Porosity — Cooperative Proton and Li-ion Conduction in a 2D-Layered MOF via Mechanical Insertion of Lithium Halides

4 measurement groups · 8 results

Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.

Ti-dobdc pristine · Pellet

Activated at 373 K under vacuum (10^-2 Pa) for 4 h; H2O vapour sorption measured at 298 K.

Temperature: 298
Atmosphere: H2O vapour
Context: water uptake/hygroscopicity relevant to proton and Li-ion conduction
Measurement source: S2/S8 · Materials and Methods · Figure S6

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
H2O uptake near P/P0 = 0.9	about 13 mol mol^-1 at P/P0 ~0.9	—	—	Visual Estimate Approximate	S8 · Figure S6 · Figure S6c

Ti-dobdc-LiBr (MOF:LiBr = 1:1) · Pellet

Activated at 373 K under vacuum (10^-2 Pa) for 4 h; H2O vapour sorption measured at 298 K.

Temperature: 298
Atmosphere: H2O vapour
Context: water uptake/hygroscopicity relevant to proton and Li-ion conduction
Measurement source: S2/S8 · Materials and Methods · Figure S6

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
LiX sample uptake relative to pristine at P/P0 = 0.9	three times higher than pristine Ti-dobdc	—	—	Text Approximate	3 · Results · Figure S6c
H2O uptake at P/P0 = 0.02	approximately six H2O molecules per formula unit	—	—	Text Approximate	3 · Results · Figure S6a
H2O uptake near P/P0 = 0.9	about 34 mol mol^-1 at P/P0 ~0.9	—	—	Visual Estimate Approximate	S8 · Figure S6 · Figure S6c

Ti-dobdc-LiCl (MOF:LiCl = 1:1) · Pellet

Activated at 373 K under vacuum (10^-2 Pa) for 4 h; H2O vapour sorption measured at 298 K.

Temperature: 298
Atmosphere: H2O vapour
Context: water uptake/hygroscopicity relevant to proton and Li-ion conduction
Measurement source: S2/S8 · Materials and Methods · Figure S6

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
H2O uptake at P/P0 = 0.02	approximately six H2O molecules per formula unit	—	—	Text Approximate	3 · Results · Figure S6a
H2O uptake near P/P0 = 0.9	about 31 mol mol^-1 at P/P0 ~0.9	—	—	Visual Estimate Approximate	S8 · Figure S6 · Figure S6c

Ti-dobdc-LiI (MOF:LiI = 1:1) · Pellet

Activated at 373 K under vacuum (10^-2 Pa) for 4 h; H2O vapour sorption measured at 298 K.

Temperature: 298
Atmosphere: H2O vapour
Context: water uptake/hygroscopicity relevant to proton and Li-ion conduction
Measurement source: S2/S8 · Materials and Methods · Figure S6

Property	Reported value	Normalised value	Uncertainty	Origin and quality	Source
H2O uptake at P/P0 = 0.02	approximately six H2O molecules per formula unit	—	—	Text Approximate	3 · Results · Figure S6a
H2O uptake near P/P0 = 0.9	about 29 mol mol^-1 at P/P0 ~0.9	—	—	Visual Estimate Approximate	S8 · Figure S6 · Figure S6c