Microscopy Morphology — Thermally Driven Resistive Switching in Solution-Processable Thin Films of Coordination Polymers

6 measurement groups · 7 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Ag-TCNQ thin film on SAM/Au · Thin Film

Cross-sectional image of Ag-TCNQ thin film from step II; inset zoomed view.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Ag-TCNQ final thin-film thickness	approximately 850 nm	—	—	Figure Axis Approximate	S3 · Figure caption/label · Figure S3b

Cu-TCNQ thin film on SAM/Au · Thin Film

Cross-sectional image of Cu-TCNQ thin film from step I; inset zoomed view.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Cu-TCNQ initial thin-film thickness	approximately 550 nm	—	—	Figure Axis Approximate	S3 · Figure caption/label · Figure S3a

Cu-TCNQ thin film on SAM/Au · Thin Film

Pure Cu-TCNQ thin film before and after dipping into AgNO3 solution for 5 h.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Cu-TCNQ etching by AgNO3	Cu-TCNQ thin film completely etched away after dipping into AgNO3 solution for 5 h	—	—	Text Exact Reported	5010 · Main text · Figure S4 referenced

Ag-TCNQ thin film on SAM/Au · Thin Film

Cu-TCNQ thin film morphology before AgNO3/TCNQ LbL and after 1 and 10 cycles.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
morphological evolution during AgNO3/TCNQ cycles	small Ag nanoparticles formed in the first cycle; over progressive cycles Cu-TCNQ nanoflakes vanished and Ag-TCNQ nanorods formed	—	—	Text Qualitative	5010 · Main text · Figure S5 referenced

Ag-TCNQ thin film on SAM/Au · Thin Film

Attempted direct Ag-TCNQ growth on SAMs with exposed -COOH, -NH2 and -SH groups.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
direct Ag-TCNQ growth on varied SAM terminal groups	changing terminal groups from -COOH to -NH2 or -OH/-SH did not help grow Ag-TCNQ crystals	—	—	Text Qualitative	5009 · Main text · Figure S1 referenced

Cu-TCNQ thin film on SAM/Au · Thin Film

Cu(OAc)2/TCNQ and CuI/TCNQ solution mixing controls; FESEM of Cu-TCNQ precipitate rods.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Cu(OAc)2 plus TCNQ solution control	no precipitation upon mixing Cu(OAc)2 and TCNQ solutions	—	—	Caption Qualitative	S4 · Figure caption · Figure S6a
CuI plus TCNQ solution control	precipitation upon mixing CuI and TCNQ solution; FESEM showed long rods of Cu-TCNQ	—	—	Caption Qualitative	S4 · Figure caption · Figure S6b,c