Porosity — Macrocyclic ligand-driven ion selectivity and high surface area in a 2D conductive MOF

3 measurement groups · 7 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

pristine Cu-EP powder · Powder

Argon adsorption/desorption isotherms at 77 K; full isotherm BET fitting range 0.05 to 0.30 P/P0; pre-evacuated 30 C 30 min then 60 C 8 h

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
BET surface areaMarked as a best value within this paper	1,502 m2/g	—	—	Text Exact Reported	203 · Structure characterization of Cu-EP · Figure 2D; Table S4
hexagonal channel pore width	around 23.5 A	—	—	Text Approximate	203 · Structure characterization of Cu-EP · Figure 2D
intrinsic pocket pore width	around 6.5 A	—	—	Text Approximate	203 · Structure characterization of Cu-EP · Figure 2D

Cu-EP-Cs-2 · Powder

Measured surface areas of Cs metalated samples; compared with hypothetical values based on pocket occupancy

Temperature: 77
Atmosphere: argon
Context: Cs metalation series
Measurement source: S32 · BET surface areas of metalated samples · Table S10

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
BET surface area of Cu-EP-Cs-0.5Marked as a best value within this paper	1345 +/- 90 m2/g	—	+/- 90 m2/g	SI Table Exact Reported	S32 · BET surface areas of metalated samples · Table S10
BET surface area of Cu-EP-Cs-1Marked as a best value within this paper	1234 +/- 81 m2/g	—	+/- 81 m2/g	SI Table Exact Reported	S32 · BET surface areas of metalated samples · Table S10
BET surface area of Cu-EP-Cs-2Marked as a best value within this paper	1195 +/- 81 m2/g	—	+/- 81 m2/g	SI Table Exact Reported	S32 · BET surface areas of metalated samples · Table S10

Cu-HHTC powder · Powder

Control/literature Cu-HHTC surface area reported in comparison table

Temperature: 77
Atmosphere: argon
Context: Cu-HHTC pristine control
Measurement source: S23 · Comparison in surface areas and conductivity · Table S4

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Cu-HHTC control surface area	1133 m2/g	—	—	SI Table Exact Reported	S23 · Comparison in surface areas and conductivity · Table S4