Liu J., Zhou W., Liu J. et al. · Angewandte Chemie - International Edition · 2015 · 7441-7445
Open a family to keep every result attached to its sample, method and conditions.
Paraphrased for this database from the authors’ stated interpretations — never quoted verbatim — and kept separate from reported measurements.
FTO-supported free-base and Pd Zn-SURMOF 2 films retain nearly steady 530 nm photocurrent over 1800 s under 0.06 V bias in the reported photoelectrochemical durability tests.
Caveat: Visual estimates from Figures S33-S34; durability was tested once over 1800 s under the reported conditions.
43-44 / p044-p045 · Supplementary Figures · Figures S33-S34 · Linked to 8 structured results
QCM-D shows rapid acetonitrile and I-/I3- uptake and small dissipation changes, supporting electrolyte accessibility and rigidity/stability of the films.
Caveat: No BET or gas sorption porosity data are reported; QCM-D supports liquid permeation/stability rather than absolute pore volume.
29-31 / p030-p032 · Supplementary Figures · Figures S19-S21 · Linked to 6 structured results
The spray LPE process yields highly oriented, well-ordered crystalline porphyrin Zn-SURMOF 2 thin films.
Caveat: Crystallinity for Pd is represented primarily by qualitative XRD orientation captions rather than full indexed peak tables.
7442 / p002 · Main text · Figure 2 · Linked to 3 structured results
IR spectra support formation of zinc paddle-wheel structures with bidentate bridging carboxylate coordination.
Caveat: IR assignment is inferential and based on COO- splitting and loss of free COOH C=O features.
20-21 / p021-p022 · Supplementary Figures · Figures S11-S12 · Linked to 2 structured results
Adding Pd into the porphyrin centre more than doubles the photovoltaic efficiency relative to the free-base Zn-SURMOF 2 device.
Caveat: Device uses liquid electrolyte and no mask; these details are reported in SI.
7443 / p003 · Main text · Figure 3 · Linked to 4 structured results
The wavelength-dependent photocurrents of both free-base and Pd Zn-SURMOF 2/FTO follow the porphyrin chromophore absorption, with a photocurrent action maximum shifted to about 400 nm by solvatochromatic effects.
Caveat: Action-spectrum values are approximate figure-axis readings, and Figure S32 has the already-audited red/blue colour-assignment inconsistency.
40-42 / p041-p043 · Supplementary Figures · Figures S30-S32 · Linked to 3 structured results
FP-TRMC/TAS indicates unusually high photocarrier generation efficiency and appreciable local hole mobility in the porphyrin Zn-SURMOF 2 films.
Caveat: Mobilities are local-scale values inferred by correlated FP-TRMC/TAS kinetics, not direct DC transport mobilities.
7443 / p003 · Main text · Figures S26-S28 · Linked to 4 structured results
The authors link high OPV performance to computed indirect band gaps in ordered porphyrin Zn-SURMOF 2 semiconductors, which suppress recombination after relaxation.
Caveat: The mechanistic link is a proposed interpretation from computation and device behaviour; direct exciton diffusion length calculation is stated to be beyond the work.
7444 / p004 · Main text · Figure 5 · Linked to 4 structured results
Names and aliases are kept exactly within the paper’s own identity model.
| Material | Composition | Structure context | Source |
|---|---|---|---|
| Bare fluorine-doped tin oxide substrate control | F:SnO2 | unknown · UnknownConductive transparent oxide substrate used as bottom electrode and electrochemical control. | 6 / p007 · 1.5 Photoelectrochemical measurements |
| Free-base porphyrin Zn-SURMOF 2 | Not specifiedZn paddle-wheel units from zinc acetate · 5,15-diphenyl-10,20-di(4-carboxyphenyl)porphyrin (free-base porphyrin) | 3D · PristineSURMOF 2 paddle-wheel framework with P4 symmetry, parallel 1-D channels, layers perpendicular to substrates and [001] out-of-plane orientation. | 7442 / p002 · Main text · Figure 2 |
| Free-base carboxyphenyl porphyrin linker control | Not specified[] · ['5,15-diphenyl-10,20-di(4-carboxyphenyl)porphyrin'] | 0D · Model System | 18 / p019; 24 / p025 · Supplementary Figures · Figures S9 and S15 |
| Pd porphyrin linker control | Not specified['Pd(II) metalloporphyrin centre'] · ['Pd(II) 5,15-diphenyl-10,20-di(4-carboxyphenyl)porphyrin'] | 0D · Model System | 19 / p020 · Supplementary Figures · Figure S10 |
| Pd porphyrin Zn-SURMOF 2 | Not specifiedZn paddle-wheel units from zinc acetate; Pd(II) in porphyrin macrocycle · Pd(II) 5,15-diphenyl-10,20-di(4-carboxyphenyl)porphyrin | 3D · PristineSURMOF 2 paddle-wheel framework with P4 symmetry, parallel 1-D channels, layers perpendicular to substrates and [001] out-of-plane orientation. | 13 / p014 · Supplementary Figures · Figure S4 |
| Zn porphyrin Zn-SURMOF 2 computational model | Not specifiedZn paddle-wheel units and Zn metalloporphyrin centres · Zn-metallated porphyrin dicarboxylate linker model | 3D · Model SystemPeriodic SURMOF 2 electronic-structure model. | 7444 / p004 · Main text |
Sample form, processing state and composition status define the context for measurements.
| Sample | Form and role | Processing and geometry | Source |
|---|---|---|---|
| Bare FTO substrateresearch_0200__mat__bare_fto_control | Electrode · Pristine Control · Unknown | Bare FTO used as electrochemical and photocurrent control.FTO glass | 34 / p035 · Supplementary Figures · Figure S24 |
| Free-base porphyrin Zn-SURMOF 2/FTO, 300 nmresearch_0200__mat__fb_zn_surmof2 | Electrode · Target Sample · Pristine Framework | As-grown film on FTO used for XRD, SEM, UV-Vis, photoelectrochemistry and device fabrication.FTO glass · 300 nm; 30 deposition cycles | 14 / p015 · Supplementary Figures · Figure S5 |
| Free-base porphyrin Zn-SURMOF 2/FTO thickness series (100 and 300 nm)research_0200__mat__fb_zn_surmof2 | Electrode · Target Sample · Pristine Framework | As-grown thickness series used for photoelectrochemical action, on-off, and durability measurements.FTO glass · 100 nm and 300 nm | 35 / p036 · Supplementary Figures · Figure S25 |
| Free-base porphyrin Zn-SURMOF 2 thin films on various substratesresearch_0200__mat__fb_zn_surmof2 | Thin Film · Target Sample · Pristine Framework | As-deposited spray LPE SURMOF film at room temperature.FTO glass, quartz glass, soda-lime glass, glass-coated QCM sensor, MHDA/Au, or Si depending on measurement · about 10 nm per deposition cycle; commonly 300 nm for 30 cycles; 1 um for FP-TRMC/TAS | 3 / p004 · 1.2 Preparation |
| Free-base porphyrin Zn-SURMOF 2 on Si substrate, 30-cycle spray filmresearch_0200__mat__fb_zn_surmof2 | Thin Film · Target Sample · Pristine Framework | 30 spray cycles; characterised by cross-section SEM and AFM.Si substrate · ~300 nm | 45 / p046 · Supplementary Figures · Figure S35 |
| Free-base porphyrin Zn-SURMOF 2 on MHDA/Auresearch_0200__mat__fb_zn_surmof2 | Thin Film · Target Sample · Pristine Framework | Film grown on carboxyl-terminated MHDA/Au for IRRAS and XPS.16-mercaptohexadecanoic acid SAM on Au | 2 / p003 · 1.1 Preparation of substrates |
| Free-base porphyrin ethanol solution controlresearch_0200__mat__free_base_porphyrin_linker_control | Unknown · Pristine Control · Unknown | 20 uM free-base porphyrin in ethanol.none | 18 / p019; 24 / p025 · Supplementary Figures · Figures S9 and S15 |
| Free-base porphyrin Zn-SURMOF 2 photovoltaic cellresearch_0200__mat__fb_zn_surmof2 | Electrode · Target Sample · Composite | Sandwich photovoltaic device with I-/I3- acetonitrile electrolyte and 20 um hot-melt spacer.FTO glass photoelectrode with Pt-coated FTO counter electrode · about 300 nm; active area 0.25 cm2 | 7 / p008 · 1.6.1 Assembly of photovoltaic devices |
| Free-base porphyrin Zn-SURMOF 2 on glass-coated QCM sensorresearch_0200__mat__fb_zn_surmof2 | Thin Film · Target Sample · Pristine Framework | As-grown film exposed to acetonitrile and I-/I3- electrolyte in QCM-D.glass-coated QCM-D sensor | 29 / p030 · Supplementary Figures · Figure S19 |
| Free-base porphyrin Zn-SURMOF 2 on quartz glassresearch_0200__mat__fb_zn_surmof2 | Thin Film · Target Sample · Pristine Framework | Film used for UV-Vis, transient absorption, and fluorescence measurements.quartz glass | 2 / p003 · 1.1 Preparation of substrates |
| Free-base porphyrin Zn-SURMOF 2 computational modelresearch_0200__mat__fb_zn_surmof2 | Model · Model System · Model | Periodic framework and hydrogenated porphyrin electronic-structure calculations. | 8-9 / p009-p010 · 1.8 Computational studies |
| Free-base porphyrin Zn-SURMOF 2, 1 um FP-TRMC/TAS filmresearch_0200__mat__fb_zn_surmof2 | Thin Film · Target Sample · Pristine Framework | Identical film sample used for FP-TRMC and TAS.not specified · 1 um | 8 / p009 · 1.7 Evaluation of charge carrier mobility and carrier generation efficiency |
| Pd porphyrin Zn-SURMOF 2/FTO, 300 nmresearch_0200__mat__pd_zn_surmof2 | Electrode · Target Sample · Pristine Framework | As-grown film on FTO used for XRD, SEM, photoelectrochemistry and device fabrication.FTO glass · 300 nm; 30 deposition cycles | 14 / p015 · Supplementary Figures · Figure S5 |
| Pd porphyrin Zn-SURMOF 2/FTO thickness series (100 and 300 nm)research_0200__mat__pd_zn_surmof2 | Electrode · Target Sample · Pristine Framework | As-grown thickness series used for photoelectrochemical action, on-off, and durability measurements.FTO glass · 100 nm and 300 nm | 35 / p036 · Supplementary Figures · Figure S25 |
| Pd porphyrin Zn-SURMOF 2 thin films on various substratesresearch_0200__mat__pd_zn_surmof2 | Thin Film · Target Sample · Pristine Framework | As-deposited spray LPE SURMOF film at room temperature.FTO glass, quartz glass, soda-lime glass, glass-coated QCM sensor, or MHDA/Au depending on measurement · about 10 nm per deposition cycle; commonly 300 nm for 30 cycles; 1 um for FP-TRMC/TAS | 14 / p015 · Supplementary Figures · Figure S5 |
| Pd porphyrin Zn-SURMOF 2 on MHDA/Auresearch_0200__mat__pd_zn_surmof2 | Thin Film · Target Sample · Pristine Framework | Film grown on carboxyl-terminated MHDA/Au for IRRAS and XPS.16-mercaptohexadecanoic acid SAM on Au | 17 / p018 · Supplementary Figures · Figure S8 |
| Pd porphyrin ethanol solution controlresearch_0200__mat__pd_porphyrin_linker_control | Unknown · Pristine Control · Unknown | 20 uM Pd porphyrin in ethanol.none | 19 / p020 · Supplementary Figures · Figure S10 |
| Pd porphyrin Zn-SURMOF 2 photovoltaic cellresearch_0200__mat__pd_zn_surmof2 | Electrode · Target Sample · Composite | Sandwich photovoltaic device with I-/I3- acetonitrile electrolyte and 20 um hot-melt spacer.FTO glass photoelectrode with Pt-coated FTO counter electrode · about 300 nm; active area 0.25 cm2 | 7 / p008 · 1.6.1 Assembly of photovoltaic devices |
| Pd porphyrin Zn-SURMOF 2 on glass-coated QCM sensorresearch_0200__mat__pd_zn_surmof2 | Thin Film · Target Sample · Pristine Framework | As-grown film exposed to acetonitrile and I-/I3- electrolyte in QCM-D.glass-coated QCM-D sensor | 31 / p032 · Supplementary Figures · Figure S21 |
| Pd porphyrin Zn-SURMOF 2 on quartz glassresearch_0200__mat__pd_zn_surmof2 | Thin Film · Target Sample · Pristine Framework | Film used for UV-Vis and fluorescence measurements.quartz glass | 19 / p020 · Supplementary Figures · Figure S10 |
| Pd porphyrin Zn-SURMOF 2 computational modelresearch_0200__mat__pd_zn_surmof2 | Model · Model System · Model | Periodic GGA-DFT band-structure model. | 7444 / p004 · Main text · Figure 5 |
| Pd porphyrin Zn-SURMOF 2, 1 um FP-TRMC/TAS filmresearch_0200__mat__pd_zn_surmof2 | Thin Film · Target Sample · Pristine Framework | Identical film sample used for FP-TRMC and TAS.not specified · 1 um | 8 / p009 · 1.7 Evaluation of charge carrier mobility and carrier generation efficiency |
| Zn porphyrin Zn-SURMOF 2 computational modelresearch_0200__mat__zn_porphyrin_zn_surmof2_model | Model · Model System · Model | Periodic electronic-structure model used for band-gap comparison. | 7444 / p004 · Main text |