Complete recipeSource: Both
Route 1: Other
2 · Experimental Section - Synthesis · Scheme 1
Metal precursorslead(II) nitrate; nickel(II) thiocyanate tetrahydrate
Linker precursorsH2L from 3-methoxysalicylaldehyde and 1,3-diaminopropane, used in situ
Solventsmethanol (20 mL ligand step; 10 mL Pb solution; 10 mL Ni solution)
Atmosphereopen atmosphere for slow evaporation; other steps not specified
Temperaturereflux for ligand step; room-temperature stirring/crystallisation after metal addition (not explicitly stated)
Timeca. 1 h reflux; 15 min after Pb addition; about 2 h after Ni addition; 3-4 days slow evaporation
Work-upLigand not isolated; solution slow-evaporated in open atmosphere; X-ray quality crystals isolated.
Scalability contextAuthors state they are working to get better yield and develop more systems based on this strategy.
Show 5 structured reagent records
| Role | Reagent | Amount / concentration | Source |
|---|---|---|---|
| Linker | 3-Methoxysalicylaldehyde | 304 mg, 2 mmol | 2 · Experimental Section - Synthesis · Scheme 1 |
| Linker | 1,3-diaminopropane | 0.13 mL, 1 mmol | 2 · Experimental Section - Synthesis · Scheme 1 |
| Solvent | methanol | 20 mL for ligand step; 40 mL total including metal solutions | 2 · Experimental Section - Synthesis · Scheme 1 |
| Metal Source | lead(II) nitrate | 332 mg, 1 mmol | 2 · Experimental Section - Synthesis · Scheme 1 |
| Metal Source | nickel(II) thiocyanate tetrahydrate | 250 mg, 1 mmol | 2 · Experimental Section - Synthesis · Scheme 1 |