Zhu X., He T., Song X. et al. · Advanced Materials · 2024 · 2412432
Open a family to keep every result attached to its sample, method and conditions.
Paraphrased for this database from the authors’ stated interpretations — never quoted verbatim — and kept separate from reported measurements.
Continuous semiconductive MOF glass films provide a large-area, low-temperature route to direct X-ray detectors.
Caveat: Application performance is demonstrated on lab X-ray detector devices, not on a commercial detector stack.
main p.7 · 3. Conclusion · Linked to 3 structured results
The originally published Figure 2a mistakenly used the recrystallised-sample PXRD pattern rather than freshly synthesised MOF powder; the corrected pattern still agrees with the theoretical pattern.
Caveat: Correction states the change does not affect experimental results, discussions or conclusions.
correction p.1 · Correction · Corrected Figure 2a · Linked to 1 structured result
ZnPIm retained its glassy amorphous state during X-ray testing.
Caveat: This supporting result was added in the correction's updated Supporting Information and is represented locally by the correction document.
correction p.1 · Correction · Figure S16 · Linked to 1 structured result
MOFs with organic linkers lacking benzene rings are reported to have higher mobility-lifetime products and longer carrier-diffusion lengths than those containing benzene rings.
Caveat: The relationship is inferred by the authors from the four-linker series; no independent mechanistic transport experiment beyond mu-tau/diffusion comparison is shown.
main p.6 · 2.2. X-Ray Performance and Imaging · Table S3 · Linked to 8 structured results
The smooth, homogeneous glass morphology is linked to reduced material defects and improved charge transfer compared with pressed discs.
Caveat: Disc X-ray response is described qualitatively; quantitative disc response values were not present in the available text.
main p.5 · 2.2. X-Ray Performance and Imaging · Figure 2c; Figure S11 · Linked to 4 structured results
The H2PO4 linker is proposed to facilitate proton transport within the ZnPIm framework, contributing to semiconductive characteristics.
Caveat: The statement is mechanistic interpretation; direct proton-transport measurements were not present in the available text.
main p.2 · Introduction · Linked to 2 structured results
Names and aliases are kept exactly within the paper’s own identity model.
| Material | Composition | Structure context | Source |
|---|---|---|---|
| ZnBTA | [Zn3(H2PO4)6(H2O)3]BTAZinc phosphate units. · BTA, 1,2,3-benzotriazole. | unknown · PristineMOF glass comparator with powder, glass and simulated PXRD patterns reported in the SI. | SI p.S5 · 2. Supplementary Figures · Figure S1 |
| ZnHBIm | [Zn3(H2PO4)6(H2O)3]HBImZinc phosphate units. · HBIm, described as benzimidazolate in the SI caption. | unknown · PristineMOF glass comparator with powder, glass and simulated PXRD patterns reported in the SI. | SI p.S5 · 2. Supplementary Figures · Figure S1 |
| ZnPIm | [Zn(HPO4)(H2PO4)2](ImH2)2Tetrahedrally coordinated Zn2+ centres in zinc phosphate chain units. · Imidazolium/imidazole-derived species plus HPO4 and H2PO4 phosphate ligands. | 1D · PristineIonic zinc phosphate-imidazolium MOF with extended 1D chain frameworks; crystalline powder converts to amorphous MOF glass film on melting. | main p.2 · 2.1. Synthesis, Structure and Characterization · Figure 1a |
| ZnTzH | [Zn(H2PO4)2]TzHZinc phosphate units. · TzH, 1,2,3-triazole. | unknown · PristineMOF glass comparator with powder, glass and simulated PXRD patterns reported in the SI. | SI p.S5 · 2. Supplementary Figures · Figure S1 |
Sample form, processing state and composition status define the context for measurements.
| Sample | Form and role | Processing and geometry | Source |
|---|---|---|---|
| ZnBTA MOF glass detectorresearch_0338__mat__znbta | Electrode · Target Sample · Pristine Framework | MOF glass detector prepared from ZnBTA series material.Unspecified device substrate | main p.6 · 2.2. X-Ray Performance and Imaging · Figure 4a-b |
| ZnHBIm MOF glass detectorresearch_0338__mat__znhbim | Electrode · Target Sample · Pristine Framework | MOF glass detector prepared from ZnHBIm series material.Unspecified device substrate | main p.6 · 2.2. X-Ray Performance and Imaging · Figure 4a-b |
| Ag/ZnPIm/Ag planar MOF glass detectorresearch_0338__mat__znpim | Electrode · Target Sample · Pristine Framework | ZnPIm glass film engineered with symmetric Ag electrodes.Unspecified device substrate · approximately 0.8 mm | main p.5 · 2.2. X-Ray Performance and Imaging · Figure 3a |
| ZnPIm MOF glass filmresearch_0338__mat__znpim | Thin Film · Target Sample · Pristine Framework | MOF powder melted on a substrate at its melting point to form a continuous glass film.Unspecified substrate | SI p.S2 · Experimental section - Preparation of MOF glass films · Figure S8 |
| DFT model of ZnPImresearch_0338__mat__znpim | Model · Model System · Model | HSE06 DFT model system. | SI p.S2 · Experimental section - Computational methods |
| Dry ZnPIm powderresearch_0338__mat__znpim | Powder · Target Sample · Pristine Framework | Ground precursor mixture, then evacuated at 100 C overnight to obtain a dry pure-phase compound. | SI p.S2 · Experimental section - Synthesis of [Zn(HPO4)(H2PO4)2](ImH2)2 |
| Pressed ZnPIm MOF discresearch_0338__mat__znpim | Pellet · Pristine Control · Pristine Framework | Pressed-disc counterpart of ZnPIm powder. | main p.2 · 2.1. Synthesis, Structure and Characterization · Figure 2c |
| ZnTzH MOF glass detectorresearch_0338__mat__zntzh | Electrode · Target Sample · Pristine Framework | MOF glass detector prepared from ZnTzH series material.Unspecified device substrate | main p.6 · 2.2. X-Ray Performance and Imaging · Figure 4a-b |