Other — Effects of intervalence charge transfer interaction between π-stacked mixed valent tetrathiafulvalene ligands on the electrical conductivity of 3D metal-organic frameworks

4 measurement groups · 4 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Cs-MOF 4 · Powder

TGA under N2 atmosphere using SDT Q600; all four MOFs lose ca. 5-10 wt% below 100-150 °C and plateau until ca. 300 °C.

Atmosphere: N2
Geometry: powder TGA
Context: pristine framework sample state
Measurement source: S2/S7 · General Materials and Methods; Fig. S3 · Fig. S3

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
thermal stability / initial solvent loss	ca. 5-10 wt% loss up to 100-150 °C; stable plateau until ca. 300 °C	—	—	Text Range	13383 · Thermogravimetric analysis and porosity measurements · Fig. S3

K-MOF 2 · Powder

TGA under N2 atmosphere using SDT Q600; all four MOFs lose ca. 5-10 wt% below 100-150 °C and plateau until ca. 300 °C.

Atmosphere: N2
Geometry: powder TGA
Context: pristine framework sample state
Measurement source: S2/S7 · General Materials and Methods; Fig. S3 · Fig. S3

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
thermal stability / initial solvent loss	ca. 5-10 wt% loss up to 100-150 °C; stable plateau until ca. 300 °C	—	—	Text Range	13383 · Thermogravimetric analysis and porosity measurements · Fig. S3

Na-MOF 1-ox · Powder

TGA under N2 atmosphere using SDT Q600; all four MOFs lose ca. 5-10 wt% below 100-150 °C and plateau until ca. 300 °C.

Atmosphere: N2
Geometry: powder TGA
Context: pristine framework sample state
Measurement source: S2/S7 · General Materials and Methods; Fig. S3 · Fig. S3

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
thermal stability / initial solvent loss	ca. 5-10 wt% loss up to 100-150 °C; stable plateau until ca. 300 °C	—	—	Text Range	13383 · Thermogravimetric analysis and porosity measurements · Fig. S3

Rb-MOF 3 · Powder

TGA under N2 atmosphere using SDT Q600; all four MOFs lose ca. 5-10 wt% below 100-150 °C and plateau until ca. 300 °C.

Atmosphere: N2
Geometry: powder TGA
Context: pristine framework sample state
Measurement source: S2/S7 · General Materials and Methods; Fig. S3 · Fig. S3

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
thermal stability / initial solvent loss	ca. 5-10 wt% loss up to 100-150 °C; stable plateau until ca. 300 °C	—	—	Text Range	13383 · Thermogravimetric analysis and porosity measurements · Fig. S3