Complete recipeSource: Both
Route 1: Solvothermal
8 · Methods: Synthesis of UU-100(Co) thin-film on FTO surface
Metal precursorsZrCl4, 26 mg, 0.11 mmol; Co already present in cobaloxime linker
Linker precursorscobaloxime linker, 30 mg, 0.038 mmol; SAM from 1 mM cobaloxime linker in anhydrous DMF
SolventsAnhydrous DMF, 8 mL; DMF for SAM and washing; 50 uL H2O
AdditivesAnhydrous acetic acid, 35 uL, 0.61 mmol
Atmospheresealed vial; no inert atmosphere reported for synthesis
Temperature80
Time120
Substrate orientationSAM-modified FTO transferred with FTO side facing down
Work-upAfter solvothermal growth, slowly cool to room temperature; wash with DMF; remove unwanted growth on glass side with DMF-wetted Kimtech paper.
ActivationSoaked in DMF for future analysis; no dry activation reported.
Scalability contextIncludes a 2 h 80 degC pre-heating step to form Zr cluster solution before adding cobaloxime linker and growing for 5 days.
Show 6 structured reagent records
| Role | Reagent | Amount / concentration | Source |
|---|---|---|---|
| Metal Source | ZrCl4 | 26 mg, 0.11 mmol | 8 · Methods: Synthesis of UU-100(Co) thin-film on FTO surface |
| Linker | cobaloxime linker | 30 mg, 0.038 mmol · 1 mM for SAM pretreatment | 8 · Methods: Synthesis of UU-100(Co) thin-film on FTO surface |
| Acid | anhydrous acetic acid | 35 uL, 0.61 mmol | 8 · Methods: Synthesis of UU-100(Co) thin-film on FTO surface |
| Solvent | DMF | 8 mL | 8 · Methods: Synthesis of UU-100(Co) thin-film on FTO surface |
| Additive | H2O | 50 uL | 8 · Methods: Synthesis of UU-100(Co) thin-film on FTO surface |
| Other | SAM-modified FTO | 1 x 2 cm | 8 · Methods: Synthesis of UU-100(Co) thin-film on FTO surface |