Porosity — Proton Transport in a Highly Conductive Porous Zirconium-Based Metal-Organic Framework: Molecular Insight

Measurement evidence

Porosity

Proton Transport in a Highly Conductive Porous Zirconium-Based Metal-Organic Framework: Molecular Insight · Borges D.D., Devautour-Vinot S., Jobic H. et al. · Angewandte Chemie - International Edition · 2016 · 3919-3924

2 measurement groups · 2 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

N2 adsorption/desorption

UiO-66(Zr)-(CO2D)2 characterisation powder · Powder

BelsorpII max BEL apparatus; sample degassed at 373 K for 6 h; BET analysis.

Atmosphere
N2
Context
deuterated analogue
Measurement source
3 · Nitrogen Sorption · Figure S3
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
BET accessible surface areaMarked as a best value within this paper~444 m2 g^-1~Text
Approximate
3 · Nitrogen Sorption · Figure S3

Water adsorption isotherm

UiO-66(Zr)-(CO2H)2 pressed pellet for impedance · Pellet

303 K; reproduced from prior ref. 6 in SI.

Temperature
303
Atmosphere
water vapour
Context
pristine hydrated MOF
Measurement source
6 · Complex Impedance Spectroscopy · Figure S6
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
water uptake near P/P0 = 1approximately 14.7 mmol/g at P/P0 near 1visual estimateVisual Estimate
Approximate
6 · Complex Impedance Spectroscopy · Figure S6