Complete recipeSource: Main
Route 1: Other
main p.3 / article p.343 · Synthetic procedure
Metal precursorsCuI (190 mg, 1.00 mmol)
Linker precursors2-amino-4-chloropyrimidine (aClpym) (130 mg, 1.00 mmol)
SolventsEthanol (23 mL) for ligand solution; acetonitrile (12 mL) for CuI solution.
AtmosphereNot specified for synthesis.
Temperature25
Time24
Oxidant / reductantNone reported.
Work-upFiltered; washed with acetonitrile (2 x 3 mL) and ethanol (2 x 3 mL); dried under vacuum.
ActivationDried under vacuum; no porosity activation reported.
Scalability contextSingle-step room-temperature precipitation; yield 242 mg, 76% based on Cu.
Show 4 structured reagent records
| Role | Reagent | Amount / concentration | Source |
|---|---|---|---|
| Metal Source | Copper(I) iodide (CuI) | 190 mg, 1.00 mmol | main p.3 / article p.343 · Synthetic procedure |
| Linker | 2-amino-4-chloropyrimidine (aClpym) | 130 mg, 1.00 mmol | main p.3 / article p.343 · Synthetic procedure |
| Solvent | ethanol (EtOH) | 23 mL | main p.3 / article p.343 · Synthetic procedure |
| Solvent | acetonitrile (CH3CN) | 12 mL | main p.3 / article p.343 · Synthetic procedure |