Shukla S., Joshi N.N., Kadian S. et al. · Journal of Materials Chemistry C · 2024 · 3886-3901
Open a family to keep every result attached to its sample, method and conditions.
Paraphrased for this database from the authors’ stated interpretations — never quoted verbatim — and kept separate from reported measurements.
P3 and P4 show better HER onset than P1/P2, whereas P1 and P2 show higher OER current densities.
Caveat: HER text states 1 M KOH, while Fig. 12 caption states 0.1 M KOH; supplied SI does not resolve the discrepancy.
3898-3899 · Electrochemical behavior studies · Fig. 12 · Linked to 4 structured results
Mixed-metal MOFs, especially P1 and P2, deliver higher anodic current response than the Cu-Try control, attributed to faster electron delocalisation and 3d-3d metal connectivity.
Caveat: Peak currents are measured on graphite paste composite electrodes and may include electrode formulation effects.
3895-3896 · Electrochemical behavior studies · Fig. 8 · Linked to 3 structured results
Thermal treatment increases electrochemical current response, attributed to carbonisation of organic linkers into conductive carbon frameworks.
Caveat: Main text provides qualitative comparison only; no numerical Fig. 10 values extracted.
3897-3898 · Electrochemical behavior studies · Fig. 10 · Linked to 1 structured result
Trypan blue remains chemically intact during MOF synthesis, preserving azo, C=C, and sulfonate linkages that support conjugation and metal coordination.
Caveat: Based on FTIR/UV-vis interpretation in the main text; supplied SI does not add raw FTIR or UV-vis tables.
3891 · Spectroscopic analyses · Fig. 4 · Linked to 4 structured results
3d-3d MOFs P1 and P2 are proposed to have lower charge-transfer resistance than 3d-4f P3/P4 because overlapping d orbitals provide more continuous electron pathways.
Caveat: Rct values are not numerically tabulated in the main text; this is a qualitative Nyquist interpretation.
3896-3897 · Electrochemical behavior studies · Fig. 9(f) · Linked to 1 structured result
Charge transport in the Trypan-blue MOFs is assigned predominantly to electron hopping rather than band-like delocalisation because all reported mobilities are below 0.1 cm^2 V^-1 s^-1.
Caveat: Mobility is CV-derived, not direct field-effect or four-probe mobility.
3896 · Electrochemical behavior studies · Eqns 1-2; Fig. 9 · Linked to 5 structured results
Names and aliases are kept exactly within the paper’s own identity model.
| Material | Composition | Structure context | Source |
|---|---|---|---|
| Co-Try MOF | Not specifiedCo · Trypan blue (Try) | unknown · PristineNot reported; used as a single-metal CV comparator. | 3897, 3899 · Electrochemical behavior studies · Fig. 11; Fig. S12-S15 |
| Cu-Try MOF (E) | Cu1.45C4.5O2.5NCu · Trypan blue (Try) | 3D · PristineMonoclinic P21/c; high crystallinity by PXRD. | 3889, 3892 · Results and discussion; Table 1 · Fig. 2; Table 1 |
| Er-Try MOF | Not specifiedEr · Trypan blue (Try) | unknown · PristineNot reported; used as a single-metal CV comparator. | 3897, 3899 · Electrochemical behavior studies · Fig. 11; Fig. S12-S15 |
| Cu-Co-Try MOF (P1) | Cu2.1Co1.2C8O5.8NCu and Co · Trypan blue (Try) | 3D · PristinePolymorphic mixture assigned to P3221 hexagonal, Pm3m cubic, and C2/c monoclinic components. | 3886, 3889, 3892 · Abstract; Results and discussion; Table 1 · Table 1 |
| Cu-Zn-Try MOF (P2) | Cu0.4Zn0.9C4.6O2.7NCu and Zn · Trypan blue (Try) | 3D · PristinePolymorphic mixture of P21/c1 monoclinic and P-1 triclinic components. | 3886, 3889, 3892 · Abstract; Results and discussion; Table 1 · Table 1 |
| Cu-Er-Try MOF (P3) | Cu0.06Er1.0C7.2O1.0NCu and Er · Trypan blue (Try) | 3D · PristinePolymorphic mix of two monoclinic P121/n1 systems; semi-crystalline by PXRD. | 3886, 3889, 3892, 3894 · Abstract; Results and discussion; Table 1 · Table 1; Fig. 6 |
| Cu-Yb-Try MOF (P4) | Cu0.1Yb1.1C9.7O3.9NCu and Yb · Trypan blue (Try) | 3D · PristineSemi-crystalline by PXRD; P4 XRD pattern shown in SI Fig. S11. | 3886, 3889, 3894 · Abstract; Results and discussion · Fig. S11 cited |
| Thermally treated Trypan-blue MOFs P1-P4 | Not specifiedCu/Co/Zn/Er/Yb depending on parent MOF · Carbonised/decomposed Trypan-blue-derived framework | unknown · DerivedThermally treated at 280 C and 580 C for electrochemical comparison; high-temperature treatment attributed to carbonisation. | 3898 · Electrochemical behavior studies · Fig. 10 |
| Yb-Try MOF | Not specifiedYb · Trypan blue (Try) | unknown · PristineNot reported; used as a single-metal CV comparator. | 3897, 3899 · Electrochemical behavior studies · Fig. 11; Fig. S12-S15 |
| Zn-Try MOF | Not specifiedZn · Trypan blue (Try) | unknown · PristineNot reported; used as a single-metal CV comparator. | 3897, 3899 · Electrochemical behavior studies · Fig. 11; Fig. S12-S15 |
Sample form, processing state and composition status define the context for measurements.
| Sample | Form and role | Processing and geometry | Source |
|---|---|---|---|
| Co-Try MOF graphite paste electroderesearch_0251__mat__m_co_try_control | Electrode · Pristine Control · Composite | single-metal MOF comparator electrode; preparation route not reported in main text or SIgraphite paste electrode, inferred from electrochemical comparison context | 3897, 3899 · Electrochemical behavior studies · Fig. 11; Fig. S12-S15 |
| Cu-Try MOF graphite paste electrode (E)research_0251__mat__m_e_cu_try | Electrode · Pristine Control · Composite | final ground MOF converted to paste with graphite powder at 10:1 and filled into GPE3 mm graphite paste electrode well | 3888 · Electrochemical measurements · Section 2.4 |
| Cu-Try MOF powder (E)research_0251__mat__m_e_cu_try | Powder · Pristine Control · Pristine Framework | as-synthesised, centrifuged, ethanol-washed, vacuum-dried at 100 C for 12 h | 3888 · Synthesis of MOFs · Section 2.2 |
| Er-Try MOF graphite paste electroderesearch_0251__mat__m_er_try_control | Electrode · Pristine Control · Composite | single-metal MOF comparator electrode; preparation route not reported in main text or SIgraphite paste electrode, inferred from electrochemical comparison context | 3897, 3899 · Electrochemical behavior studies · Fig. 11; Fig. S12-S15 |
| Cu-Co-Try MOF graphite paste electrode (P1)research_0251__mat__m_p1_cu_co_try | Electrode · Target Sample · Composite | final ground MOF converted to paste with graphite powder at 10:1 and filled into GPE3 mm graphite paste electrode well | 3888 · Electrochemical measurements · Section 2.4 |
| Cu-Co-Try MOF powder (P1)research_0251__mat__m_p1_cu_co_try | Powder · Target Sample · Mixed Metal | as-synthesised, centrifuged, ethanol-washed, vacuum-dried at 100 C for 12 h | 3888 · Synthesis of MOFs · Section 2.2 |
| Cu-Zn-Try MOF graphite paste electrode (P2)research_0251__mat__m_p2_cu_zn_try | Electrode · Target Sample · Composite | final ground MOF converted to paste with graphite powder at 10:1 and filled into GPE3 mm graphite paste electrode well | 3888 · Electrochemical measurements · Section 2.4 |
| Cu-Zn-Try MOF powder (P2)research_0251__mat__m_p2_cu_zn_try | Powder · Target Sample · Mixed Metal | as-synthesised, centrifuged, ethanol-washed, vacuum-dried at 100 C for 12 h | 3888 · Synthesis of MOFs · Section 2.2 |
| Cu-Er-Try MOF graphite paste electrode (P3)research_0251__mat__m_p3_cu_er_try | Electrode · Target Sample · Composite | final ground MOF converted to paste with graphite powder at 10:1 and filled into GPE3 mm graphite paste electrode well | 3888 · Electrochemical measurements · Section 2.4 |
| Cu-Er-Try MOF powder (P3)research_0251__mat__m_p3_cu_er_try | Powder · Target Sample · Mixed Metal | as-synthesised, centrifuged, ethanol-washed, vacuum-dried at 100 C for 12 h | 3888 · Synthesis of MOFs · Section 2.2 |
| Cu-Yb-Try MOF graphite paste electrode (P4)research_0251__mat__m_p4_cu_yb_try | Electrode · Target Sample · Composite | final ground MOF converted to paste with graphite powder at 10:1 and filled into GPE3 mm graphite paste electrode well | 3888 · Electrochemical measurements · Section 2.4 |
| Cu-Yb-Try MOF powder (P4)research_0251__mat__m_p4_cu_yb_try | Powder · Target Sample · Mixed Metal | as-synthesised, centrifuged, ethanol-washed, vacuum-dried at 100 C for 12 h | 3888 · Synthesis of MOFs · Section 2.2 |
| Thermally treated P1-P4 MOF setresearch_0251__mat__m_thermally_treated_try_mofs | Electrode · Paper Level Unspecified · Derived Carbon | parent P1-P4 MOFs thermally treated at 280 C or 580 C before CV comparisonelectrode used for CV comparison | 3898 · Electrochemical behavior studies · Fig. 10 |
| Yb-Try MOF graphite paste electroderesearch_0251__mat__m_yb_try_control | Electrode · Pristine Control · Composite | single-metal MOF comparator electrode; preparation route not reported in main text or SIgraphite paste electrode, inferred from electrochemical comparison context | 3897, 3899 · Electrochemical behavior studies · Fig. 11; Fig. S12-S15 |
| Zn-Try MOF graphite paste electroderesearch_0251__mat__m_zn_try_control | Electrode · Pristine Control · Composite | single-metal MOF comparator electrode; preparation route not reported in main text or SIgraphite paste electrode, inferred from electrochemical comparison context | 3897, 3899 · Electrochemical behavior studies · Fig. 11; Fig. S12-S15 |