cMOF Evidence Base
Diffraction Structure — Ultrathin MOF nanosheet-based resistive sensors for highly sensitive detection of methanol

Measurement evidence

Diffraction Structure

Ultrathin MOF nanosheet-based resistive sensors for highly sensitive detection of methanol · Dai F., Cui X., Luo Y. et al. · Chemical Communications · 2022 · 11543-11546

2 measurement groups · 13 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Powder X-ray diffraction

X-ray diffraction and scattering

Co-TCPP-Ac NSs · Nanosheet

Cu-Kalpha radiation, lambda = 1.5406 A; nanosheet, bulk, and simulated patterns compared.

Context
pristine nanosheets compared with bulk crystal
Measurement source
2 · main text · Fig. S2a
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Nanosheet XRD assigned planes(021), (200), and (042) diffraction planes; identical to bulk crystal——Text
Qualitative		2 · main text · Fig. S2a

Single-crystal X-ray diffraction

X-ray diffraction and scattering

Co-TCPP-Ac bulk crystals · Single Crystal

Cu-Kalpha radiation, lambda = 1.54178 A, data collected at 273 K; PLATON/SQUEEZE used for disordered solvent.

Temperature
273
Context
pristine bulk crystal framework
Measurement source
3 · X-ray Structural Studies · Table S1
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Unit-cell volume9704.0(7) A39.704 nm3(7)SI Table
Exact Reported		4 · Table S1 · Table S1
Channel dimensions along a axis16.2 x 8.2 A2——Text
Rounded Reported		2 · main text · Fig. 1d,e
Co...Co paddlewheel separation2.807 A0.2807 nm—Text
Exact Reported		2 · main text · Fig. 1
Average Co1-N bond length1.963 A0.1963 nm—Text
Exact Reported		2 · main text · Fig. 1a
Average Co2-O carboxylate bond length2.014 A0.2014 nm—Text
Exact Reported		2 · main text · Fig. 1a
Crystal system and space grouporthorhombic, Cmmm——SI Table
Exact Reported		4 · Table S1 · Table S1
Empirical formulaC50H27Co3N4O11——SI Table
Exact Reported		4 · Table S1 · Table S1
Pore dimensions viewed along b and c axes16.6 x 6.0 A2——Text
Rounded Reported		2 · main text · Fig. 1b,c
PLATON solvent cavity volume fraction67.0%0.67 fraction—Text
Rounded Reported		2 · main text · Fig. 1
Unit-cell a parameter17.5964(9) A1.75964 nm(9)SI Table
Exact Reported		4 · Table S1 · Table S1
Unit-cell b parameter33.2980(10) A3.3298 nm(10)SI Table
Exact Reported		4 · Table S1 · Table S1
Unit-cell c parameter16.5618(6) A1.65618 nm(6)SI Table
Exact Reported		4 · Table S1 · Table S1