Diffraction Structure — Asymmetrical Substitution Manipulates Stacking Modes in 2D Conductive MOF Crystals

Measurement evidence

Diffraction Structure

Asymmetrical Substitution Manipulates Stacking Modes in 2D Conductive MOF Crystals · Liu Y., Yao H., Zhang H. et al. · Journal of the American Chemical Society · 2025 · 48127-48135

3 measurement groups · 10 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

PXRD and cRED

Cu3F2HHTP2 blue powder/rod crystals · Powder

Synchrotron PXRD and cRED/SAED used to assign wavy bridged bilayer structure.

Temperature
96
Atmosphere
cryo-transfer TEM for cRED
Context
pristine target
Measurement source
5 · Results and Discussion · Figure 4; Figures S32-S33
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Cu3F2HHTP2 interlayer Cu-O coordination distance2.66 AText
Rounded Reported
5 · Results and Discussion · Figure 4i
Cu3F2HHTP2 interlayer Cu-O coordination distance2.71 AText
Rounded Reported
5 · Results and Discussion · Figure 4i
Cu3F2HHTP2 interlayer Cu-O coordination distance2.72, 2.71, and 2.66 AText
Rounded Reported
5 · Results and Discussion · Figure 4i
Cu3F2HHTP2 bridged-bilayer interlayer spacing3.14 AText
Rounded Reported
5 · Results and Discussion · Figure 4f
Cu3F2HHTP2 adjacent-bilayer interlayer spacing3.15 AText
Rounded Reported
5 · Results and Discussion · Figure 4f
Cu3F2HHTP2 parallel displacement between bridged-bilayer layers1.22 AText
Rounded Reported
5 · Results and Discussion · Figure 4c
Cu3F2HHTP2 one-dimensional hexagonal pore diameter21.6 AText
Rounded Reported
5 · Results and Discussion · Figure 4c

PXRD and cRED

Cu3FHHTP2 blue powder/rod crystals · Powder

Synchrotron PXRD and cRED/SAED used to assign layered structure and stacking.

Temperature
96
Atmosphere
cryo-transfer TEM for cRED
Context
pristine target
Measurement source
5 · Results and Discussion · Figure 4; Figures S30-S31
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Cu3FHHTP2 interlayer distance3.19 AText
Rounded Reported
5 · Results and Discussion · Figure 4e
Cu3FHHTP2 hexagonal pore diameter21.5 AText
Rounded Reported
5 · Results and Discussion · Figure 4b

PXRD Pawley fitting, HRTEM/FFT and structural comparison

Cu3HHTP2 powder/rod crystals · Powder

Experimental PXRD pattern fitted with orthorhombic symmetry; microscopy used for microstructural evidence.

Context
pristine control
Measurement source
55-56 · Figures S40-S41 · Figure S41
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Cu3HHTP2 interlayer distance3.36 AFigure Axis
Rounded Reported
5 · Figure 4 · Figure 4d