cMOF Evidence Base

Synthesis evidence

Proton Transport in a Highly Conductive Porous Zirconium-Based Metal-Organic Framework: Molecular Insight

Borges D.D., Devautour-Vinot S., Jobic H. et al. · Angewandte Chemie - International Edition · 2016 · 3919-3924

2 structured synthesis routes

Completeness describes how fully the route could be reconstructed from the main article and supporting information.

Vague recipeSource: Both

Route 1: Unknown

4 · Experimental Section

Linker precursorsdeuterium-enriched analogous molecule (D6; EI: 98% from Euriso-top)
SolventsD2O used for post-activation exchange
Temperatureboiling D2O, approximate 100
Work-upHydrogen atoms of mu2-OH bridges exchanged by stirring activated sample in boiling D2O.
ActivationSynthetic conditions and activation from literature ref. 17.
Show 2 structured reagent records
RoleReagentAmount / concentrationSource
Linkerdeuterium-enriched analogous molecule (D6; EI: 98% from Euriso-top)Not specified4 · Experimental Section
SolventD2ONot specified4 · Experimental Section
Vague recipeSource: Main

Route 2: Unknown

4 · Experimental Section

Linker precursors1,2,4,5-benzenetetracarboxylic acid linker
ActivationActivated according to previously reported procedure in ref. 17.
Scalability contextMain text calls the synthesis soft, green, low-cost and environmentally friendly, but gives no stepwise recipe.
Show 1 structured reagent record
RoleReagentAmount / concentrationSource
Linker1,2,4,5-benzenetetracarboxylic acid linkerNot specified4 · Experimental Section