cMOF Evidence Base
Other — Fabrication of an Active Electronic Device Using a Hetero-bimetallic Coordination Polymer

Measurement evidence

Other

Fabrication of an Active Electronic Device Using a Hetero-bimetallic Coordination Polymer · Roy S., Halder S., Drew M.G.B. et al. · ACS Omega · 2018 · 12788-12796

2 measurement groups · 10 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Yield, elemental analysis, and routine analytical characterisation of isolated product

Bulk elemental and compositional analysis

X-ray quality crystalline [(NCS)Pb(H2O)LNi(NCS)]n · Single Crystal

Isolated crystalline product after methanol synthesis and slow evaporation.

Atmosphere
open atmosphere crystallisation
Context
pristine heterobimetallic CP
Measurement source
2 · Experimental Section - Synthesis
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
calculated carbon elemental analysisC, 34.06%——Text
Exact Reported		2 · Experimental Section - Synthesis
found carbon elemental analysisC, 33.9%——Text
Exact Reported		2 · Experimental Section - Synthesis
formula weightFW = 740.46——Text
Exact Reported		2 · Experimental Section - Synthesis
isolated crystalline product yield518 mg (70%)——Text
Exact Reported		2 · Experimental Section - Synthesis

Thermogravimetric analysis

Thermogravimetric analysis

Powdered/bulk [(NCS)Pb(H2O)LNi(NCS)]n · Powder

Dynamic nitrogen atmosphere, 20 mL min^-1; heating rate 10 deg C min^-1.

Atmosphere
dynamic nitrogen
Context
pristine CP
Measurement source
S9-S10 · Thermo-gravimetric analysis · Figure S8
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
dehydrated complex stability limit~230 deg C——Text
Approximate		S9-S10 · Thermo-gravimetric analysis · Figure S8
TGA heating rate10 deg C min^-1——Text
Exact Reported		S9-S10 · Thermo-gravimetric analysis · Figure S8
TGA nitrogen flow rate20 mL min^-1——Text
Exact Reported		S9-S10 · Thermo-gravimetric analysis · Figure S8
hydrated complex stability limit~80 deg C——Text
Approximate		S9-S10 · Thermo-gravimetric analysis · Figure S8
water-loss mass loss2.23% from 50-80 deg C——Text
Exact Reported		S9-S10 · Thermo-gravimetric analysis · Figure S8
calculated water-loss mass losscalc. 2.21%——Text
Exact Reported		S9-S10 · Thermo-gravimetric analysis · Figure S8