cMOF Evidence Base
Diffraction Structure — Hybrid metal-organic chalcogenide nanowires with electrically conductive inorganic core through diamondoid-directed assembly

Measurement evidence

Diffraction Structure

Hybrid metal-organic chalcogenide nanowires with electrically conductive inorganic core through diamondoid-directed assembly · Yan H., Hohman J.N., Li F.H. et al. · Nature Materials · 2017 · 349-355

3 measurement groups · 8 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Single-crystal X-ray diffraction (SC-XRD)

X-ray diffraction and scattering

As-synthesised 1ADCu needle-shaped crystals · Single Crystal

Crystals lifted from solvent, coated with Paratone-N oil, mounted on Kapton loop; data collected at 100 K with synchrotron radiation.

Temperature
100
Context
Pristine bulk crystal.
Measurement source
SI p.3 · Table S1 · Table S1
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
1ADCu b-axis length6.800(3) Angstrom—(3)SI Table
Exact Reported		SI p.3 · Table S1 · Table S1
Average Cu-S bond length in 1ADCu by SC-XRD2.281 +/- 0.014 Angstrom—+/- 0.014SI Table
Exact Reported		SI p.4 · Table S2 · Table S2
1ADCu empirical formulaC30H45Cu3S3——SI Table
Exact Reported		SI p.3 · Table S1 · Table S1
1ADCu space groupP21/c——SI Table
Exact Reported		SI p.3 · Table S1 · Table S1

Powder X-ray diffraction

X-ray diffraction and scattering

Solvent-processed 1ADCu powder · Powder

Calculated single-crystal pattern compared with pristine and solvent-processed powders.

Temperature
room temperature
Geometry
Borosilicate capillary tubes; Debye-Scherrer geometry for powder samples.
Context
Pristine and solvent-processed 1ADCu.
Measurement source
SI p.7 · Supplementary figures · Fig. S2
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
1ADCu lattice retained after IPA solvent processingPXRD of solvent-processed crystals matches pristine/calculated pattern——Caption
Qualitative		SI p.7 · Supplementary figures · Fig. S2

Single-crystal X-ray diffraction (SC-XRD)

X-ray diffraction and scattering

As-synthesised 4DICu crystals · Single Crystal

Crystals mounted as above; data collected at 100 K with synchrotron radiation.

Temperature
100
Context
Pristine bulk crystal.
Measurement source
SI p.3 · Table S1 · Table S1
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
4DICu b-axis length6.500(1) Angstrom—(1)SI Table
Exact Reported		SI p.3 · Table S1 · Table S1
4DICu empirical formulaC28H38Cu2S2——SI Table
Exact Reported		SI p.3 · Table S1 · Table S1
4DICu space groupP21/n——SI Table
Exact Reported		SI p.3 · Table S1 · Table S1