Spectroscopy — Thermally Driven Resistive Switching in Solution-Processable Thin Films of Coordination Polymers

5 measurement groups · 14 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Ag-TCNQ thin film on SAM/Au · Thin Film

Initial Cu-TCNQ film compared with final Ag-TCNQ film after step II

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Ag L-alpha EDXS line in final Ag-TCNQ film	approximately 2.93 keV	—	—	Text Approximate	5009 · Main text · Figure 2c
Ag L-beta EDXS line in final Ag-TCNQ film	approximately 3.15 keV	—	—	Text Approximate	5009 · Main text · Figure 2c
Cu L-alpha EDXS line in initial Cu-TCNQ film	approximately 0.93 keV	—	—	Text Approximate	5009 · Main text · Figure 2c

Ag-TCNQ thin film on SAM/Au · Thin Film

Raman bands of initial and final thin films assigned to monoanionic TCNQ ligand

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
TCNQ C-CN stretching Raman band	1374 cm-1	—	—	Text Exact Reported	5010 · Main text · Figure S2 referenced
TCNQ C=C ring stretching Raman band	1602 cm-1	—	—	Text Exact Reported	5010 · Main text · Figure S2 referenced
TCNQ CN stretching Raman band	2205 cm-1	—	—	Text Exact Reported	5010 · Main text · Figure S2 referenced

Ag-TCNQ thin film on SAM/Au · Thin Film

Ag-TCNQ thin film measured at 300 K, 400 K and after cooling to 300 K

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Ag-TCNQ HRS C-CN Raman band	approximately 1374 cm-1	—	—	Text Approximate	5011 · Main text · Figure 4b
Ag-TCNQ HRS C=C Raman band	approximately 1603 cm-1	—	—	Text Approximate	5011 · Main text · Figure 4b
Ag-TCNQ HRS CN Raman band	approximately 2206 cm-1	—	—	Text Approximate	5011 · Main text · Figure 4b
neutral TCNQ Raman bands during switching	new bands at approximately 1457 and approximately 2229 cm-1 were not observed	—	—	Text Qualitative	5011 · Main text · Figure 4b

Ag-TCNQ thin film on SAM/Au · Thin Film

Ag 3d and Cu 2p regions recorded on final Ag-TCNQ thin film

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Ag 3d XPS binding energy, as printed first value	373.2 eV	—	—	Text Exact Reported	5010 · Main text · Figure 2e
Ag 3d XPS binding energy, as printed second value	367.53 eV	—	—	Text Exact Reported	5010 · Main text · Figure 2e
Cu 2p XPS signal in final Ag-TCNQ film	no reasonable Cu 2p XPS signal at 930-960 eV	—	—	Text Qualitative	5010 · Main text · Figure 2e

Cu-TCNQ thin film on SAM/Au · Thin Film

Cu-TCNQ thin-film Raman spectra at 300 K and 370 K during switching-control experiment.

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
Cu-TCNQ thin-film variable-temperature Raman change	no appreciable change in temperature-dependent Raman data	—	—	Text Qualitative	5013 · Main text · Figure S7 referenced