Jiang X., Yao T., Wang S. et al. · Sensors and Actuators B: Chemical · 2024 · 135410
Open a family to keep every result attached to its sample, method and conditions.
Paraphrased for this database from the authors’ stated interpretations — never quoted verbatim — and kept separate from reported measurements.
The hydrophilic ST-HA hydrogel coating provides superior antifouling performance in real serum compared with bare and BSA-modified GCE.
Caveat: Only the 100% serum gel contamination value is reported exactly in text; other gel and BSA bars are not numerically tabulated.
7 · 3.5 Antifouling performance · Fig. 4 · Linked to 3 structured results
Spike recovery results indicate the proposed immunosensor is suitable for SCCA detection in real serum samples.
Caveat: Clinical serum comparison table S1 is mentioned but the SI text layer does not include the table body.
8 · 3.9 Application · Table 2 · Linked to 2 structured results
The CuFe-MOF immunoprobe/hydrogel immunosensor enables fg mL-1-level SCCA detection over a broad linear range.
Caveat: Application sensing performance, not an intrinsic transport property of the MOF.
7 · 3.7 Analytical performance · Fig. 5; Table 1 · Linked to 4 structured results
No first-hand direct electrical transport, thermoelectric or porosity measurements for pristine CuFe-MOF were reported.
Caveat: The conductive role is assessed only through electrochemical behaviour of composite electrodes and qualitative discussion.
5 · 3.4 Electrochemical characterization · Fig. 3A,B
The planar conjugated BDC ligand and 2D MOF nanosheet architecture are proposed to improve conductivity at the antifouling sensing interface.
Caveat: The paper does not report a direct electrical conductivity, resistivity, mobility or thermoelectric measurement for CuFe-MOF.
1 · Abstract · Linked to 1 structured result
Fe-Cu bimetallic sites are claimed to promote electron transfer from Cu(I) to Fe(III), accelerate Fe(III)/Fe(II) conversion and enhance Fenton-like catalytic activity.
Caveat: Mechanistic hydroxyl-radical/electron-transfer claim is inferred from catalytic sensing behaviour and literature rather than direct radical quantification in the extracted text.
8 · 4. Conclusion · Linked to 3 structured results
Names and aliases are kept exactly within the paper’s own identity model.
| Material | Composition | Structure context | Source |
|---|---|---|---|
| Au-Thi@ST-HA antifouling hydrogel | ST-HA gel with Au nanoparticles and thionineAu nanoparticles · 5-serotonin hydrochloride and hyaluronic acid crosslinked with PEI | unknown · CompositeHydrophilic hydrogel with amide-bond formation verified by FTIR and Au distribution verified by SEM/EDS. | 2 · 2.3 Preparation of antifouling hydrogel substrate |
| BSA/Ab2/CuFe-MOF immunoprobe | BSA/Ab2/CuFe-MOFCu and Fe in CuFe-MOF · BDC in CuFe-MOF; biomolecular BSA and antibody Ab2 | 2D · CompositeCuFe-MOF modified with labeling antibody Ab2 and BSA blocking layer. | 2 · 2.4 Preparation of immunoprobe |
| Cu2O nanocubes | Cu2OCu | 0D · PristineCu2O precursor crystals matched the Cu2O standard card COD-1000063 by XRD. | 5 · 3.3 Characterization of immunoprobe · Fig. 2A |
| Cu-BDC bulk | Cu-BDCCu · 1,4-benzenedicarboxylate (BDC) from H2BDC | unknown · PristineBulk Cu-BDC XRD peaks indexed to COD-687690. | 1.3 Experimental |
| Cu-BDC nanosheets | Cu-BDCCu · 1,4-benzenedicarboxylate (BDC) from H2BDC | 2D · Pristine2D Cu-BDC nanosheets with shifted/disappearing XRD peaks relative to bulk Cu-BDC; lamellar nanosheet morphology by SEM/TEM. | 4 · 2.4 Preparation of immunoprobe |
| 2D CuFe-MOF | CuFe-MOF; Cu/Fe-BDCCu and Fe · 1,4-benzenedicarboxylate (BDC) from H2BDC | 2D · PristineMixed-metal 2D MOF nanosheets; XRD peaks ascribed to Cu-BDC bulk and FeO2 reference peaks, with Fe incorporation supported by XPS and EDS. | 1 · Abstract |
| Glassy carbon electrode platform | C | unknown · Model SystemElectrode substrate used for electrochemical measurements. | 1.2 Apparatus |
Sample form, processing state and composition status define the context for measurements.
| Sample | Form and role | Processing and geometry | Source |
|---|---|---|---|
| Au-Thi@ST-HA hydrogelresearch_0571__mat__au_thi_st_ha_gel | Thin Film · Composite Sample · Composite | ST-HA hydrogel crosslinked with PEI and loaded with Au nanoparticles/thionineGCE when cast as sensing substrate | 2 · 2.3 Preparation of antifouling hydrogel substrate |
| Bare GCEresearch_0571__mat__gce_platform | Electrode · Pristine Control · Model | polished and cleaned electrodeglassy carbon electrode | 2 · 2.5 Fabrication of immunosensor |
| BSA/Ab2/CuFe-MOF immunoproberesearch_0571__mat__bsa_ab2_cufe_immunoprobe | Nanosheet · Composite Sample · Composite | CuFe-MOF activated by EDC/NHS, labelled with Ab2, blocked with BSA | 2 · 2.4 Preparation of immunoprobe |
| Cu2O nanocubesresearch_0571__mat__cu2o_precursor | Powder · Composite Component · Unknown | precursor powder/nanocubes | 2 · 2.4 Preparation of immunoprobe |
| Cu-BDC bulkresearch_0571__mat__cu_bdc_bulk | Powder · Pristine Control · Pristine Framework | solvothermal bulk powder dried at 60 C overnight | 1.3 Experimental |
| Cu-BDC nanosheetsresearch_0571__mat__cu_bdc_nanosheets | Nanosheet · Pristine Control · Pristine Framework | washed blue solid re-dispersed in methanol | 2 · 2.4 Preparation of immunoprobe |
| 2D CuFe-MOFresearch_0571__mat__cu_fe_mof | Nanosheet · Target Sample · Mixed Metal | brown product washed and vacuum-dried | 2 · 2.4 Preparation of immunoprobe |
| CuFe-MOF feed-ratio seriesresearch_0571__mat__cu_fe_mof | Nanosheet · Target Sample · Mixed Metal | Cu:Fe feed ratios: Cu-BDC, 1:0.25, 1:0.5, 1:0.75, 1:1, 1:2 | 5 · 3.3 Characterization of immunoprobe · Fig. 2L |
| GCE-Gel-Ab1-Antigen-Probe immunosensorresearch_0571__mat__gce_platform | Electrode · Composite Sample · Composite | GCE coated with Au-Thi@ST-HA gel, Ab1, BSA, antigen, and BSA/Ab2/CuFe-MOF probeglassy carbon electrode | 2 · 2.5 Fabrication of immunosensor |
| BSA-modified GCEresearch_0571__mat__gce_platform | Electrode · Pristine Control · Composite | GCE modified with BSA antifouling layerglassy carbon electrode | 6 · 3.5 Antifouling performance of immunosensor · Fig. 4 |
| GCE-Gelresearch_0571__mat__gce_platform | Electrode · Composite Sample · Composite | GCE modified with Au-Thi@ST-HA hydrogelglassy carbon electrode | 6 · 3.5 Antifouling performance of immunosensor · Fig. 4 |