Electrical Transport — Pyridyl-Isonicotinoyl Hydrazone-Bridged Zn(II) Coordination Framework with Thiophenedicarboxylato Link: Structure, Biological Activity, and Electrical Conductivity

Measurement evidence

Electrical Transport

Pyridyl-Isonicotinoyl Hydrazone-Bridged Zn(II) Coordination Framework with Thiophenedicarboxylato Link: Structure, Biological Activity, and Electrical Conductivity · Shit M., Halder S., Dey A. et al. · Inorganic Chemistry · 2023 · 19937-19947

2 measurement groups · 30 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

current-voltage (I-V) and Schottky-diode analysis under dark and photoillumination

ITO/compound 1/Al metal-semiconductor thin-film device · Thin Film

Room temperature 26 deg C; applied bias within +/-2 V; dark and light illumination with intensity approximately 100 mW cm-2.

Temperature
299
Atmosphere
not reported
Geometry
ITO/compound 1/metal MS junction thin-film device; main text emphasises Al/compound 1 interface, SI states ITO/compound 1/Al but also names gold as metal electrode
Context
pristine framework thin-film MS device
Measurement source
rendered pages 3-5 / article pp.19939-19941 · Optical and Electrical Characterization · Figures 5-9; Table 1
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Schottky barrier height, dark0.61 eVTable
Exact Reported
rendered page 5 / article p.19941 · Table 1 · Table 1
Schottky barrier height, lightMarked as a best value within this paper0.47 eVTable
Exact Reported
rendered page 5 / article p.19941 · Table 1 · Table 1
electrical conductivity, dark2.21 x 10^-5 S cm^-1Table
Exact Reported
rendered page 5 / article p.19941 · Table 1 · Table 1
electrical conductivity, lightMarked as a best value within this paper6.36 x 10^-5 S cm^-1Table
Exact Reported
rendered page 5 / article p.19941 · Table 1 · Table 1
compound 1 dispersion concentration for device fabrication18 mg/mlText
Exact Reported
rendered page 18 / SI p.S18 · Device Fabrication
effective diode area7.065 x 10^-2 cm2Text
Exact Reported
rendered page 19 / SI p.S19 · Electrical Characterization
ideality factor eta, dark2.93Table
Exact Reported
rendered page 5 / article p.19941 · Table 1 · Table 1
ideality factor eta, lightMarked as a best value within this paper2.08Table
Exact Reported
rendered page 5 / article p.19941 · Table 1 · Table 1
low-voltage transport regimeRegion I slope approximately 1; Ohmic ruleText
Approximate
rendered page 4 / article p.19940 · Optical and Electrical Characterization · Figure 8
higher-voltage transport regimeRegion II follows I proportional to V2; trap-free SCLCText
Approximate
rendered page 4 / article p.19940 · Optical and Electrical Characterization · Figure 8
photosensitivityMarked as a best value within this paper4.88Table
Exact Reported
rendered page 5 / article p.19941 · Table 1 · Table 1
rectification ratio Ion/Ioff, dark26.27Table
Exact Reported
rendered page 5 / article p.19941 · Table 1 · Table 1
rectification ratio Ion/Ioff, lightMarked as a best value within this paper80.85Table
Exact Reported
rendered page 5 / article p.19941 · Table 1 · Table 1
series resistance from dV/dlnI, dark801.49 ohmTable
Exact Reported
rendered page 5 / article p.19941 · Table 1 · Table 1
series resistance from dV/dlnI, lightMarked as a best value within this paper456.70 ohmTable
Exact Reported
rendered page 5 / article p.19941 · Table 1 · Table 1
series resistance from H, dark807.18 ohmTable
Exact Reported
rendered page 5 / article p.19941 · Table 1 · Table 1
series resistance from H, lightMarked as a best value within this paper460.82 ohmTable
Exact Reported
rendered page 5 / article p.19941 · Table 1 · Table 1

SCLC/Mott-Gurney charge-transport parameter analysis

ITO/compound 1/Al metal-semiconductor thin-film device · Thin Film

Parameters derived from higher-voltage I vs V2, ln(I) vs ln(V), capacitance-frequency and related analyses; SI equations/data referenced.

Temperature
299
Atmosphere
not reported
Geometry
Al/compound 1 MS junction thin-film device
Context
pristine framework thin-film MS device
Measurement source
rendered pages 4-6 / article pp.19940-19942 · Optical and Electrical Characterization · Figures 8-9; Table 2
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
diffusion coefficient D, dark1.62 x 10^-5Table
Exact Reported
rendered page 6 / article p.19942 · Table 2 · Table 2
diffusion coefficient D, lightMarked as a best value within this paper1.05 x 10^-4Table
Exact Reported
rendered page 6 / article p.19942 · Table 2 · Table 2
relative dielectric constant epsilon_r, Table 2 dark row3.66 x 10^-1Table
Exact Reported
rendered page 6 / article p.19942 · Table 2 · Table 2
relative dielectric constant from prose0.486Text
Exact Reported
rendered page 5 / article p.19941 · Optical and Electrical Characterization · Figure S9
film thickness assumed for dielectric calculation~1 um~Text
Approximate
rendered page 20 / SI p.S20 · Electrical Characterization · Equation S7
diffusion length LD, dark1.27 x 10^-7 mTable
Exact Reported
rendered page 6 / article p.19942 · Table 2 · Table 2
diffusion length LD, lightMarked as a best value within this paper2.06 x 10^-7 mTable
Exact Reported
rendered page 6 / article p.19942 · Table 2 · Table 2
effective mobility, dark6.26 x 10^-4 m2 V^-1 s^-1Table
Exact Reported
rendered page 6 / article p.19942 · Table 2 · Table 2
effective mobility, lightMarked as a best value within this paper4.07 x 10^-3 m2 V^-1 s^-1Table
Exact Reported
rendered page 6 / article p.19942 · Table 2 · Table 2
mobility-transit time product, dark3.14 x 10^-13Table
Exact Reported
rendered page 6 / article p.19942 · Table 2 · Table 2
mobility-transit time product, lightMarked as a best value within this paper8.22 x 10^-13Table
Exact Reported
rendered page 6 / article p.19942 · Table 2 · Table 2
transit time tau, dark5.02 x 10^-10 sTable
Exact Reported
rendered page 6 / article p.19942 · Table 2 · Table 2
transit time tau, lightMarked as a best value within this paper20.2 x 10^-10 sTable
Exact Reported
rendered page 6 / article p.19942 · Table 2 · Table 2