cMOF Evidence Base
Electrical Transport — Large-Area Metal–Organic Framework Glasses for Efficient X-Ray Detection

Measurement evidence

Electrical Transport

Large-Area Metal–Organic Framework Glasses for Efficient X-Ray Detection · Zhu X., He T., Song X. et al. · Advanced Materials · 2024 · 2412432

8 measurement groups · 20 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

DC-field Hall-effect measurement

Hall-effect measurements

ZnBTA MOF glass detector · Electrode

Hall results for MOF glass detectors with different organic linkers.

Geometry
MOF glass detector
Context
Pristine ZnBTA comparator glass detector.
Measurement source
SI p.S12 · Supplementary Figures · Table S1
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Hall carrier mobility46.42 cm2 V^-1 S^-1——SI Table
Exact Reported		SI p.S12 · Supplementary Figures · Table S1
Carrier typep——SI Table
Qualitative		SI p.S12 · Supplementary Figures · Table S1

Hecht-equation mobility-lifetime product and diffusion length

ZnBTA MOF glass detector · Electrode

Table S3 reports charge-carrier mobility-lifetime product, long carrier-diffusion length and Zn-N distance for organic-linker series.

Geometry
MOF glass detector
Context
Pristine ZnBTA comparator glass detector.
Measurement source
SI p.S17 · Supplementary Figures · Table S3
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Long carrier-diffusion length25 um——SI Table
Exact Reported		SI p.S17 · Supplementary Figures · Table S3
Mobility-lifetime product2.51 x 10^-4 cm2 V^-1——SI Table
Exact Reported		SI p.S17 · Supplementary Figures · Table S3
Zn-N distance6.44 A——SI Table
Exact Reported		SI p.S17 · Supplementary Figures · Table S3

DC-field Hall-effect measurement

Hall-effect measurements

ZnHBIm MOF glass detector · Electrode

Hall results for MOF glass detectors with different organic linkers.

Geometry
MOF glass detector
Context
Pristine ZnHBIm comparator glass detector.
Measurement source
SI p.S12 · Supplementary Figures · Table S1
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Hall carrier mobility38.29 cm2 V^-1 S^-1——SI Table
Exact Reported		SI p.S12 · Supplementary Figures · Table S1
Carrier typen——SI Table
Qualitative		SI p.S12 · Supplementary Figures · Table S1

Hecht-equation mobility-lifetime product and diffusion length

ZnHBIm MOF glass detector · Electrode

Table S3 reports charge-carrier mobility-lifetime product, long carrier-diffusion length and Zn-N distance for organic-linker series.

Geometry
MOF glass detector
Context
Pristine ZnHBIm comparator glass detector.
Measurement source
SI p.S17 · Supplementary Figures · Table S3
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Long carrier-diffusion length31 um——SI Table
Exact Reported		SI p.S17 · Supplementary Figures · Table S3
Mobility-lifetime product3.89 x 10^-4 cm2 V^-1——SI Table
Exact Reported		SI p.S17 · Supplementary Figures · Table S3
Zn-N distance5.56 A——SI Table
Exact Reported		SI p.S17 · Supplementary Figures · Table S3

DC-field Hall-effect measurement

Hall-effect measurements

Ag/ZnPIm/Ag planar MOF glass detector · Electrode

10 mm x 10 mm MOF glass; Lake Shore Hall effect system 7707A; Au electrodes on four corners; field sweep 10 G to 1 kG.

Geometry
Au four-corner Hall sample
Context
Pristine ZnPIm MOF glass device.
Measurement source
SI p.S3 · Hall-effect measurement · Table S1
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Hall carrier mobilityMarked as a best value within this paper1174.81 cm2 V^-1 S^-1——SI Table
Exact Reported		SI p.S12 · Supplementary Figures · Table S1
Carrier typep-type semiconducting property——SI Table
Qualitative		SI p.S12 · Supplementary Figures · Table S1

Bias-dependent photocurrent fit using modified Hecht equation

Photoresponse and photoelectrochemistry

Ag/ZnPIm/Ag planar MOF glass detector · Electrode

Mobility-lifetime product derived from bias-dependent photocurrent curve.

Atmosphere
air
Geometry
Ag/ZnPIm/Ag planar detector
Context
Pristine ZnPIm MOF glass detector.
Measurement source
main p.5 · 2.2. X-Ray Performance and Imaging · Figure 3b; Table S3
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Long carrier-diffusion lengthMarked as a best value within this paper47 um——SI Table
Exact Reported		SI p.S17 · Supplementary Figures · Table S3
Mobility-lifetime productMarked as a best value within this paper8.82 x 10^-4 cm2 V^-1——SI Table
Exact Reported		SI p.S17 · Supplementary Figures · Table S3
Zn-N distance3.67 A——SI Table
Exact Reported		SI p.S17 · Supplementary Figures · Table S3

DC-field Hall-effect measurement

Hall-effect measurements

ZnTzH MOF glass detector · Electrode

Hall results for MOF glass detectors with different organic linkers.

Geometry
MOF glass detector
Context
Pristine ZnTzH comparator glass detector.
Measurement source
SI p.S12 · Supplementary Figures · Table S1
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Hall carrier mobility452.65 cm2 V^-1 S^-1——SI Table
Exact Reported		SI p.S12 · Supplementary Figures · Table S1
Carrier typep——SI Table
Qualitative		SI p.S12 · Supplementary Figures · Table S1

Hecht-equation mobility-lifetime product and diffusion length

ZnTzH MOF glass detector · Electrode

Table S3 reports charge-carrier mobility-lifetime product, long carrier-diffusion length and Zn-N distance for organic-linker series.

Geometry
MOF glass detector
Context
Pristine ZnTzH comparator glass detector.
Measurement source
SI p.S17 · Supplementary Figures · Table S3
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Long carrier-diffusion length37 um——SI Table
Exact Reported		SI p.S17 · Supplementary Figures · Table S3
Mobility-lifetime product5.46 x 10^-4 cm2 V^-1——SI Table
Exact Reported		SI p.S17 · Supplementary Figures · Table S3
Zn-N distance2.18 A——SI Table
Exact Reported		SI p.S17 · Supplementary Figures · Table S3