Synthesis · Ultrathin MOF nanosheet-based resistive sensors for highly sensitive detection of methanol

3 structured synthesis routes

Completeness describes how fully the route could be reconstructed from the main article and supporting information.

Complete recipeSource: Both

2 · Synthesis of Co-TCPP-AC bulk crystals

Metal precursorsCoCl2.6H2O (10.0 mg, 0.042 mmol)

Linker precursorsH6TCPP (10.0 mg, 0.013 mmol)

SolventsDMA (1.0 mL)

AdditivesHClO4 (50 uL)

Atmospheresealed tube; atmosphere not otherwise specified

Temperature120

Time24

Work-upCollected by filtration, washed with DMA and ethanol, dried in air.

ActivationNo separate activation reported.

Scalability contextYield 70% based on cobalt.

Show 4 structured reagent records

Role	Reagent	Amount / concentration	Source
Metal Source	CoCl2.6H2O	10.0 mg, 0.042 mmol	2 · Synthesis of Co-TCPP-AC bulk crystals
Linker	H6TCPP	10.0 mg, 0.013 mmol	2 · Synthesis of Co-TCPP-AC bulk crystals
Solvent	DMA	1.0 mL	2 · Synthesis of Co-TCPP-AC bulk crystals
Acid	HClO4	50 uL	2 · Synthesis of Co-TCPP-AC bulk crystals

Partial recipeSource: Both

4 · Fabrication of gas sensors · Fig. S5

SolventsCoating dispersion solvent not specified

Atmosphereambient/air during gas-sensor fabrication not explicitly specified

Temperature60 drying

Time0.0083 h spin-coating; 3 h drying

Substrate orientationPlanar PCB substrate with Cu/Ni interdigital electrodes

Work-upSpin-coated at 800 rpm for 30 s, dried in oven at 60 degC for 3 h.

ActivationNo separate activation reported.

Show 1 structured reagent record

Role	Reagent	Amount / concentration	Source
Other	Co-TCPP-Ac NS thin film precursor/dispersion	not reported · not reported	4 · Fabrication of gas sensors · Fig. S5

Partial recipeSource: Both

2 · Synthesis of Co-TCPP-AC NSs

Metal precursorsCoCl2.6H2O (5.0 mg, 0.021 mmol)

Linker precursorsH6TCPP (2.5 mg, 0.006 mmol)

SolventsDMA (10.0 mL)

AdditivesHClO4 (25 uL); PVP (10.0 mg, MW = 40,000)

Atmospheresealed tube; atmosphere not otherwise specified

Temperature120

Time6 h at 120 degC, then cooled to 25 degC over 10 h

Work-upIsolation/washing procedure not stated for nanosheets; yield reported.

ActivationNo separate activation reported.

Scalability contextYield about 2.25 mg (45% based on cobalt).

Show 5 structured reagent records

Role	Reagent	Amount / concentration	Source
Metal Source	CoCl2.6H2O	5.0 mg, 0.021 mmol	2 · Synthesis of Co-TCPP-AC NSs
Linker	H6TCPP	2.5 mg, 0.006 mmol	2 · Synthesis of Co-TCPP-AC NSs
Solvent	DMA	10.0 mL	2 · Synthesis of Co-TCPP-AC NSs
Acid	HClO4	25 uL	2 · Synthesis of Co-TCPP-AC NSs
Additive	Polyvinyl pyrrolidone (PVP, MW = 40,000)	10.0 mg	2 · Synthesis of Co-TCPP-AC NSs