Measurement evidence
Ligand-Insertion Strategy for Constructing 2D Conjugated Metal–Organic Framework with Large Pore Size for Electrochemical Analytics · Wang X.-Z., Chen Y., Cao X.-M. et al. · Angewandte Chemie - International Edition · 2025 · e202413115
Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.
As-prepared Cu3(HHTP)(DHBQ)1.5/1.53 black powder · Powder
KBr pellets, 4000-400 cm-1 range, comparing MOF with HHTP and DHBQ ligands.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| FT-IR C=C stretching peak | 1239 cm-1 | — | — | Text Exact Reported | 2 · Structural Characterization on the Sample · Figure 1a |
| FT-IR C-O stretching peak | 1457 cm-1 | — | — | Text Exact Reported | 2 · Structural Characterization on the Sample · Figure 1a |
As-prepared Cu3(HHTP)(DHBQ)1.5/1.53 black powder · Powder
XPS calibrated to C 1s 284.8 eV; elemental analysis of C, H, N; mapping by SEM/EDS.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| Average charge at each CuO4 unit | -0.87 | — | — | Text Exact Reported | 4 · Structural Characterization on the Sample · Figure S5; Table S5 |
| Cu(II) fraction from XPS ratio | Cu(II)/Cu(I) = 85:15 | 0.85 fraction | — | Text Exact Reported | 3-4 · Structural Characterization on the Sample · Figure S5b |
| Elemental-analysis chemical formulaMarked as a best value within this paper | Cu3(HHTP)(DHBQ)1.5(H2O)19.00(H2en)1.66 | — | — | Text Exact Reported | 3 · Structural Characterization on the Sample · Table S5 |
| Semiquinone to catecholate ratio | 0.47:1 | — | — | Text Exact Reported | 4 · Structural Characterization on the Sample · Figure S5c |