cMOF Evidence Base
Electrochemistry Application — Ligand-Insertion Strategy for Constructing 2D Conjugated Metal–Organic Framework with Large Pore Size for Electrochemical Analytics

Measurement evidence

Electrochemistry Application

Ligand-Insertion Strategy for Constructing 2D Conjugated Metal–Organic Framework with Large Pore Size for Electrochemical Analytics · Wang X.-Z., Chen Y., Cao X.-M. et al. · Angewandte Chemie - International Edition · 2025 · e202413115

2 measurement groups · 12 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Cyclic voltammetry with redox probes and Randles-Sevcik analysis

Voltammetry

Cu3(HHTP)2-coated GCE control · Electrode

Same KCl 0.1 M redox-probe conditions as target electrode, using Cu3(HHTP)2/GCE control.

Geometry
MOF/Nafion-coated 3 mm GCE
Context
composite electrode with pristine control MOF component
Measurement source
6 · Electrochemical Analysis with MOF-Coated Electrodes · Figure 3
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Effective diffusion coefficient for FcMeOH on Cu3(HHTP)2/GCE3.57 x 10-6 cm2 s-13.57e-10 m2 s-1—Figure Axis
Approximate		6 · Electrochemical Analysis with MOF-Coated Electrodes · Figure 3d
Effective diffusion coefficient for Fe(CN)6(3-) on Cu3(HHTP)2/GCE1.80 x 10-6 cm2 s-11.8e-10 m2 s-1—Figure Axis
Approximate		6 · Electrochemical Analysis with MOF-Coated Electrodes · Figure 3e
Effective diffusion coefficient for IrCl6(3-) on Cu3(HHTP)2/GCE8.25 x 10-7 cm2 s-18.25e-11 m2 s-1—Figure Axis
Approximate		6 · Electrochemical Analysis with MOF-Coated Electrodes · Figure 3f

Cyclic voltammetry with redox probes and Randles-Sevcik analysis

Voltammetry

Cu3(HHTP)(DHBQ)1.5/1.53-coated GCE · Electrode

Three-electrode setup with MOF-loaded GCE working electrode, Ag/AgCl reference and Pt counter; KCl 0.1 M containing FcMeOH, Fe(CN)6(3-) or IrCl6(3-) at 1 mM; scan-rate-dependent CV.

Geometry
MOF/Nafion-coated 3 mm GCE
Context
composite electrode with pristine framework active component
Measurement source
5-6 · Electrochemical Analysis with MOF-Coated Electrodes · Figure 3; Figure S15
PropertyReported valueNormalised valueUncertaintyOrigin and qualitySource
Reported surface area of Cu3(HHTP)2 control458.4 m2 g-1 for Cu3(HHTP)2——Text
Exact Reported		5 · Electrochemical Analysis with MOF-Coated Electrodes
Effective diffusion coefficient for FcMeOH on target MOF/GCEMarked as a best value within this paper8.24 x 10-6 cm2 s-18.24e-10 m2 s-1—Figure Axis
Approximate		6 · Electrochemical Analysis with MOF-Coated Electrodes · Figure 3d
Effective diffusion coefficient for Fe(CN)6(3-) on target MOF/GCE3.21 x 10-6 cm2 s-13.21e-10 m2 s-1—Figure Axis
Approximate		6 · Electrochemical Analysis with MOF-Coated Electrodes · Figure 3e
Effective diffusion coefficient for IrCl6(3-) on target MOF/GCE2.58 x 10-6 cm2 s-12.58e-10 m2 s-1—Figure Axis
Approximate		5-6 · Electrochemical Analysis with MOF-Coated Electrodes · Figure 3f
FcMeOH molecular size0.45 nm——Text
Exact Reported		5 · Electrochemical Analysis with MOF-Coated Electrodes · Figure 3
Fe(CN)6(3-) molecular size0.70 nm——Text
Exact Reported		5 · Electrochemical Analysis with MOF-Coated Electrodes · Figure 3
IrCl6(3-) molecular size0.82 nm——Text
Exact Reported		5 · Electrochemical Analysis with MOF-Coated Electrodes · Figure 3
Peak-separation range for target redox probes at 100 mV s-1116-176 mV——Text
Range		5 · Electrochemical Analysis with MOF-Coated Electrodes · Figure 3a-c
Ru(bpy)3(3+) redox response on target/control MOF electrodesNo prominent redox peak——Text
Qualitative		5 · Electrochemical Analysis with MOF-Coated Electrodes · Figure S16