Other — Three-type precursors for low-temperature solution-processed void-and-crack-free copper(I) iodide films: comparison of electrical conductivities and optical transparency

4 measurement groups · 21 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Isolated CuI-1A2P powdery solid · Powder

Experimental and calculated C/H/N percentages for the isolated CuI-1A2P complex formula.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Isolated CuI-1A2P calculated carbon	25.89%	—	—	SI Table Exact Reported	SI p012 · Supporting Information · Table S2
Isolated CuI-1A2P experimental carbon	25.95%	—	—	SI Table Exact Reported	SI p012 · Supporting Information · Table S2
Isolated CuI-1A2P calculated hydrogen	6.29%	—	—	SI Table Exact Reported	SI p012 · Supporting Information · Table S2
Isolated CuI-1A2P experimental hydrogen	6.17%	—	—	SI Table Exact Reported	SI p012 · Supporting Information · Table S2
Isolated CuI-1A2P calculated nitrogen	10.13%	—	—	SI Table Exact Reported	SI p012 · Supporting Information · Table S2
Isolated CuI-1A2P experimental nitrogen	10.10%	—	—	SI Table Exact Reported	SI p012 · Supporting Information · Table S2

CuI(1A2P) film on glass · Thin Film

CuI dissolved in AN, DES, 2ME/2AE, 2ME/1A2P, or 2ME/2AM1P at 0.13-0.70 mol L-1; alkanolamine/CuI = 5 mol/mol for alkanolamine systems.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
CuI-1A2P precursor ratio series documented in SI	1A2P/CuI ratios 1, 1.1, 1.15, 1.2, 1.5, 2, 3, 4 at 0.26 M	—	—	SI Table Exact Reported	SI p003 · Supporting Information · Table S1
Alkanolamine saturated-concentration order	2AE > 1A2P > 2AM1P	—	—	Text Qualitative	4 · 3.1 CuI precursor solutions · Fig. 2
CuI in AN shows undissolved solids above concentration	>0.25 mol L-1	—	—	Text Approximate	3 · 3.1 CuI precursor solutions
DES precursor solutions transparent over concentration range	0.70 to 0.13 mol L-1	—	—	Text Range	3 · 3.1 CuI precursor solutions
No CuI dissolution or colour change in nitrogen glovebox	dissolution and colour change did not occur in N2-filled glove box	—	—	Text Qualitative	4 · 3.1 CuI precursor solutions · Supplementary Fig. S3

Isolated CuI-1A2P powdery solid · Powder

Isolated CuI-1A2P complex heated in dry air at 10 deg C min-1 to 600 deg C for TG-DTA; photographs at 80-120 deg C with 1.7 deg C min-1 heating rate.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
CuI-1A2P complete melting temperature	120 deg C	—	—	Text Exact Reported	6 · 3.3 Isolated powdery solid of CuI-1A2P complex · Fig. 6
Cu:1A2P ratio in isolated complex	approximately 1:2	—	—	Text Approximate	6 · 3.3 Isolated powdery solid of CuI-1A2P complex
Isolated CuI-1A2P complex formula	CuI(C3H8NO)(C3H9NO)1.4.(2ME)0.57(toluene)0.08	—	—	Text Exact Reported	6 · 3.3 Isolated powdery solid of CuI-1A2P complex · Supplementary Table S2
CuI-1A2P decomposition to CuIMarked as a best value within this paper	132 deg C	—	—	Text Exact Reported	6 · 3.3 Isolated powdery solid of CuI-1A2P complex · Supplementary Fig. S14b
CuI-1A2P liquid phase disappearance	130 deg C	—	—	Text Exact Reported	6 · 3.3 Isolated powdery solid of CuI-1A2P complex · Fig. 6
CuI-1A2P slight melting temperature	100 deg C	—	—	Text Exact Reported	6 · 3.3 Isolated powdery solid of CuI-1A2P complex · Fig. 6
CuI oxidation to CuO	420 deg C	—	—	Text Exact Reported	6 · 3.3 Isolated powdery solid of CuI-1A2P complex · Supplementary Fig. S14c
CuI-1A2P solvent release temperature	below 120 deg C	—	—	Text Approximate	6 · 3.3 Isolated powdery solid of CuI-1A2P complex · Supplementary Fig. S13

Isolated CuI-2AE powdery solid · Powder

Isolated CuI-2AE complex thermal melting/decomposition compared with CuI-1A2P complex.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
CuI-2AE thermal decomposition temperature	>141 deg C	—	—	Text Approximate	6 · 3.3 Isolated powdery solid of CuI-1A2P complex · Supplementary Figs. S15 and S16
CuI-2AE melting temperature	>100 deg C	—	—	Text Approximate	6 · 3.3 Isolated powdery solid of CuI-1A2P complex · Supplementary Figs. S15 and S16