Electrical Transport — Mixed metal conductive MOFs constructed from Trypan blue linked metal nodes: characteristic features and electrochemical performance

9 measurement groups · 11 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

CV-derived charge mobility calculation

Voltammetry

Cu-Try MOF graphite paste electrode (E) · Electrode

Mobility calculated from diffusion coefficient and Randles-Sevcik relation; below 0.1 cm^2 V^-1 s^-1 interpreted as hopping transport

Measurement source: 3896 · Electrochemical behavior studies · Equations 1-2; Fig. 9

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
E charge mobility	1.08e-07	—	—	Text Exact Reported	3896 · Electrochemical behavior studies · Eqns 1-2; Fig. 9
E log Ip vs log v^1/2 R2	0.982	—	—	Figure Axis Rounded Reported	3898 · Electrochemical behavior studies · Fig. 9

Electrochemical impedance spectroscopy (EIS)

Impedance spectroscopy

Cu-Co-Try MOF graphite paste electrode (P1) · Electrode

0.1 N HCl; open-circuit initial voltage; 0.1 Hz to 100 kHz; 5 mV amplitude

Measurement source: 3888, 3896 · Electrochemical measurements; Electrochemical behavior studies · Fig. 9(f)

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Nyquist/Rct qualitative orderMarked as a best value within this paper	Rct order: P1 lowest; P4 highest; P2 approximately P3 intermediate	—	—	Text Qualitative	3896 · Electrochemical behavior studies · Fig. 9(f)

CV-derived charge mobility calculation

Voltammetry

Cu-Co-Try MOF graphite paste electrode (P1) · Electrode

Mobility calculated from diffusion coefficient and Randles-Sevcik relation; below 0.1 cm^2 V^-1 s^-1 interpreted as hopping transport

Measurement source: 3896 · Electrochemical behavior studies · Equations 1-2; Fig. 9

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
P1 charge mobility	0.00125	—	—	Text Exact Reported	3896 · Electrochemical behavior studies · Eqns 1-2; Fig. 9
P1 log Ip vs log v^1/2 R2	0.989	—	—	Figure Axis Rounded Reported	3898 · Electrochemical behavior studies · Fig. 9

Electrochemical impedance spectroscopy (EIS)

Impedance spectroscopy

Cu-Zn-Try MOF graphite paste electrode (P2) · Electrode

0.1 N HCl; open-circuit initial voltage; 0.1 Hz to 100 kHz; 5 mV amplitude

Measurement source: 3888, 3896 · Electrochemical measurements; Electrochemical behavior studies · Fig. 9(f)

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source

CV-derived charge mobility calculation

Voltammetry

Cu-Zn-Try MOF graphite paste electrode (P2) · Electrode

Mobility calculated from diffusion coefficient and Randles-Sevcik relation; below 0.1 cm^2 V^-1 s^-1 interpreted as hopping transport

Measurement source: 3896 · Electrochemical behavior studies · Equations 1-2; Fig. 9

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
P2 charge mobilityMarked as a best value within this paper	0.00142	—	—	Text Exact Reported	3896 · Electrochemical behavior studies · Eqns 1-2; Fig. 9
P2 log Ip vs log v^1/2 R2	0.981	—	—	Figure Axis Rounded Reported	3898 · Electrochemical behavior studies · Fig. 9

Electrochemical impedance spectroscopy (EIS)

Impedance spectroscopy

Cu-Er-Try MOF graphite paste electrode (P3) · Electrode

0.1 N HCl; open-circuit initial voltage; 0.1 Hz to 100 kHz; 5 mV amplitude

Measurement source: 3888, 3896 · Electrochemical measurements; Electrochemical behavior studies · Fig. 9(f)

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source

CV-derived charge mobility calculation

Voltammetry

Cu-Er-Try MOF graphite paste electrode (P3) · Electrode

Mobility calculated from diffusion coefficient and Randles-Sevcik relation; below 0.1 cm^2 V^-1 s^-1 interpreted as hopping transport

Measurement source: 3896 · Electrochemical behavior studies · Equations 1-2; Fig. 9

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
P3 charge mobility	0.000158	—	—	Text Exact Reported	3896 · Electrochemical behavior studies · Eqns 1-2; Fig. 9
P3 log Ip vs log v^1/2 R2	0.984	—	—	Figure Axis Rounded Reported	3898 · Electrochemical behavior studies · Fig. 9

Electrochemical impedance spectroscopy (EIS)

Impedance spectroscopy

Cu-Yb-Try MOF graphite paste electrode (P4) · Electrode

0.1 N HCl; open-circuit initial voltage; 0.1 Hz to 100 kHz; 5 mV amplitude

Measurement source: 3888, 3896 · Electrochemical measurements; Electrochemical behavior studies · Fig. 9(f)

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source

CV-derived charge mobility calculation

Voltammetry

Cu-Yb-Try MOF graphite paste electrode (P4) · Electrode

Mobility calculated from diffusion coefficient and Randles-Sevcik relation; below 0.1 cm^2 V^-1 s^-1 interpreted as hopping transport

Measurement source: 3896 · Electrochemical behavior studies · Equations 1-2; Fig. 9

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
P4 charge mobility	0.000151	—	—	Text Exact Reported	3896 · Electrochemical behavior studies · Eqns 1-2; Fig. 9
P4 log Ip vs log v^1/2 R2	0.957	—	—	Figure Axis Rounded Reported	3898 · Electrochemical behavior studies · Fig. 9