Electrochemistry Application — Experimental manifestation of redox-conductivity in metal-organic frameworks and its implication for semiconductor/insulator switching

Measurement evidence

Electrochemistry Application

Experimental manifestation of redox-conductivity in metal-organic frameworks and its implication for semiconductor/insulator switching · Li J., Kumar A., Johnson B.A. et al. · Nature Communications · 2023 · 4388

1 measurement group · 2 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Cyclic voltammetry

Zn(pyrazol-NDI) thin film on FTO · Thin Film

CV in Ar-saturated DMF with 0.1 M KPF6 supporting electrolyte; representative slow scan at 5 mV s-1.

Atmosphere: Ar-saturated
Geometry: One-compartment three-electrode cell; MOF thin film on FTO working electrode, glassy carbon rod counter electrode, Ag/AgNO3 reference.
Context: Pristine Zn(pyrazol-NDI) thin film with electrochemically addressable redox states.
Measurement source: 3 · Electrochemical modulation · Fig. 2d

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Zn(pyrazol-NDI) NDI/NDI radical anion formal potential	-0.79 V vs Ag/AgNO3	—	—	Text Exact Reported	3 · Electrochemical modulation · Fig. 2d
Zn(pyrazol-NDI) NDI radical anion/NDI dianion formal potential	-1.17 V vs Ag/AgNO3	—	—	Text Exact Reported	3 · Electrochemical modulation · Fig. 2d