Complete recipeSource: Both
Route 1: Other
S4-S5 · Material Synthesis and Characterization
Metal precursors0.5 M CsOH solution (0.15 mL)
Linker precursorsTTFTC-Me4 (5 mg, 0.0115 mmol), converted by in situ saponification
Solvents1:2 THF/MeOH mixture (1.5 mL) in inner vial; 1:1 THF/MeOH (5 mL) in outer vial for vapour diffusion
AdditivesCsOH base
Atmosphereambient in screw-capped vial
Temperature20
Time72
Oxidant / reductantnone; material remained unchanged on air exposure
Work-upfiltered, rinsed with MeCN three times, soaked in MeCN for 12 h
Activationfiltered and dried under vacuum for 24 h
Scalability context5 mL inner vial/20 mL outer vial vapour-diffusion crystal synthesis; yield 10.91 mg (84%).
Show 5 structured reagent records
| Role | Reagent | Amount / concentration | Source |
|---|---|---|---|
| Linker | TTFTC-Me4 | 5 mg, 0.0115 mmol | S4-S5 · Material Synthesis and Characterization |
| Base | CsOH solution | 0.15 mL · 0.5 M | S4-S5 · Material Synthesis and Characterization |
| Solvent | THF/MeOH inner solution | 1.5 mL · 1:2 mixture | S4-S5 · Material Synthesis and Characterization |
| Solvent | THF/MeOH outer vapour reservoir | 5 mL · 1:1 mixture | S4-S5 · Material Synthesis and Characterization |
| Solvent | MeCN | rinse three times; soak 12 h | S4-S5 · Material Synthesis and Characterization |