs remains difficult to reveal.
p004 / article p.441 · Results and discussion
HITP was successfully doped into the Cu-HHTP thin-film framework, and the HITP/HHTP ratio increased with mixed-ligand feed ratio.
Caveat: Quantitative fitted composition ratios are not reported.
p002 / article p.439 · Results and discussion · Fig. 2(d,e); Fig. S7 · Linked to 5 structured results
The spray LbL process gives pinhole-free, dense, continuous HITP-doped Cu-HHTP nanofilms with controlled nanometre-scale thickness.
Caveat: Roughness values beyond the reported upper bound were visually estimated from figure axes.
p002 / article p.439 · Results and discussion · Fig. 2(a,b); Figs. S1-S6 · Linked to 5 structured results
Rich defects in films with 1.0-10.0 mol% HITP may favour charge transfer with benzene and TEA, explaining strong selectivity improvements.
Caveat: The authors explicitly state that the exact sensing mechanism is difficult to reveal.
p004 / article p.441 · Results and discussion · Figs. 3(f), 4 · Linked to 4 structured results
Low-level HITP doping increases sigma/C0 by about two orders of magnitude, attributed to conductive Cu-o-phenylenediamine coordination linkages, while higher dopant fractions give less additional gain because film quality declines.
Caveat: Only sigma/C0 (I/d) is reported for the films, not an absolute conductivity in S cm-1.
p002 / article p.439 · Results and discussion · Fig. 2(c) · Linked to 4 structured results
Names and aliases are kept exactly within the paper’s own identity model.
| Material | Composition | Structure context | Source |
|---|---|---|---|
| Cu-HHTP / Cu3(HHTP)2Browse family: Cu₃(HHTP)₂ / Cu–HHTP | Cu3(HHTP)2Cu ions / Cu-ligand sheets · 2,3,6,7,10,11-hexahydroxytriphenylene or hexahydrotriphenylene as printed (HHTP, -OH) | 2D · PristineHoneycomb-like porous framework with 2D hexagonal Cu-ligand layers in the ab plane, slipped-parallel AB stacking along c, and 1D channels. | p002 / article p.439 · Results and discussion · Fig. 1 |
| Cu-HITP / Cu3(HITP)2Browse family: Cu₃(HITP)₂ / Cu–HITP | Cu3(HITP)2Cu ions / Cu-ligand sheets · 2,3,6,7,10,11-hexaiminotriphenylene or hexaiminotriphenylene as printed (HITP, -NH2) | 2D · PristineIsostructural pristine framework to Cu3(HHTP)2 with honeycomb-like porous 2D layers. | p001-p002 / article pp.438-439 · Introduction; Results and discussion · Fig. 1 |
| HITP-doped Cu-HHTP-10C | HITP-doped Cu3(HHTP)2 / Cu-HHTP-HITPCu ions · Mixed HHTP and HITP ligands | 2D · PristineHexagonal dual-ligand electronically conductive MOF nanofilm made by 10-cycle spray layer-by-layer liquid-phase epitaxy; HITP is incorporated as a dopant in the Cu-HHTP framework. | p001 / article p.438 · Introduction · Fig. 1 |
Sample form, processing state and composition status define the context for measurements.
| Sample | Form and role | Processing and geometry | Source |
|---|---|---|---|
| pristine Cu3(HHTP)2-10C thin filmresearch_0084__mat__mat_cu_hhtp | Thin Film · Pristine Control · Pristine Framework | Spray LbL 10-cycle thin-film control; standalone pristine recipe not separately detailed in SI.OH-functionalised substrates; used as a comparator to HITP-doped films · about 18-20 nm from Fig. 2(b) visual read | p002 / article p.439 · Results and discussion · Fig. 2(b) |
| pristine Cu-HHTP literature pellet comparatorresearch_0084__mat__mat_cu_hhtp | Pellet · Pristine Control · Pristine Framework | Literature comparator; not prepared in this article. | p003 / article p.440 · Results and discussion |
| pristine Cu-HITP literature pellet comparatorresearch_0084__mat__mat_cu_hitp | Pellet · Pristine Control · Pristine Framework | Literature comparator; not prepared in this article. | p003 / article p.440 · Results and discussion |
| 0.1 mol% HITP doped Cu-HHTP-10Cresearch_0084__mat__mat_hitp_doped_cu_hhtp | Thin Film · Target Sample · Doped | Activated HITP-doped nanofilm after 10 spray LbL cycles.OH-functionalised substrate; sapphire/Au interdigital electrodes for sensing · AFM edge values about 17.8-20.7 nm; mean about 19 nm from Fig. S1 visual read | p002 / SI p.2 · Figure caption · Fig. S1 |
| 0.5 mol% HITP doped Cu-HHTP-10Cresearch_0084__mat__mat_hitp_doped_cu_hhtp | Thin Film · Target Sample · Doped | Activated HITP-doped nanofilm after 10 spray LbL cycles.OH-functionalised substrate; sapphire/Au interdigital electrodes for sensing · AFM edge values about 27.6-29.8 nm; mean about 29 nm from Fig. S2 visual read | p003 / SI p.3 · Figure caption · Fig. S2 |
| 10.0 mol% HITP doped Cu-HHTP-10Cresearch_0084__mat__mat_hitp_doped_cu_hhtp | Thin Film · Target Sample · Doped | Activated HITP-doped nanofilm after 10 spray LbL cycles.OH-functionalised substrate; sapphire/Au interdigital electrodes for sensing · AFM edge values about 65.0-69.8 nm; mean about 67 nm from Fig. S5 visual read | p006 / SI p.6 · Figure caption · Fig. S5 |
| 1.0 mol% HITP doped Cu-HHTP-10Cresearch_0084__mat__mat_hitp_doped_cu_hhtp | Thin Film · Target Sample · Doped | Activated HITP-doped nanofilm after 10 spray LbL cycles.OH-functionalised substrate; sapphire/Au interdigital electrodes for sensing · AFM edge values about 25.0-26.0 nm; mean about 25.5 nm from Fig. S3 visual read | p004 / SI p.4 · Figure caption · Fig. S3 |
| 5.0 mol% HITP doped Cu-HHTP-10Cresearch_0084__mat__mat_hitp_doped_cu_hhtp | Thin Film · Target Sample · Doped | Activated HITP-doped nanofilm after 10 spray LbL cycles.OH-functionalised substrate; sapphire/Au interdigital electrodes for sensing · AFM edge values about 46.1-47.9 nm; mean about 47 nm from Fig. S4 visual read | p005 / SI p.5 · Figure caption · Fig. S4 |
| x mol% HITP doped Cu-HHTP-10C nanofilm seriesresearch_0084__mat__mat_hitp_doped_cu_hhtp | Thin Film · Target Sample · Doped | Spray LbL 10-cycle films activated by successive immersion in DMF for 2 h and ethanol for 12 h at room temperature, then dried by N2.OH-functionalised sapphire, Si/SiO2, quartz, glass, or Au-interdigital-electrode substrates depending on measurement; sapphire/Au electrodes for sensors · 20-70 nm overall; all <80 nm by main-text report | p001 / SI p.1 · Fabrication of HITP doped Cu3(HHTP)2-10C thin film |