Synthesis · Mixed metal conductive MOFs constructed from Trypan blue linked metal nodes: characteristic features and electrochemical performance

5 structured synthesis routes

Completeness describes how fully the route could be reconstructed from the main article and supporting information.

Partial recipeSource: Main

Route 1: Solvothermal

3888 · Synthesis of Cux (Try)x · Section 2.2

Metal precursorsCu(NO3)2.H2O (100 mg)

Linker precursorsTrypan blue solution (0.4%) (100 uL)

SolventsDMF (4 mL)

Atmospherenot specified

Temperature110

Time24

Work-upcentrifuged from mixture; washed repeatedly with ethanol

Activationdried in a vacuum oven at 100 C for 12 h

Scalability contextAuthors state Trypan blue utilisation without waste may reduce environmental impact, but no scale-up experiment is reported.

Show 3 structured reagent records

Role	Reagent	Amount / concentration	Source
Metal Source	Cu(NO3)2.H2O	100 mg	3888 · Synthesis of Cux (Try)x · Section 2.2
Linker	Trypan blue solution (0.4%)	100 uL · 0.4%	3888 · Synthesis of Cux (Try)x · Section 2.2
Solvent	DMF	4 mL	3888 · Synthesis of Cux (Try)x · Section 2.2

Partial recipeSource: Main

Route 2: Solvothermal

3888 · Synthesis of Cux Coy (Try)x · Section 2.2

Metal precursorsCu(NO3)2.H2O (100 mg); Co(NO3)2 (100 mg)

Linker precursorsTrypan blue solution (0.4%) (100 uL)

SolventsDMF (4 mL)

Atmospherenot specified

Temperature110

Time24

Work-upcentrifuged from mixture; washed repeatedly with ethanol

Activationdried in a vacuum oven at 100 C for 12 h

Scalability contextAuthors state Trypan blue utilisation without waste may reduce environmental impact, but no scale-up experiment is reported.

Show 4 structured reagent records

Role	Reagent	Amount / concentration	Source
Metal Source	Cu(NO3)2.H2O	100 mg	3888 · Synthesis of Cux Coy (Try)x · Section 2.2
Metal Source	Co(NO3)2	100 mg	3888 · Synthesis of Cux Coy (Try)x · Section 2.2
Linker	Trypan blue solution (0.4%)	100 uL · 0.4%	3888 · Synthesis of Cux Coy (Try)x · Section 2.2
Solvent	DMF	4 mL	3888 · Synthesis of Cux Coy (Try)x · Section 2.2

Partial recipeSource: Main

Route 3: Solvothermal

3888 · Synthesis of Cux Zny (Try)x · Section 2.2

Metal precursorsCu(NO3)2.H2O (100 mg); Zn(NO3)2.H2O (100 mg)

Linker precursorsTrypan blue solution (0.4%) (100 uL)

SolventsDMF (4 mL)

Atmospherenot specified

Temperature110

Time24

Work-upcentrifuged from mixture; washed repeatedly with ethanol

Activationdried in a vacuum oven at 100 C for 12 h

Scalability contextAuthors state Trypan blue utilisation without waste may reduce environmental impact, but no scale-up experiment is reported.

Show 4 structured reagent records

Role	Reagent	Amount / concentration	Source
Metal Source	Cu(NO3)2.H2O	100 mg	3888 · Synthesis of Cux Zny (Try)x · Section 2.2
Metal Source	Zn(NO3)2.H2O	100 mg	3888 · Synthesis of Cux Zny (Try)x · Section 2.2
Linker	Trypan blue solution (0.4%)	100 uL · 0.4%	3888 · Synthesis of Cux Zny (Try)x · Section 2.2
Solvent	DMF	4 mL	3888 · Synthesis of Cux Zny (Try)x · Section 2.2

Partial recipeSource: Main

Route 4: Solvothermal

3888 · Synthesis of Cux Ery (Try)x · Section 2.2

Metal precursorsCu(NO3)2.H2O (100 mg); Er(Cl3)3 (100 mg) as printed/OCRed

Linker precursorsTrypan blue solution (0.4%) (100 uL)

SolventsDMF (4 mL)

Atmospherenot specified

Temperature110

Time24

Work-upcentrifuged from mixture; washed repeatedly with ethanol

Activationdried in a vacuum oven at 100 C for 12 h

Scalability contextAuthors state Trypan blue utilisation without waste may reduce environmental impact, but no scale-up experiment is reported.

Show 4 structured reagent records

Role	Reagent	Amount / concentration	Source
Metal Source	Cu(NO3)2.H2O	100 mg	3888 · Synthesis of Cux Ery (Try)x · Section 2.2
Metal Source	Er(Cl3)3	100 mg	3888 · Synthesis of Cux Ery (Try)x · Section 2.2
Linker	Trypan blue solution (0.4%)	100 uL · 0.4%	3888 · Synthesis of Cux Ery (Try)x · Section 2.2
Solvent	DMF	4 mL	3888 · Synthesis of Cux Ery (Try)x · Section 2.2

Partial recipeSource: Main

Route 5: Solvothermal

3888 · Synthesis of Cux Yby (Try)x · Section 2.2

Metal precursorsCu(NO3)2.H2O (100 mg); Yb(Cl3)3 (100 mg) as printed/OCRed

Linker precursorsTrypan blue solution (0.4%) (100 uL)

SolventsDMF (4 mL)

Atmospherenot specified

Temperature110

Time24

Work-upcentrifuged from mixture; washed repeatedly with ethanol

Activationdried in a vacuum oven at 100 C for 12 h

Scalability contextAuthors state Trypan blue utilisation without waste may reduce environmental impact, but no scale-up experiment is reported.

Show 4 structured reagent records

Role	Reagent	Amount / concentration	Source
Metal Source	Cu(NO3)2.H2O	100 mg	3888 · Synthesis of Cux Yby (Try)x · Section 2.2
Metal Source	Yb(Cl3)3	100 mg	3888 · Synthesis of Cux Yby (Try)x · Section 2.2
Linker	Trypan blue solution (0.4%)	100 uL · 0.4%	3888 · Synthesis of Cux Yby (Try)x · Section 2.2
Solvent	DMF	4 mL	3888 · Synthesis of Cux Yby (Try)x · Section 2.2