Electrochemistry Application — Effects of intervalence charge transfer interaction between π-stacked mixed valent tetrathiafulvalene ligands on the electrical conductivity of 3D metal-organic frameworks

8 measurement groups · 16 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

solid-state cyclic voltammetry

Voltammetry

Cs-MOF 4 · Powder

MOF suspension drop-cast on Pt-disc working electrode; 0.1 M TBAPF6/MeCN; Ag/AgCl reference, Pt counter electrode.

Geometry: drop-cast MOF thin film on Pt-disc electrode
Context: pristine framework sample state
Measurement source: S2 · General Materials and Methods

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
first anodic oxidation peak	~170 mV vs Ag/AgCl	—	—	Text Approximate	13385 · Electrochemical behavior of TTFTC ligand and MOFs · Fig. 4
second anodic oxidation peak	~550 mV vs Ag/AgCl	—	—	Text Approximate	13385 · Electrochemical behavior of TTFTC ligand and MOFs · Fig. 4

solid-state cyclic voltammetry

Voltammetry

K-MOF 2 · Powder

MOF suspension drop-cast on Pt-disc working electrode; 0.1 M TBAPF6/MeCN; Ag/AgCl reference, Pt counter electrode.

Geometry: drop-cast MOF thin film on Pt-disc electrode
Context: pristine framework sample state
Measurement source: S2 · General Materials and Methods

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
first anodic oxidation peak	~200 mV vs Ag/AgCl	—	—	Text Approximate	13385 · Electrochemical behavior of TTFTC ligand and MOFs · Fig. 4
second anodic oxidation peak	~600 mV vs Ag/AgCl	—	—	Text Approximate	13385 · Electrochemical behavior of TTFTC ligand and MOFs · Fig. 4

solid-state cyclic voltammetry

Voltammetry

K-MOF 2-ox · Powder

MOF suspension drop-cast on Pt-disc working electrode; 0.1 M TBAPF6/MeCN; Ag/AgCl reference, Pt counter electrode.

Geometry: drop-cast MOF thin film on Pt-disc electrode
Context: pristine framework sample state
Measurement source: S2 · General Materials and Methods

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
first anodic oxidation peak	~200 mV vs Ag/AgCl	—	—	Text Approximate	13385 · Electrochemical behavior of TTFTC ligand and MOFs · Fig. 4
second anodic oxidation peak	~600 mV vs Ag/AgCl	—	—	Text Approximate	13385 · Electrochemical behavior of TTFTC ligand and MOFs · Fig. 4

solution-phase cyclic voltammetry

Voltammetry

TTFTC-H4 ligand · Powder

0.2 mM ligand in 0.1 M TBAPF6/MeCN; glassy carbon working, Ag/AgCl reference, Pt counter electrode.

Geometry: solution CV
Context: molecular ligand control
Measurement source: S2/S8 · General Materials and Methods · Fig. S6

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
first oxidation potential	580 mV	—	—	Text Rounded Reported	13384 · Electrochemical behavior of TTFTC ligand and MOFs · Fig. S6
second oxidation potential	980 mV	—	—	Text Rounded Reported	13384 · Electrochemical behavior of TTFTC ligand and MOFs · Fig. S6

solution-phase cyclic voltammetry

Voltammetry

TTFTC-Me4 ligand · Powder

0.2 mM ligand in 0.1 M TBAPF6/MeCN; glassy carbon working, Ag/AgCl reference, Pt counter electrode.

Geometry: solution CV
Context: molecular ligand control
Measurement source: S2/S8 · General Materials and Methods · Fig. S6

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
first oxidation potential	880 mV	—	—	Text Rounded Reported	13384 · Electrochemical behavior of TTFTC ligand and MOFs · Fig. S6
second oxidation potential	1180 mV	—	—	Text Rounded Reported	13384 · Electrochemical behavior of TTFTC ligand and MOFs · Fig. S6

solid-state cyclic voltammetry

Voltammetry

Na-MOF 1-ox · Powder

MOF suspension drop-cast on Pt-disc working electrode; 0.1 M TBAPF6/MeCN; Ag/AgCl reference, Pt counter electrode.

Geometry: drop-cast MOF thin film on Pt-disc electrode
Context: pristine framework sample state
Measurement source: S2 · General Materials and Methods

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
first anodic oxidation peak	~200 mV vs Ag/AgCl	—	—	Text Approximate	13385 · Electrochemical behavior of TTFTC ligand and MOFs · Fig. 4
second anodic oxidation peak	~620 mV vs Ag/AgCl	—	—	Text Approximate	13385 · Electrochemical behavior of TTFTC ligand and MOFs · Fig. 4

solid-state cyclic voltammetry

Voltammetry

Rb-MOF 3 · Powder

MOF suspension drop-cast on Pt-disc working electrode; 0.1 M TBAPF6/MeCN; Ag/AgCl reference, Pt counter electrode.

Geometry: drop-cast MOF thin film on Pt-disc electrode
Context: pristine framework sample state
Measurement source: S2 · General Materials and Methods

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
first anodic oxidation peak	~170 mV vs Ag/AgCl	—	—	Text Approximate	13385 · Electrochemical behavior of TTFTC ligand and MOFs · Fig. 4
second anodic oxidation peak	~550 mV vs Ag/AgCl	—	—	Text Approximate	13385 · Electrochemical behavior of TTFTC ligand and MOFs · Fig. 4

solid-state cyclic voltammetry

Voltammetry

Rb-MOF 3-ox · Powder

MOF suspension drop-cast on Pt-disc working electrode; 0.1 M TBAPF6/MeCN; Ag/AgCl reference, Pt counter electrode.

Geometry: drop-cast MOF thin film on Pt-disc electrode
Context: pristine framework sample state
Measurement source: S2 · General Materials and Methods

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
first anodic oxidation peak	~170 mV vs Ag/AgCl	—	—	Text Approximate	13385 · Electrochemical behavior of TTFTC ligand and MOFs · Fig. 4
second anodic oxidation peak	~550 mV vs Ag/AgCl	—	—	Text Approximate	13385 · Electrochemical behavior of TTFTC ligand and MOFs · Fig. 4