Partial recipeSource: Both
Route 1: Other
rendered page 2 / article p.19938 · Experimental Section - Synthesis · Scheme 1
Metal precursorsZn(NO3)2.6H2O (0.060 g, 0.2 mmol) in water (2 mL)
Linker precursorspcih (0.045 g, 0.2 mmol) in methanol (2 mL); H2tdc (0.035 g, 0.2 mmol) neutralized with Et3N (0.042 g, 0.4 mmol) in EtOH (2 mL)
Solventsmethanol, water, DMF/MeOH buffer (2 mL, 1:1 v/v), ethanol
AdditivesEt3N used to neutralize H2tdc; DMF/MeOH buffer
Atmospherenot reported in main text
Temperatureroom temperature implied for layered crystallisation but not explicitly reported
Time168
Work-upBlock-shaped yellow crystals isolated after 7 days; further washing/drying not reported in main text or SI.
Activationnot reported
Scalability contextSmall-batch layered crystallisation; reported isolated amount 0.201 g and 70% yield.
Show 6 structured reagent records
| Role | Reagent | Amount / concentration | Source |
|---|---|---|---|
| Linker | pyridine-4-carboxaldehyde isonicotinoyl hydrazine (pcih) | 0.045 g, 0.2 mmol · in methanol (2 mL) | rendered page 2 / article p.19938 · Experimental Section - Synthesis · Scheme 1 |
| Metal Source | Zn(NO3)2.6H2O | 0.060 g, 0.2 mmol · in water (2 mL) | rendered page 2 / article p.19938 · Experimental Section - Synthesis · Scheme 1 |
| Solvent | DMF and MeOH buffer | 2 mL, 1:1 v/v | rendered page 2 / article p.19938 · Experimental Section - Synthesis · Scheme 1 |
| Linker | H2tdc / 2,5-thiophene dicarboxylic acid | 0.035 g, 0.2 mmol · in EtOH (2 mL) after neutralisation | rendered page 2 / article p.19938 · Experimental Section - Synthesis · Scheme 1 |
| Base | Et3N | 0.042 g, 0.4 mmol · used to neutralize H2tdc | rendered page 2 / article p.19938 · Experimental Section - Synthesis · Scheme 1 |
| Solvent | EtOH | 2 mL | rendered page 2 / article p.19938 · Experimental Section - Synthesis · Scheme 1 |