cMOF Evidence Base
Other — NH2-UiO-66 Metal-Organic Framework Nanoparticles for Hydroxide Ion Conductive Photoswitches

Measurement evidence

Other

NH2-UiO-66 Metal-Organic Framework Nanoparticles for Hydroxide Ion Conductive Photoswitches · Wang S., Fan S., Fang Z. et al. · ACS Applied Nano Materials · 2021 · 8352-8359

4 measurement groups · 8 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Infrared photography under visible light from xenon lamp

NH2-UiO-66-10 · Powder

Powder exposed to visible light at 50 mW cm^-2; temperature recorded from room temperature to 10 min illumination.

Geometry
powder sample under xenon lamp
Context
pristine framework powder
Measurement source
p003 · Results · Figure 2b
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
powder temperature after visible-light illumination48.3 deg C after 10 min321.45 K—Text
Exact Reported		p003 · Results · Figure 2b
initial powder temperature under visible-light test26 deg C299.15 K—Text
Exact Reported		p003 · Results · Figure 2b

Temperature evolution under xenon-lamp irradiation

NH2-UiO-66-50 · Powder

Temperature as a function of irradiation time for NH2-UiO-66-10 and NH2-UiO-66-50 powders.

Geometry
powder under xenon lamp
Context
pristine framework powders
Measurement source
p002 · Additional figures · Figure S2b
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
NH2-UiO-66-50 temperature after 10 min xenon-lamp irradiation~45 deg C after 10 min318.15 K—Figure Axis
Approximate		p002 · Additional figures · Figure S2b

Thermogravimetric analysis after activation

Thermogravimetric analysis

activated NH2-UiO-66-10 · Powder

TG curves of activated NH2-UiO-66-10 and NH2-UiO-66-50 from ca. 40 to 800 deg C.

Context
activated pristine powders
Measurement source
p005 · Additional figures · Figure S5
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
activated NH2-UiO-66-10 mass remaining at 80 deg C~99 wt%99 wt%—Figure Axis
Approximate		p005 · Additional figures · Figure S5
activated NH2-UiO-66-50 mass remaining at 800 deg C~52 wt%52 wt%—Figure Axis
Approximate		p005 · Additional figures · Figure S5

Thermogravimetric analysis (PE TGA)

Thermogravimetric analysis

fully hydrated NH2-UiO-66-10 · Powder

Fully hydrated NH2-UiO-66-10 heated; compared in text with activated NH2-UiO-66-10 (SI Figure S5 missing).

Context
hydrated framework powder
Measurement source
p005-p006 · Results; Methods · Figure 5c
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
hydrogen-bond energy cited for water network2-3 kcal mol^-1 (~0.11 eV)——Text
Range		p005 · Results
hydrated NH2-UiO-66-10 TGA plateau range80-220 deg C——Text
Range		p005 · Results · Figure 5c
hydrated NH2-UiO-66-10 mass loss to 80 deg C~18%18 wt%—Text
Approximate		p005 · Results · Figure 5c