Diffraction Structure — Photoinduced Charge-Carrier Generation in Epitaxial MOF Thin Films: High Efficiency as a Result of an Indirect Electronic Band Gap?

Measurement evidence

Diffraction Structure

Photoinduced Charge-Carrier Generation in Epitaxial MOF Thin Films: High Efficiency as a Result of an Indirect Electronic Band Gap? · Liu J., Zhou W., Liu J. et al. · Angewandte Chemie - International Edition · 2015 · 7441-7445

2 measurement groups · 5 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Out-of-plane and in-plane X-ray diffraction

Free-base porphyrin Zn-SURMOF 2/FTO, 300 nm · Electrode

Cu Kalpha radiation; 2theta 2-20 deg; out-of-plane and in-plane geometries for oriented film on FTO.

Geometry
Thin film on FTO glass substrate
Context
Pristine MOF film on conductive substrate
Measurement source
11-12 / p012-p013 · Supplementary Figures · Figures S2-S3
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Out-of-plane (001) peak position2theta = 3.7 degCaption
Rounded Reported
11 / p012 · Supplementary Figures · Figure S2
Lattice parameter a perpendicular to substratea = 2.4 nmCaption
Rounded Reported
11 / p012 · Supplementary Figures · Figure S2
Lattice parameter b parallel to substrateb = 2.4 nmCaption
Rounded Reported
12 / p013 · Supplementary Figures · Figure S3
Layer spacing / lattice parameter cc = 0.66 nm calculated; observed d value 0.64 nmCaption
Rounded Reported
12 / p013 · Supplementary Figures · Figure S3

Out-of-plane X-ray diffraction

Pd porphyrin Zn-SURMOF 2 thin films on various substrates · Thin Film

Pd porphyrin Zn-SURMOF 2 fabricated on quartz glass, MHDA/Au, FTO glass and glass.

Geometry
Thin films on multiple substrates
Context
Pristine MOF films
Measurement source
16 / p017 · Supplementary Figures · Figure S7
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Preferred orientationHighly crystalline films grown exclusively along [001] orientation on quartz glass, MHDA/Au, FTO glass and glassCaption
Qualitative
16 / p017 · Supplementary Figures · Figure S7