cMOF Evidence Base

Synthesis evidence

Fe–O–Zr in MOF for effective photo-Fenton Bisphenol A degradation: Boosting mechanism of electronic transmission

Guan Z., Zhu S., Ding S. et al. · Chemosphere · 2022 · 134481

4 structured synthesis routes

Completeness describes how fully the route could be reconstructed from the main article and supporting information.

Partial recipeSource: SI

Route 1: Drop Cast

Text S4 Electrochemical analysis tests

Metal precursorsFeUiO-1 powder
Solventsethanol
AdditivesNafion solution (5.0 wt%)
Atmospherevacuum drying after coating; coating atmosphere not reported
Temperature60
Time8
Substrate orientationFTO electrode
Work-upUltrasonic dispersion for 3 h; 60 uL suspension dropped onto FTO.
ActivationVacuum dried at 60 C for 8 h.
Show 3 structured reagent records
RoleReagentAmount / concentrationSource
OtherFeUiO-1 powder5 mgText S4 Electrochemical analysis tests
AdditiveNafion solution0.01 mL · 5.0 wt%Text S4 Electrochemical analysis tests
Solventethanol0.1 mLText S4 Electrochemical analysis tests
Partial recipeSource: Both

Route 2: Other

3 · 2.2 Preparation of materials

Metal precursorsUiO-66; FeSO4
Linker precursorsBDC already present in UiO-66
Solventsmethanol
Atmospherenot reported
Oxidant / reductantFeSO4 used as Fe source
Work-upHeated in a water bath until evaporation, dried in an oven, removed, washed to remove excess iron from the surface, and dried again until complete.
ActivationOven drying after washing; temperature/time not reported in main text.
Show 3 structured reagent records
RoleReagentAmount / concentrationSource
OtherUiO-660.5 g3 · 2.2 Preparation of materials
Metal SourceFeSO40.05 g, 0.1 g, 0.5 g, 1 g, or 2 g3 · 2.2 Preparation of materials
Solventmethanol (CH3OH, >=99.0%)Not specified3 · 2.2 Preparation of materials
Partial recipeSource: SI

Route 3: Drop Cast

Text S4 Electrochemical analysis tests

Metal precursorsUiO-66 powder
Solventsethanol
AdditivesNafion solution (5.0 wt%)
Atmospherevacuum drying after coating; coating atmosphere not reported
Temperature60
Time8
Substrate orientationFTO electrode
Work-upUltrasonic dispersion for 3 h; 60 uL suspension dropped onto FTO.
ActivationVacuum dried at 60 C for 8 h.
Show 3 structured reagent records
RoleReagentAmount / concentrationSource
OtherUiO-66 powder5 mgText S4 Electrochemical analysis tests
AdditiveNafion solution0.01 mL · 5.0 wt%Text S4 Electrochemical analysis tests
Solventethanol0.1 mLText S4 Electrochemical analysis tests
Partial recipeSource: Both

Route 4: Solvothermal

3 · 2.2 Preparation of materials

Metal precursorszirconium chloride
Linker precursorsterephthalic acid
SolventsDMF
Atmospherenot reported
Temperature120
Time24
Work-upCentrifuged, washed twice with water and once with methanol.
ActivationDried overnight in an oven at 70 C.
Show 3 structured reagent records
RoleReagentAmount / concentrationSource
Metal SourceZirconium(IV) chloride (ZrCl4, 98%)0.2 mmol3 · 2.2 Preparation of materials
Linkerbenzene dicarboxylic acid / terephthalic acid (C8H6O4, 99%)0.2 mmol3 · 2.2 Preparation of materials
SolventDMF30 mL3 · 2.2 Preparation of materials