Measurement evidence
Continuous and reversible tuning of inter-layer spacings in two-dimensional conductive metal organic frameworks · Dontireddy G.M.R., Suman S.P., Merino-Gardea J.L. et al. · Journal of Materials Chemistry A · 2025 · 8734-8741
Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.
Cu3HHTT2 multi-sample comparison series · Powder
Pristine Cu3HHTT2 compared with heat-treated Cu3HHTT2 at 90 deg C.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| Cu3HHTT2 PXRD after heating | No notable changes to diffraction patterns after 90 deg C heat treatment. | — | — | Text Qualitative | p005 · Solvent removal in Ni6HHTT3 · Fig. S14 |
Ga9HHTP4 multi-sample comparison series · Powder
FWHM compared for in-plane 4.7 deg peak and inter-layer-stacking 25.8 deg peak.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| Ga9HHTP4 acetonitrile-soaked FWHM at 25.8 deg inter-layer peak | ~1.55 deg 2theta | — | visual estimate | Figure Axis Approximate | p029 · Figure S23 · Fig. S23b |
| Ga9HHTP4 pristine FWHM at 25.8 deg inter-layer peak | ~0.36 deg 2theta | — | visual estimate | Figure Axis Approximate | p029 · Figure S23 · Fig. S23b |
| Ga9HHTP4 water-soaked FWHM at 25.8 deg inter-layer peak | ~0.80 deg 2theta | — | visual estimate | Figure Axis Approximate | p006 · Discussion · Fig. S23b |
Pristine Ga9HHTP4 powder · Powder
As-synthesised powder compared with simulated PXRD pattern.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| Ga9HHTP4 phase purity | Experimental PXRD matched simulated pattern; high crystallinity and phase purity. | — | — | Text Qualitative | p002 · Results · Fig. S1 |
Ga9HHTP4 multi-sample comparison series · Powder
Heat-treated Ga9HHTP4 soaked in water or organic solvents overnight, then compared by PXRD.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| Organic solvent-exchanged Ga9HHTP4 inter-layer spacing range | 3.29-3.35 Angstrom | — | range | Text Range | p004 · Solvent removal/exchange in Ga9HHTP4 · Fig. 2b,c and Fig. S10 |
| Water-soaked HT-Ga9HHTP4 inter-layer spacing | from 3.27 to 3.42 Angstrom | — | — | Text Exact Reported | p003 · Solvent removal/exchange in Ga9HHTP4 · Fig. 2b,c and Fig. S8 |
Heat-treated Ga9HHTP4 (HT-Ga9HHTP4) · Powder
Ga9HHTP4 under reduced pressure; 30 min vacuum at room temperature, then stepwise heating to 85 deg C.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| Heat-treated Ga9HHTP4 inter-layer spacing | 3.27 Angstrom after shift to 27.2 deg | — | — | Text Exact Reported | p003 · Solvent removal/exchange in Ga9HHTP4 · Fig. 1e |
| Pristine Ga9HHTP4 inter-layer spacing | 3.45 Angstrom | — | — | Text Exact Reported | p003 · Solvent removal/exchange in Ga9HHTP4 · Fig. 1e |
Pristine Ni6HHTT3 powder · Powder
As-synthesised powder compared with simulated PXRD pattern.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| Ni6HHTT3 phase purity | Experimental PXRD matched simulated pattern; high crystallinity and phase purity. | — | — | Caption Qualitative | p007 · Figure S1 · Fig. S1 |
Heat-treated Ni6HHTT3 · Powder
Ni6HHTT3 under reduced pressure at room temperature and upon heating to 90 deg C.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| Heat-treated Ni6HHTT3 inter-layer spacing | 3.28(6) Angstrom | — | (6) | Text Exact Reported | p005 · Solvent removal in Ni6HHTT3 · Fig. 3c |
| Pristine Ni6HHTT3 inter-layer spacing | 3.30(2) Angstrom | — | (2) | Text Exact Reported | p005 · Solvent removal in Ni6HHTT3 · Fig. 3c |