cMOF Evidence Base

Synthesis evidence

NH2-UiO-66 Metal-Organic Framework Nanoparticles for Hydroxide Ion Conductive Photoswitches

Wang S., Fan S., Fang Z. et al. · ACS Applied Nano Materials · 2021 · 8352-8359

9 structured synthesis routes

Completeness describes how fully the route could be reconstructed from the main article and supporting information.

Partial recipeSource: Main

Route 1: Other

p006 · Methods - Hydroxide Ion Conductivity Measurement

Metal precursorsas-synthesised NH2-UiO-66 nanoparticles
Linker precursors2-amino-terephthalate framework already formed
Solvents1 mM aqueous KOH
AdditivesKOH hydroxide source
Time24
Work-uppellets equilibrated in constant temperature/humidity environment for 2 h before measurement
Activationpressed into pellets at 20 MPa for 10 s; Ag electrodes evaporated; KOH immersion introduced hydroxide ions
Show 3 structured reagent records
RoleReagentAmount / concentrationSource
Otheras-synthesized NH2-UiO-66 nanoparticlesNot specifiedp006 · Methods - Hydroxide Ion Conductivity Measurement
BaseKOH aqueous solution1 mMp006 · Methods - Hydroxide Ion Conductivity Measurement
Othersilver electrodesNot specifiedp006 · Methods - Hydroxide Ion Conductivity Measurement
Partial recipeSource: Main

Route 2: Solvothermal

p002-p006 · Result and Discussion; Methods

Metal precursorszirconium tetrachloride (ZrCl4)
Linker precursors2-amino-terephthalic acid (H2ATA)
SolventsN,N-dimethylformamide (DMF)
Additivesacetic acid, 0 equiv relative to ZrCl4
Temperature120
Time24
Work-upnot reported in supplied main text
Activationnot reported in supplied main text
Show 4 structured reagent records
RoleReagentAmount / concentrationSource
Metal Sourcezirconium tetrachloride (ZrCl4, 98%, Aladdin)Not specifiedp002-p006 · Result and Discussion; Methods
LinkerH2ATA (98%, Aladdin)Not specifiedp002-p006 · Result and Discussion; Methods
SolventDMF [HCON(CH3)2, Sigma-Aldrich]Not specifiedp002-p006 · Result and Discussion; Methods
Acidacetic acid (CH3COOH)0 equivp002-p006 · Result and Discussion; Methods
Partial recipeSource: Main

Route 3: Other

p006 · Methods - Hydroxide Ion Conductivity Measurement

Metal precursorsas-synthesised NH2-UiO-66 nanoparticles
Linker precursors2-amino-terephthalate framework already formed
Solvents1 mM aqueous KOH
AdditivesKOH hydroxide source
Time24
Work-uppellets equilibrated in constant temperature/humidity environment for 2 h before measurement
Activationpressed into pellets at 20 MPa for 10 s; Ag electrodes evaporated; KOH immersion introduced hydroxide ions
Show 3 structured reagent records
RoleReagentAmount / concentrationSource
Otheras-synthesized NH2-UiO-66 nanoparticlesNot specifiedp006 · Methods - Hydroxide Ion Conductivity Measurement
BaseKOH aqueous solution1 mMp006 · Methods - Hydroxide Ion Conductivity Measurement
Othersilver electrodesNot specifiedp006 · Methods - Hydroxide Ion Conductivity Measurement
Partial recipeSource: Main

Route 4: Solvothermal

p002-p006 · Result and Discussion; Methods

Metal precursorszirconium tetrachloride (ZrCl4)
Linker precursors2-amino-terephthalic acid (H2ATA)
SolventsN,N-dimethylformamide (DMF)
Additivesacetic acid, 100 equiv relative to ZrCl4
Temperature120
Time24
Work-upnot reported in supplied main text
Activationnot reported in supplied main text
Show 4 structured reagent records
RoleReagentAmount / concentrationSource
Metal Sourcezirconium tetrachloride (ZrCl4, 98%, Aladdin)Not specifiedp002-p006 · Result and Discussion; Methods
LinkerH2ATA (98%, Aladdin)Not specifiedp002-p006 · Result and Discussion; Methods
SolventDMF [HCON(CH3)2, Sigma-Aldrich]Not specifiedp002-p006 · Result and Discussion; Methods
Acidacetic acid (CH3COOH)100 equivp002-p006 · Result and Discussion; Methods
Partial recipeSource: Main

Route 5: Solvothermal

p002-p006 · Result and Discussion; Methods

Metal precursorszirconium tetrachloride (ZrCl4)
Linker precursors2-amino-terephthalic acid (H2ATA)
SolventsN,N-dimethylformamide (DMF)
Additivesacetic acid, 10 equiv relative to ZrCl4
Temperature120
Time24
Work-upnot reported in supplied main text
Activationnot reported in supplied main text
Show 4 structured reagent records
RoleReagentAmount / concentrationSource
Metal Sourcezirconium tetrachloride (ZrCl4, 98%, Aladdin)Not specifiedp002-p006 · Result and Discussion; Methods
LinkerH2ATA (98%, Aladdin)Not specifiedp002-p006 · Result and Discussion; Methods
SolventDMF [HCON(CH3)2, Sigma-Aldrich]Not specifiedp002-p006 · Result and Discussion; Methods
Acidacetic acid (CH3COOH)10 equivp002-p006 · Result and Discussion; Methods
Partial recipeSource: Main

Route 6: Other

p006 · Methods - Hydroxide Ion Conductivity Measurement

Metal precursorsas-synthesised NH2-UiO-66 nanoparticles
Linker precursors2-amino-terephthalate framework already formed
Solvents1 mM aqueous KOH
AdditivesKOH hydroxide source
Time24
Work-uppellets equilibrated in constant temperature/humidity environment for 2 h before measurement
Activationpressed into pellets at 20 MPa for 10 s; Ag electrodes evaporated; KOH immersion introduced hydroxide ions
Show 3 structured reagent records
RoleReagentAmount / concentrationSource
Otheras-synthesized NH2-UiO-66 nanoparticlesNot specifiedp006 · Methods - Hydroxide Ion Conductivity Measurement
BaseKOH aqueous solution1 mMp006 · Methods - Hydroxide Ion Conductivity Measurement
Othersilver electrodesNot specifiedp006 · Methods - Hydroxide Ion Conductivity Measurement
Partial recipeSource: Main

Route 7: Solvothermal

p002-p006 · Result and Discussion; Methods

Metal precursorszirconium tetrachloride (ZrCl4)
Linker precursors2-amino-terephthalic acid (H2ATA)
SolventsN,N-dimethylformamide (DMF)
Additivesacetic acid, 50 equiv relative to ZrCl4
Temperature120
Time24
Work-upnot reported in supplied main text
Activationnot reported in supplied main text
Show 4 structured reagent records
RoleReagentAmount / concentrationSource
Metal Sourcezirconium tetrachloride (ZrCl4, 98%, Aladdin)Not specifiedp002-p006 · Result and Discussion; Methods
LinkerH2ATA (98%, Aladdin)Not specifiedp002-p006 · Result and Discussion; Methods
SolventDMF [HCON(CH3)2, Sigma-Aldrich]Not specifiedp002-p006 · Result and Discussion; Methods
Acidacetic acid (CH3COOH)50 equivp002-p006 · Result and Discussion; Methods
Partial recipeSource: Main

Route 8: Other

p006 · Methods - Hydroxide Ion Conductivity Measurement

Metal precursorsas-synthesised NH2-UiO-66 nanoparticles
Linker precursors2-amino-terephthalate framework already formed
Solvents1 mM aqueous KOH
AdditivesKOH hydroxide source
Time24
Work-uppellets equilibrated in constant temperature/humidity environment for 2 h before measurement
Activationpressed into pellets at 20 MPa for 10 s; Ag electrodes evaporated; KOH immersion introduced hydroxide ions
Show 3 structured reagent records
RoleReagentAmount / concentrationSource
Otheras-synthesized NH2-UiO-66 nanoparticlesNot specifiedp006 · Methods - Hydroxide Ion Conductivity Measurement
BaseKOH aqueous solution1 mMp006 · Methods - Hydroxide Ion Conductivity Measurement
Othersilver electrodesNot specifiedp006 · Methods - Hydroxide Ion Conductivity Measurement
Vague recipeSource: Main

Route 9: Solvothermal

p006 · Methods - Synthesis of NH2-UiO-66 and UiO-66 Powders

Metal precursorszirconium tetrachloride (ZrCl4)
Linker precursorsterephthalic acid (H2BDC)
SolventsN,N-dimethylformamide (DMF)
Additivesacetic acid modulator by same method; exact amount not specified
Temperature120
Time24
Work-upnot reported in supplied main text
Activationnot reported in supplied main text
Show 4 structured reagent records
RoleReagentAmount / concentrationSource
Metal Sourcezirconium tetrachloride (ZrCl4, 98%, Aladdin)Not specifiedp006 · Methods - Synthesis of NH2-UiO-66 and UiO-66 Powders
Linkerterephthalic acid (H2BDC, 99%, Aladdin)Not specifiedp006 · Methods - Synthesis of NH2-UiO-66 and UiO-66 Powders
SolventDMF [HCON(CH3)2, Sigma-Aldrich]Not specifiedp006 · Methods - Synthesis of NH2-UiO-66 and UiO-66 Powders
Acidacetic acid (CH3COOH)Not specifiedp006 · Methods - Synthesis of NH2-UiO-66 and UiO-66 Powders