Dai F., Cui X., Luo Y. et al. · Chemical Communications · 2022 · 11543-11546
Open a family to keep every result attached to its sample, method and conditions.
Paraphrased for this database from the authors’ stated interpretations — never quoted verbatim — and kept separate from reported measurements.
The Co-TCPP-Ac NS thin-film sensor detects methanol at room temperature with high response, low detection limit, repeatability, stability, and selectivity.
Caveat: Application values are first-hand device measurements; raw data are not provided in the supplied documents.
4 · summary · Fig. 3 · Linked to 6 structured results
Co-TCPP-Ac nanosheets retain the same crystal structure as Co-TCPP-Ac bulk crystals.
Caveat: Powder XRD and electron diffraction support phase retention; full single-crystal refinement was performed on bulk crystals, not nanosheets.
2 · main text · Fig. S2a · Linked to 3 structured results
High methanol selectivity is attributed to interactions between methanol and Co-TCPP-Ac NSs, abundant unsaturated Co sites, ultrathin morphology, and suitable conductivity.
Caveat: Mechanistic attribution is plausible and supported by spectroscopy, but adsorption energetics or direct site quantification were not reported.
4 · main text · Fig. 4 · Linked to 5 structured results
Co-TCPP-Ac NSs are inferred to be n-type semiconductors because resistance decreases upon exposure to reducing methanol gas.
Caveat: The claim is mechanistic inference from sensing response and UPS/FTIR, not a direct Hall measurement.
3 · main text · Fig. 4 · Linked to 2 structured results
Names and aliases are kept exactly within the paper’s own identity model.
| Material | Composition | Structure context | Source |
|---|---|---|---|
| Co-TCPP-Ac | [Co3(TCPP)(Ac)]n.(CH3CH3N+); empirical formula C50H27Co3N4O11 in Table S1Co2+ porphyrin centres and Co2 paddlewheel secondary building units · 5,10,15,20-tetra(carboxyphenyl)porphyrin (H6TCPP/TCPP) with acetate/acetic acid axial connectors | 3D · PristineOrthorhombic Cmmm, non-interpenetrated 3D framework, 4,6-c fsc topology. | 2 · main text · Fig. 1; Table S1 cited |
Sample form, processing state and composition status define the context for measurements.
| Sample | Form and role | Processing and geometry | Source |
|---|---|---|---|
| Co-TCPP-Ac bulk crystalsresearch_0585__mat__co_tcpp_ac | Single Crystal · Pristine Control · Pristine Framework | Red crystalline blocks collected by filtration, washed with DMA and ethanol, dried in air. | 2 · Experimental Section · Fig. S1 |
| Co-TCPP-Ac NSsresearch_0585__mat__co_tcpp_ac | Nanosheet · Target Sample · Pristine Framework | Surfactant-assisted solvothermal nanosheets prepared with PVP.10 +/- 2 nm by AFM | 2 · main text · Fig. 2; Fig. S2 |
| Co-TCPP-Ac NS thin film-based sensorresearch_0585__mat__co_tcpp_ac | Electrode · Target Sample · Pristine Framework | Co-TCPP-Ac NS thin film spin-coated at 800 rpm for 30 s and oven-dried at 60 degC for 3 h.Planar rigid printed circuit board with Cu/Ni interdigital electrodes | 4 · Fabrication of gas sensors · Fig. S5 |