Shit M., Halder S., Dey A. et al. · Inorganic Chemistry · 2023 · 19937-19947
Open a family to keep every result attached to its sample, method and conditions.
Paraphrased for this database from the authors’ stated interpretations — never quoted verbatim — and kept separate from reported measurements.
Compound 1 also shows anticancer activity, with the strongest reported MTT response against MDA-MB-231 cells among the tested cancer cell lines.
Caveat: Biological assay protocols are in the SI and are outside the core conductive-MOF transport focus.
rendered page 5 / article p.19941 · Cytotoxicity Studies · Figure 10 · Linked to 4 structured results
Compound 1 is assigned as a crystalline Zn(II) coordination framework with tdc2- and pcih bridges; local 2D rectangular sheets are extended into a 3D architecture by pcih bridging and supramolecular interactions.
Caveat: SI crystallographic tables were supplied, but the CIF/CCDC data file itself was not local.
rendered pages 2-3 / article pp.19938-19939 · Crystal Structure · Figures 1-2 · Linked to 3 structured results
SCLC analysis indicates higher effective mobility and diffusion length under illumination, supporting improved charge-transfer kinetics in the light phase.
Caveat: The SI supplies the capacitance-frequency plot and equations, but dielectric constant is inconsistent between main-text prose/SI prose and Table 2.
rendered pages 5-6 / article pp.19941-19942 · Optical and Electrical Characterization · Table 2 · Linked to 6 structured results
Compound 1 behaves as a semiconducting MS-junction material whose conductivity and Schottky parameters improve under illumination.
Caveat: SI provides device fabrication details and equations, but the metal top-electrode identity is inconsistent between Al/gold wording.
rendered pages 3-5 / article pp.19939-19941 · Optical and Electrical Characterization · Figure 5; Table 1 · Linked to 7 structured results
Names and aliases are kept exactly within the paper’s own identity model.
| Material | Composition | Structure context | Source |
|---|---|---|---|
| compound 1 / Zn(II) thiophenedicarboxylato-pyridyl isonicotinoyl hydrazone coordination framework | {[Zn2(tdc)2(pcih)2]n}; empirical analysis reported for C18H12N4O5SZnZn(II), distorted octahedral ZnO4N2 coordination units · tdc2- (2,5-thiophene dicarboxylate) and pcih (pyridine-4-carboxaldehyde isonicotinoyl hydrazine) | 3D · PristineSingle-crystal XRD gives monoclinic P21/n; tdc2- forms chelating/bridging Zn-carboxylate 2D rectangular sheets and pcih pyridyl-N bridges adjacent Zn centres to make a 3D molecular architecture; topology described as pcu, 6/4/c1. | rendered pages 1-2 / article pp.19937-19938 · Abstract; Results and Discussion · Figure 1; Scheme 1 |
| DFT model of compound 1 asymmetric unit | model based on single-crystal X-ray coordinates of compound 1Zn(II) · tdc2- and pcih | 0D · Model SystemComputational model uses the optimized asymmetric unit from the single-crystal X-ray diffraction coordinates rather than the full extended experimental framework. | rendered page 3 / article p.19939 · DFT Computational Study · Figure 3 |
Sample form, processing state and composition status define the context for measurements.
| Sample | Form and role | Processing and geometry | Source |
|---|---|---|---|
| optimized asymmetric-unit computational model of compound 1research_0177__mat__mat_zn_tdc_pcih_model | Model · Model System · Model | DFT model from single-crystal coordinates; no synthesis route applies to this model sample. | rendered page 3 / article p.19939 · DFT Computational Study · Figure 3 |
| finely ground/as-synthesised compound 1 powderresearch_0177__mat__mat_zn_tdc_pcih_1 | Powder · Target Sample · Pristine Framework | Finely ground sample used for PXRD, TGA, SEM/EDX and stability checks after pH 7.4 or DMSO exposure. | rendered page 3 / article p.19939 · Results and Discussion · Figures S2-S8 |
| ITO/compound 1/Al metal-semiconductor thin-film deviceresearch_0177__mat__mat_zn_tdc_pcih_1 | Thin Film · Target Sample · Pristine Framework | 18 mg/mL dispersion of compound 1 in DMF spin-coated on ITO-coated glass at 600 rpm for 5 min then 900 rpm for 5 min, vacuum dried at 80 deg C, contacted through a shadow mask; used for optical and electrical characterisation.ITO-coated glass; main text describes Al/compound 1 interface; SI describes ITO/compound 1/Al but also says gold metal electrode · ~1 um considered for dielectric calculation | rendered pages 3-4 / article pp.19939-19940 · Optical and Electrical Characterization · Figures 4-9; Tables 1-2 |
| block-shaped yellow crystals of compound 1research_0177__mat__mat_zn_tdc_pcih_1 | Single Crystal · Target Sample · Pristine Framework | Layering synthesis product; yield 0.201 g, 70%; used for single-crystal XRD and bulk characterisation. | rendered page 2 / article p.19938 · Experimental Section · Scheme 1 |