Primary studyCore evidenceThin Film Device

ChemFET Sensor: nanorods of nickel-substituted Metal–Organic framework for detection of SO2

Ingle N., Sayyad P., Bodkhe G. et al. · Applied Physics A: Materials Science and Processing · 2020 · 723

1materials
3samples
3synthesis routes
10measurements
53results
7claims and caveats

Evidence map

Open a family to keep every result attached to its sample, method and conditions.

Author interpretations and caveats

Paraphrased for this database from the authors’ stated interpretations — never quoted verbatim — and kept separate from reported measurements.

Application RelevanceSupport assessment: Medium

Ni3HHTP2 ChemFET is more responsive to SO2 than to CO, C2H2, NO2 and CH4 under the tested conditions.

Caveat: Selectivity values are read from plotted bars; exact tabulated values and SI/raw data were not available.

6 · 4 ChemFET sensing · Fig. 9 · Linked to 5 structured results

Application RelevanceSupport assessment: High

The Ni3HHTP2 ChemFET detects SO2 at a lower detection limit of 625 ppb at room temperature.

Caveat: The authors compare this to literature values, but raw detection-limit statistics are not provided.

6 · 5 Conclusions · Linked to 4 structured results

Application RelevanceSupport assessment: Medium

The rendered SI plots visually support reversible dynamic SO2 response across 625-1000 ppb and repeatable cycling at 875 ppb.

Caveat: Values are approximate figure-axis readings from rendered SI pages; no SI table or raw data were provided.

1-2 · Supporting Supplementary · Figures 1-2 · Linked to 7 structured results

Phase AssignmentSupport assessment: High

The GIXRD pattern of the synthesised material matches reported Ni3HHTP2 MOF data.

Caveat: No CIF or full refinement data are provided in the assigned documents.

2 · 3.1 X-Ray diffraction · Fig. 2 · Linked to 4 structured results

Structure Property LinkSupport assessment: Medium

The authors link Ni3HHTP2 nanorod roughness to trapping foreign gas analytes and improving ChemFET sensitivity.

Caveat: The causal link is asserted from morphology and sensing behaviour, not isolated by a roughness-controlled comparison.

3 · 3.3 Surface morphology studies · Fig. 4 · Linked to 1 structured result

Transport MechanismSupport assessment: High

The FET transfer characteristics indicate a p-type Ni3HHTP2 channel carrying holes as majority carriers.

Caveat: Carrier type is inferred from device characteristics rather than direct Hall measurement.

3 · 3.4 Field Effect Transistor measurements · Fig. 5 · Linked to 4 structured results

Transport MechanismSupport assessment: Medium

Electron-acceptor SO2 interacting with the p-type Ni3HHTP2 channel decreases drain current through charge-dipole interactions.

Caveat: Mechanistic explanation is qualitative; no independent adsorption or charge-transfer quantification is reported.

6 · 4 ChemFET sensing · Fig. 8 · Linked to 3 structured results

Material identities

Names and aliases are kept exactly within the paper’s own identity model.

MaterialCompositionStructure contextSource
Ni3HHTP2 MOF nanorodsBrowse family: Ni₃(HHTP)₂ / Ni–HHTPNi3HHTP2nickel(II) · 2,3,6,7,10,11-hexahydroxytriphenylene hydrate (HHTP)2D · PristineSemiconducting HHTP-based nickel MOF; GIXRD matched reported Ni3HHTP2 data with (100) and (200) reflections.1 · Abstract

Sample register

Sample form, processing state and composition status define the context for measurements.

Show 3 sample records
SampleForm and roleProcessing and geometrySource
Au microelectrode Si/SiO2 back-gated platformresearch_0605__mat__ni3hhtp2_mofElectrode · Paper Level Unspecified · UnknownIso-propyl alcohol cleaning, pre-baking at 110 C, Cr/Au deposition by e-beam and thermal evaporation under vacuum.highly boron doped p-type Si wafer with SiO2 insulating layer · Si 525 um; SiO2 100 nm; Cr/Au 20/180 nm2 · 2.1 Microelectrodes fabrication · Fig. 1
Ni3HHTP2 MOF ChemFET channel on Au/SiO2/Siresearch_0605__mat__ni3hhtp2_mofElectrode · Target Sample · Pristine FrameworkNi3HHTP2 solution drop-cast between two Au microelectrodes with 3 um gap and dried in ambient atmosphere.gold microelectrodes on Si/SiO2 back-gate substrate2 · 2.2 Synthesis of nanorods of Ni3HHTP2 MOF · Fig. 1
chemically synthesized Ni3HHTP2 nanorodsresearch_0605__mat__ni3hhtp2_mofPowder · Target Sample · Pristine FrameworkChemical synthesis in deionized water at 90 C; used as synthesized solution for drop casting.2 · 2.2 Synthesis of nanorods of Ni3HHTP2 MOF