Spectroscopy — Mixed metal conductive MOFs constructed from Trypan blue linked metal nodes: characteristic features and electrochemical performance

10 measurement groups · 101 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

ATR-FTIR

Infrared spectroscopy

Cu-Try MOF powder (E) · Powder

ATR-FTIR spectra compared with Trypan blue reference

Measurement source: 3890-3892 · Spectroscopic analyses · Fig. 4; Table 1

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
E FTIR C-N vibration	1334	—	—	Table Exact Reported	3892 · Table 1 · Table 1
E FTIR C-O vibration	1138	—	—	Table Exact Reported	3892 · Table 1 · Table 1
E FTIR C-S vibration	678	—	—	Table Exact Reported	3892 · Table 1 · Table 1
E FTIR C=O vibration	1617	—	—	Table Exact Reported	3892 · Table 1 · Table 1
E FTIR M-O vibration	512	—	—	Table Exact Reported	3892 · Table 1 · Table 1

XPS

X-ray photoelectron spectroscopy

Cu-Try MOF powder (E) · Powder

High-resolution XPS chemical-state analysis

Measurement source: 3891-3894 · X-Ray photoelectron analysis · Fig. 5; Table 1

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
E XPS C1s binding energies peak 1	285.56	—	—	Table Exact Reported	3892 · Table 1 · Table 1
E XPS C1s binding energies peak 2	286.91	—	—	Table Exact Reported	3892 · Table 1 · Table 1
E XPS C1s binding energies peak 3	289.24	—	—	Table Exact Reported	3892 · Table 1 · Table 1
E XPS Cu 2p1/2 binding energy	957.7	—	—	Table Exact Reported	3892 · Table 1 · Table 1
E XPS Cu 2p3/2 binding energy	937.7	—	—	Table Exact Reported	3892 · Table 1 · Table 1
E XPS Cu satellite peaks peak 1	943.3	—	—	Table Exact Reported	3892 · Table 1 · Table 1
E XPS Cu satellite peaks peak 2	947.7	—	—	Table Exact Reported	3892 · Table 1 · Table 1
E XPS Cu satellite peaks peak 3	966.1	—	—	Table Exact Reported	3892 · Table 1 · Table 1
E XPS N1s binding energies	402.69	—	—	Table Exact Reported	3892 · Table 1 · Table 1
E XPS O1s binding energies peak 1	531.5	—	—	Table Exact Reported	3892 · Table 1 · Table 1
E XPS O1s binding energies peak 2	534.42	—	—	Table Exact Reported	3892 · Table 1 · Table 1

ATR-FTIR

Infrared spectroscopy

Cu-Co-Try MOF powder (P1) · Powder

ATR-FTIR spectra compared with Trypan blue reference

Measurement source: 3890-3892 · Spectroscopic analyses · Fig. 4; Table 1

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
P1 FTIR C-N vibration	1330	—	—	Table Exact Reported	3892 · Table 1 · Table 1
P1 FTIR C-O vibration	1140	—	—	Table Exact Reported	3892 · Table 1 · Table 1
P1 FTIR C-S vibration	724	—	—	Table Exact Reported	3892 · Table 1 · Table 1
P1 FTIR C=O vibration	1700	—	—	Table Exact Reported	3892 · Table 1 · Table 1
P1 FTIR M-O vibration peak 1	597	—	—	Table Exact Reported	3892 · Table 1 · Table 1
P1 FTIR M-O vibration peak 2	511	—	—	Table Exact Reported	3892 · Table 1 · Table 1

XPS

X-ray photoelectron spectroscopy

Cu-Co-Try MOF powder (P1) · Powder

High-resolution XPS chemical-state analysis

Measurement source: 3891-3894 · X-Ray photoelectron analysis · Fig. 5; Table 1

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
P1 XPS C1s binding energies peak 1	285.39	—	—	Table Exact Reported	3892 · Table 1 · Table 1
P1 XPS C1s binding energies peak 2	287.97	—	—	Table Exact Reported	3892 · Table 1 · Table 1
P1 XPS C1s binding energies peak 3	291.69	—	—	Table Exact Reported	3892 · Table 1 · Table 1
P1 XPS Cu 2p1/2 binding energy	957.5	—	—	Table Exact Reported	3892 · Table 1 · Table 1
P1 XPS Cu 2p3/2 binding energy	937.6	—	—	Table Exact Reported	3892 · Table 1 · Table 1
P1 XPS Cu satellite peaks peak 1	942.6	—	—	Table Exact Reported	3892 · Table 1 · Table 1
P1 XPS Cu satellite peaks peak 2	946.7	—	—	Table Exact Reported	3892 · Table 1 · Table 1
P1 XPS Cu satellite peaks peak 3	966.2	—	—	Table Exact Reported	3892 · Table 1 · Table 1
P1 second-metal XPS peaks peak 1	Co: 784.7	—	—	Table Exact Reported	3892 · Table 1 · Table 1
P1 second-metal XPS peaks peak 2	Co: 788.9	—	—	Table Exact Reported	3892 · Table 1 · Table 1
P1 second-metal XPS peaks peak 3	Co: 803.2	—	—	Table Exact Reported	3892 · Table 1 · Table 1
P1 XPS N1s binding energies peak 1	390.27	—	—	Table Exact Reported	3892 · Table 1 · Table 1
P1 XPS N1s binding energies peak 2	395.02	—	—	Table Exact Reported	3892 · Table 1 · Table 1
P1 XPS N1s binding energies peak 3	403.73	—	—	Table Exact Reported	3892 · Table 1 · Table 1
P1 XPS O1s binding energies peak 1	532.13	—	—	Table Exact Reported	3892 · Table 1 · Table 1
P1 XPS O1s binding energies peak 2	535.03	—	—	Table Exact Reported	3892 · Table 1 · Table 1

ATR-FTIR

Infrared spectroscopy

Cu-Zn-Try MOF powder (P2) · Powder

ATR-FTIR spectra compared with Trypan blue reference

Measurement source: 3890-3892 · Spectroscopic analyses · Fig. 4; Table 1

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
P2 FTIR C-N vibration	1323	—	—	Table Exact Reported	3892 · Table 1 · Table 1
P2 FTIR C-O vibration	1140	—	—	Table Exact Reported	3892 · Table 1 · Table 1
P2 FTIR C-S vibration	770	—	—	Table Exact Reported	3892 · Table 1 · Table 1
P2 FTIR C=O vibration	1666	—	—	Table Exact Reported	3892 · Table 1 · Table 1
P2 FTIR M-O vibration peak 1	552	—	—	Table Exact Reported	3892 · Table 1 · Table 1
P2 FTIR M-O vibration peak 2	510	—	—	Table Exact Reported	3892 · Table 1 · Table 1

XPS

X-ray photoelectron spectroscopy

Cu-Zn-Try MOF powder (P2) · Powder

High-resolution XPS chemical-state analysis

Measurement source: 3891-3894 · X-Ray photoelectron analysis · Fig. 5; Table 1

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
P2 XPS C1s binding energies peak 1	285.94	—	—	Table Exact Reported	3892 · Table 1 · Table 1
P2 XPS C1s binding energies peak 2	288.24	—	—	Table Exact Reported	3892 · Table 1 · Table 1
P2 XPS C1s binding energies peak 3	292.21	—	—	Table Exact Reported	3892 · Table 1 · Table 1
P2 XPS Cu 2p1/2 binding energy	957.8	—	—	Table Exact Reported	3892 · Table 1 · Table 1
P2 XPS Cu 2p3/2 binding energy	937.9	—	—	Table Exact Reported	3892 · Table 1 · Table 1
P2 XPS Cu satellite peaks peak 1	943.38	—	—	Table Exact Reported	3892 · Table 1 · Table 1
P2 XPS Cu satellite peaks peak 2	947.5	—	—	Table Exact Reported	3892 · Table 1 · Table 1
P2 XPS Cu satellite peaks peak 3	965.1	—	—	Table Exact Reported	3892 · Table 1 · Table 1
P2 second-metal XPS peaks peak 1	Zn: 1016.6	—	—	Table Exact Reported	3892 · Table 1 · Table 1
P2 second-metal XPS peaks peak 2	Zn: 1025.9	—	—	Table Exact Reported	3892 · Table 1 · Table 1
P2 second-metal XPS peaks peak 3	Zn: 1039.1	—	—	Table Exact Reported	3892 · Table 1 · Table 1
P2 second-metal XPS peaks peak 4	Zn: 1049.04	—	—	Table Exact Reported	3892 · Table 1 · Table 1
P2 XPS N1s binding energies peak 1	393.98	—	—	Table Exact Reported	3892 · Table 1 · Table 1
P2 XPS N1s binding energies peak 2	398.18	—	—	Table Exact Reported	3892 · Table 1 · Table 1
P2 XPS O1s binding energies peak 1	533.01	—	—	Table Exact Reported	3892 · Table 1 · Table 1
P2 XPS O1s binding energies peak 2	535.28	—	—	Table Exact Reported	3892 · Table 1 · Table 1

ATR-FTIR

Infrared spectroscopy

Cu-Er-Try MOF powder (P3) · Powder

ATR-FTIR spectra compared with Trypan blue reference

Measurement source: 3890-3892 · Spectroscopic analyses · Fig. 4; Table 1

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
P3 FTIR C-N vibration	1298	—	—	Table Exact Reported	3892 · Table 1 · Table 1
P3 FTIR C-O vibration	1135	—	—	Table Exact Reported	3892 · Table 1 · Table 1
P3 FTIR C-S vibration	746	—	—	Table Exact Reported	3892 · Table 1 · Table 1
P3 FTIR C=O vibration	1689	—	—	Table Exact Reported	3892 · Table 1 · Table 1
P3 FTIR M-O vibration peak 1	599	—	—	Table Exact Reported	3892 · Table 1 · Table 1
P3 FTIR M-O vibration peak 2	512	—	—	Table Exact Reported	3892 · Table 1 · Table 1

XPS

X-ray photoelectron spectroscopy

Cu-Er-Try MOF powder (P3) · Powder

High-resolution XPS chemical-state analysis

Measurement source: 3891-3894 · X-Ray photoelectron analysis · Fig. 5; Table 1

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
P3 XPS C1s binding energies peak 1	286.01	—	—	Table Exact Reported	3892 · Table 1 · Table 1
P3 XPS C1s binding energies peak 2	287.71	—	—	Table Exact Reported	3892 · Table 1 · Table 1
P3 XPS C1s binding energies peak 3	291.91	—	—	Table Exact Reported	3892 · Table 1 · Table 1
P3 XPS Cu 2p1/2 binding energy	956.38	—	—	Table Exact Reported	3892 · Table 1 · Table 1
P3 XPS Cu 2p3/2 binding energy	936.5	—	—	Table Exact Reported	3892 · Table 1 · Table 1
P3 XPS Cu satellite peaks peak 1	946	—	—	Table Exact Reported	3892 · Table 1 · Table 1
P3 XPS Cu satellite peaks peak 2	962	—	—	Table Exact Reported	3892 · Table 1 · Table 1
P3 second-metal XPS peaks peak 1	Er: 201.59	—	—	Table Exact Reported	3892 · Table 1 · Table 1
P3 second-metal XPS peaks peak 2	Er: 173.16	—	—	Table Exact Reported	3892 · Table 1 · Table 1
P3 second-metal XPS peaks peak 3	Er: 189.12	—	—	Table Exact Reported	3892 · Table 1 · Table 1
P3 second-metal XPS peaks peak 4	Er: 201.59	—	—	Table Exact Reported	3892 · Table 1 · Table 1
P3 XPS N1s binding energies peak 1	395.85	—	—	Table Exact Reported	3892 · Table 1 · Table 1
P3 XPS N1s binding energies peak 2	400.01	—	—	Table Exact Reported	3892 · Table 1 · Table 1
P3 XPS O1s binding energies peak 1	532.39	—	—	Table Exact Reported	3892 · Table 1 · Table 1
P3 XPS O1s binding energies peak 2	534.79	—	—	Table Exact Reported	3892 · Table 1 · Table 1

ATR-FTIR

Infrared spectroscopy

Cu-Yb-Try MOF powder (P4) · Powder

ATR-FTIR spectra compared with Trypan blue reference

Measurement source: 3890-3892 · Spectroscopic analyses · Fig. 4; Table 1

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
P4 FTIR C-N vibration	1297	—	—	Table Exact Reported	3892 · Table 1 · Table 1
P4 FTIR C-O vibration	1134	—	—	Table Exact Reported	3892 · Table 1 · Table 1
P4 FTIR C-S vibration	745	—	—	Table Exact Reported	3892 · Table 1 · Table 1
P4 FTIR C=O vibration	1645	—	—	Table Exact Reported	3892 · Table 1 · Table 1
P4 FTIR M-O vibration peak 1	559	—	—	Table Exact Reported	3892 · Table 1 · Table 1
P4 FTIR M-O vibration peak 2	516	—	—	Table Exact Reported	3892 · Table 1 · Table 1

XPS

X-ray photoelectron spectroscopy

Cu-Yb-Try MOF powder (P4) · Powder

High-resolution XPS chemical-state analysis

Measurement source: 3891-3894 · X-Ray photoelectron analysis · Fig. 5; Table 1

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
P4 XPS C1s binding energies peak 1	285.89	—	—	Table Exact Reported	3892 · Table 1 · Table 1
P4 XPS C1s binding energies peak 2	287.35	—	—	Table Exact Reported	3892 · Table 1 · Table 1
P4 XPS C1s binding energies peak 3	291.19	—	—	Table Exact Reported	3892 · Table 1 · Table 1
P4 XPS Cu 2p1/2 binding energy	956.11	—	—	Table Exact Reported	3892 · Table 1 · Table 1
P4 XPS Cu 2p3/2 binding energy	936.06	—	—	Table Exact Reported	3892 · Table 1 · Table 1
P4 XPS Cu satellite peaks peak 1	944.67	—	—	Table Exact Reported	3892 · Table 1 · Table 1
P4 XPS Cu satellite peaks peak 2	963.34	—	—	Table Exact Reported	3892 · Table 1 · Table 1
P4 second-metal XPS peaks peak 1	Yb: 186.45	—	—	Table Exact Reported	3892 · Table 1 · Table 1
P4 second-metal XPS peaks peak 2	Yb: 196.69	—	—	Table Exact Reported	3892 · Table 1 · Table 1
P4 XPS N1s binding energies peak 1	391.01	—	—	Table Exact Reported	3892 · Table 1 · Table 1
P4 XPS N1s binding energies peak 2	395.33	—	—	Table Exact Reported	3892 · Table 1 · Table 1
P4 XPS N1s binding energies peak 3	400.21	—	—	Table Exact Reported	3892 · Table 1 · Table 1
P4 XPS O1s binding energies peak 1	531.31	—	—	Table Exact Reported	3892 · Table 1 · Table 1
P4 XPS O1s binding energies peak 2	534.38	—	—	Table Exact Reported	3892 · Table 1 · Table 1