Measurement evidence
Cooperative Proton and Li-ion Conduction in a 2D-Layered MOF via Mechanical Insertion of Lithium Halides · Sarango-Ramirez M.K., Donoshita M., Yoshida Y. et al. · Angewandte Chemie - International Edition · 2023 · e202301284
Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.
Ti-dobdc pristine · Pellet
Activation energy from variable humidity conductivity; Figure 3b and text interpret low- and high-humidity regimes.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| activation energy in high humidity regime | <0.4 eV at high humidity | — | — | Text Qualitative | 3 · Results · Figure 3b |
| activation energy in low humidity regime | >0.4 eV at 30-60% RH | — | — | Text Qualitative | 3 · Results · Figure 3b |
Ti-dobdc-LiBr (MOF:LiBr = 1:1) · Pellet
Activation energy from variable humidity conductivity; Figure 3b and text interpret low- and high-humidity regimes.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| activation energy in high humidity regime | <0.4 eV at high humidity | — | — | Text Qualitative | 3 · Results · Figure 3b |
| activation energy in low humidity regime | >0.4 eV at 30-60% RH | — | — | Text Qualitative | 3 · Results · Figure 3b |
Ti-dobdc-LiCl (MOF:LiCl = 1:1) · Pellet
Activation energy from variable humidity conductivity; Figure 3b and text interpret low- and high-humidity regimes.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| activation energy in high humidity regime | <0.4 eV at high humidity | — | — | Text Qualitative | 3 · Results · Figure 3b |
| activation energy in low humidity regime | >0.4 eV at 30-60% RH | — | — | Text Qualitative | 3 · Results · Figure 3b |
Ti-dobdc-LiI (MOF:LiI = 1:1) · Pellet
Activation energy from variable humidity conductivity; Figure 3b and text interpret low- and high-humidity regimes.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| activation energy in high humidity regime | <0.4 eV at high humidity | — | — | Text Qualitative | 3 · Results · Figure 3b |
| activation energy in low humidity regime | >0.4 eV at 30-60% RH | — | — | Text Qualitative | 3 · Results · Figure 3b |
Ti-dobdc pristine · Pellet
Variable humidity conductivity; RH range 30-95% and 298-328 K; pellet coated with gold paste.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| ionic conductivity at 30% RH, 298 K | 8.22e-07 S cm^-1 (30% RH, 298 K) | — | — | SI Table Exact Reported | S13 · Table S1 · Table S1 |
| ionic conductivity at 90% RH, 298 K | 1.61e-05 S cm^-1 (90% RH, 298 K) | — | — | SI Table Exact Reported | S13 · Table S1 · Table S1 |
| ionic conductivity at 90% RH, 328 K | 0.00015 S cm^-1 (90% RH, 328 K) | — | — | SI Table Exact Reported | S13 · Table S1 · Table S1 |
Ti-dobdc-LiBr (MOF:LiBr = 1:1) · Pellet
Variable humidity conductivity; RH range 30-95% and 298-328 K; pellet coated with gold paste.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| ionic conductivity at 30% RH, 298 K | 1.06e-06 S cm^-1 (30% RH, 298 K) | — | — | SI Table Exact Reported | S13 · Table S1 · Table S1 |
| ionic conductivity at 90% RH, 298 K | 0.00762 S cm^-1 (90% RH, 298 K) | — | — | SI Table Exact Reported | S13 · Table S1 · Table S1 |
| ionic conductivity at 90% RH, 328 K | 0.0107 S cm^-1 (90% RH, 328 K) | — | — | SI Table Exact Reported | S13 · Table S1 · Table S1 |
Ti-dobdc-LiCl (MOF:LiCl = 1:1) · Pellet
Variable humidity conductivity; RH range 30-95% and 298-328 K; pellet coated with gold paste.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| ionic conductivity at 30% RH, 298 K | 1.16e-06 S cm^-1 (30% RH, 298 K) | — | — | SI Table Exact Reported | S13 · Table S1 · Table S1 |
| ionic conductivity at 90% RH, 298 K | 0.00208 S cm^-1 (90% RH, 298 K) | — | — | SI Table Exact Reported | S13 · Table S1 · Table S1 |
| ionic conductivity at 90% RH, 328 K | 0.00964 S cm^-1 (90% RH, 328 K) | — | — | SI Table Exact Reported | S13 · Table S1 · Table S1 |
Ti-dobdc-LiI (MOF:LiI = 1:1) · Pellet
Variable humidity conductivity; RH range 30-95% and 298-328 K; pellet coated with gold paste.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| ionic conductivity at 30% RH, 298 K | 2.73e-05 S cm^-1 (30% RH, 298 K) | — | — | SI Table Exact Reported | S13 · Table S1 · Table S1 |
| ionic conductivity at 90% RH, 298 KMarked as a best value within this paper | 0.0188 S cm^-1 (90% RH, 298 K) | — | — | SI Table Exact Reported | S13 · Table S1 · Table S1 |
| ionic conductivity at 90% RH, 328 K | 0.0126 S cm^-1 (90% RH, 328 K) | — | — | SI Table Exact Reported | S13 · Table S1 · Table S1 |
Ti-dobdc-LiBr (MOF:LiBr = 1:3) · Pellet
Humidity-dependent conductivity for higher MOF:LiBr molar ratios; reported at 298 K and 30% RH.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| ionic conductivity for MOF:LiBr = 1:3 at 30% RH, 298 K | 0.00169 S cm^-1 (298 K, 30% RH) | — | — | SI Table Exact Reported | S31 · Table S25 · Table S25 |
Ti-dobdc-LiBr (MOF:LiBr = 1:5) · Pellet
Humidity-dependent conductivity for higher MOF:LiBr molar ratios; reported at 298 K and 30% RH.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| ionic conductivity for MOF:LiBr = 1:5 at 30% RH, 298 KMarked as a best value within this paper | 0.0201 S cm^-1 (298 K, 30% RH) | — | — | SI Table Exact Reported | S31 · Table S25 · Table S25 |
Ti-dobdc pristine · Pellet
Variable temperature ionic conductivity at RH 95%.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| ionic conductivity at RH 95%, 298 K | 0.000301 S cm^-1 at 298 K, 95% RH | — | — | SI Table Exact Reported | S13 · Table S2 · Table S2 |
| ionic conductivity at RH 95%, 303 K | 0.000389 S cm^-1 at 303 K, 95% RH | — | — | SI Table Exact Reported | S13 · Table S2 · Table S2 |
| ionic conductivity at RH 95%, 308 K | 0.000512 S cm^-1 at 308 K, 95% RH | — | — | SI Table Exact Reported | S13 · Table S2 · Table S2 |
| ionic conductivity at RH 95%, 313 K | 0.000787 S cm^-1 at 313 K, 95% RH | — | — | SI Table Exact Reported | S13 · Table S2 · Table S2 |
| ionic conductivity at RH 95%, 318 K | 0.00101 S cm^-1 at 318 K, 95% RH | — | — | SI Table Exact Reported | S13 · Table S2 · Table S2 |
| ionic conductivity at RH 95%, 323 K | 0.0013 S cm^-1 at 323 K, 95% RH | — | — | SI Table Exact Reported | S13 · Table S2 · Table S2 |
| ionic conductivity at RH 95%, 328 K | 0.00166 S cm^-1 at 328 K, 95% RH | — | — | SI Table Exact Reported | S13 · Table S2 · Table S2 |
| ionic conductivity at RH 95%, 338 K | 0.00232 S cm^-1 at 338 K, 95% RH | — | — | SI Table Exact Reported | S13 · Table S2 · Table S2 |
| ionic conductivity at RH 95%, 348 K | 0.00308 S cm^-1 at 348 K, 95% RH | — | — | SI Table Exact Reported | S13 · Table S2 · Table S2 |
| ionic conductivity at RH 95%, 358 K | 0.00278 S cm^-1 at 358 K, 95% RH | — | — | SI Table Exact Reported | S13 · Table S2 · Table S2 |
| ionic conductivity at RH 95%, 368 K | 0.00293 S cm^-1 at 368 K, 95% RH | — | — | SI Table Exact Reported | S13 · Table S2 · Table S2 |
| ionic conductivity at RH 95%, 373 K | 0.000113 S cm^-1 at 373 K, 95% RH | — | — | SI Table Exact Reported | S13 · Table S2 · Table S2 |
| ionic conductivity at RH 95%, 378 K | 4.82e-05 S cm^-1 at 378 K, 95% RH | — | — | SI Table Exact Reported | S13 · Table S2 · Table S2 |
| ionic conductivity at RH 95%, 383 K | 1.61e-05 S cm^-1 at 383 K, 95% RH | — | — | SI Table Exact Reported | S13 · Table S2 · Table S2 |
| ionic conductivity at RH 95%, 393 K | 4.22e-06 S cm^-1 at 393 K, 95% RH | — | — | SI Table Exact Reported | S13 · Table S2 · Table S2 |
Ti-dobdc-LiBr (MOF:LiBr = 1:1) · Pellet
Variable temperature ionic conductivity at RH 95%.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| ionic conductivity at RH 95%, 298 K | 0.00606 S cm^-1 at 298 K, 95% RH | — | — | SI Table Exact Reported | S13 · Table S2 · Table S2 |
| ionic conductivity at RH 95%, 303 K | 0.00657 S cm^-1 at 303 K, 95% RH | — | — | SI Table Exact Reported | S13 · Table S2 · Table S2 |
| ionic conductivity at RH 95%, 308 K | 0.00691 S cm^-1 at 308 K, 95% RH | — | — | SI Table Exact Reported | S13 · Table S2 · Table S2 |
| ionic conductivity at RH 95%, 313 K | 0.00734 S cm^-1 at 313 K, 95% RH | — | — | SI Table Exact Reported | S13 · Table S2 · Table S2 |
| ionic conductivity at RH 95%, 318 K | 0.00753 S cm^-1 at 318 K, 95% RH | — | — | SI Table Exact Reported | S13 · Table S2 · Table S2 |
| ionic conductivity at RH 95%, 323 K | 0.00794 S cm^-1 at 323 K, 95% RH | — | — | SI Table Exact Reported | S13 · Table S2 · Table S2 |
| ionic conductivity at RH 95%, 328 K | 0.00812 S cm^-1 at 328 K, 95% RH | — | — | SI Table Exact Reported | S13 · Table S2 · Table S2 |
| ionic conductivity at RH 95%, 338 K | 0.0082 S cm^-1 at 338 K, 95% RH | — | — | SI Table Exact Reported | S13 · Table S2 · Table S2 |
| ionic conductivity at RH 95%, 348 K | 0.0113 S cm^-1 at 348 K, 95% RH | — | — | SI Table Exact Reported | S13 · Table S2 · Table S2 |
| ionic conductivity at RH 95%, 358 K | 0.0161 S cm^-1 at 358 K, 95% RH | — | — | SI Table Exact Reported | S13 · Table S2 · Table S2 |
| ionic conductivity at RH 95%, 368 KMarked as a best value within this paper | 0.0184 S cm^-1 at 368 K, 95% RH | — | — | SI Table Exact Reported | S13 · Table S2 · Table S2 |
| ionic conductivity at RH 95%, 373 K | 0.00467 S cm^-1 at 373 K, 95% RH | — | — | SI Table Exact Reported | S13 · Table S2 · Table S2 |
| ionic conductivity at RH 95%, 378 K | 0.00387 S cm^-1 at 378 K, 95% RH | — | — | SI Table Exact Reported | S13 · Table S2 · Table S2 |
| ionic conductivity at RH 95%, 383 K | 0.00317 S cm^-1 at 383 K, 95% RH | — | — | SI Table Exact Reported | S13 · Table S2 · Table S2 |
| ionic conductivity at RH 95%, 393 K | 0.00129 S cm^-1 at 393 K, 95% RH | — | — | SI Table Exact Reported | S13 · Table S2 · Table S2 |
Ti-dobdc-LiCl (MOF:LiCl = 1:1) · Pellet
Variable temperature ionic conductivity at RH 95%.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| ionic conductivity at RH 95%, 298 K | 0.00272 S cm^-1 at 298 K, 95% RH | — | — | SI Table Exact Reported | S13 · Table S2 · Table S2 |
| ionic conductivity at RH 95%, 303 K | 0.00299 S cm^-1 at 303 K, 95% RH | — | — | SI Table Exact Reported | S13 · Table S2 · Table S2 |
| ionic conductivity at RH 95%, 308 K | 0.00356 S cm^-1 at 308 K, 95% RH | — | — | SI Table Exact Reported | S13 · Table S2 · Table S2 |
| ionic conductivity at RH 95%, 313 K | 0.00385 S cm^-1 at 313 K, 95% RH | — | — | SI Table Exact Reported | S13 · Table S2 · Table S2 |
| ionic conductivity at RH 95%, 318 K | 0.00445 S cm^-1 at 318 K, 95% RH | — | — | SI Table Exact Reported | S13 · Table S2 · Table S2 |
| ionic conductivity at RH 95%, 323 K | 0.00501 S cm^-1 at 323 K, 95% RH | — | — | SI Table Exact Reported | S13 · Table S2 · Table S2 |
| ionic conductivity at RH 95%, 328 K | 0.00677 S cm^-1 at 328 K, 95% RH | — | — | SI Table Exact Reported | S13 · Table S2 · Table S2 |
| ionic conductivity at RH 95%, 338 K | 0.00982 S cm^-1 at 338 K, 95% RH | — | — | SI Table Exact Reported | S13 · Table S2 · Table S2 |
| ionic conductivity at RH 95%, 348 K | 0.00762 S cm^-1 at 348 K, 95% RH | — | — | SI Table Exact Reported | S13 · Table S2 · Table S2 |
| ionic conductivity at RH 95%, 358 K | 0.0106 S cm^-1 at 358 K, 95% RH | — | — | SI Table Exact Reported | S13 · Table S2 · Table S2 |
| ionic conductivity at RH 95%, 368 K | 0.0132 S cm^-1 at 368 K, 95% RH | — | — | SI Table Exact Reported | S13 · Table S2 · Table S2 |
| ionic conductivity at RH 95%, 373 K | 0.0113 S cm^-1 at 373 K, 95% RH | — | — | SI Table Exact Reported | S13 · Table S2 · Table S2 |
| ionic conductivity at RH 95%, 378 K | 0.000812 S cm^-1 at 378 K, 95% RH | — | — | SI Table Exact Reported | S13 · Table S2 · Table S2 |
| ionic conductivity at RH 95%, 383 K | 6.82e-05 S cm^-1 at 383 K, 95% RH | — | — | SI Table Exact Reported | S13 · Table S2 · Table S2 |
| ionic conductivity at RH 95%, 393 K | 3e-05 S cm^-1 at 393 K, 95% RH | — | — | SI Table Exact Reported | S13 · Table S2 · Table S2 |
Ti-dobdc-LiI (MOF:LiI = 1:1) · Pellet
Variable temperature ionic conductivity at RH 95%.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| ionic conductivity at RH 95%, 298 K | 0.00797 S cm^-1 at 298 K, 95% RH | — | — | SI Table Exact Reported | S13 · Table S2 · Table S2 |
| ionic conductivity at RH 95%, 303 K | 0.00853 S cm^-1 at 303 K, 95% RH | — | — | SI Table Exact Reported | S13 · Table S2 · Table S2 |
| ionic conductivity at RH 95%, 308 K | 0.00882 S cm^-1 at 308 K, 95% RH | — | — | SI Table Exact Reported | S13 · Table S2 · Table S2 |
| ionic conductivity at RH 95%, 313 K | 0.00692 S cm^-1 at 313 K, 95% RH | — | — | SI Table Exact Reported | S13 · Table S2 · Table S2 |
| ionic conductivity at RH 95%, 318 K | 0.00799 S cm^-1 at 318 K, 95% RH | — | — | SI Table Exact Reported | S13 · Table S2 · Table S2 |
| ionic conductivity at RH 95%, 323 K | 0.00928 S cm^-1 at 323 K, 95% RH | — | — | SI Table Exact Reported | S13 · Table S2 · Table S2 |
| ionic conductivity at RH 95%, 328 K | 0.00934 S cm^-1 at 328 K, 95% RH | — | — | SI Table Exact Reported | S13 · Table S2 · Table S2 |
| ionic conductivity at RH 95%, 338 K | 0.00559 S cm^-1 at 338 K, 95% RH | — | — | SI Table Exact Reported | S13 · Table S2 · Table S2 |
| ionic conductivity at RH 95%, 348 K | 0.00831 S cm^-1 at 348 K, 95% RH | — | — | SI Table Exact Reported | S13 · Table S2 · Table S2 |
| ionic conductivity at RH 95%, 358 K | 0.0127 S cm^-1 at 358 K, 95% RH | — | — | SI Table Exact Reported | S13 · Table S2 · Table S2 |
| ionic conductivity at RH 95%, 368 K | 0.014 S cm^-1 at 368 K, 95% RH | — | — | SI Table Exact Reported | S13 · Table S2 · Table S2 |
| ionic conductivity at RH 95%, 373 K | 0.000629 S cm^-1 at 373 K, 95% RH | — | — | SI Table Exact Reported | S13 · Table S2 · Table S2 |
| ionic conductivity at RH 95%, 378 K | 0.000406 S cm^-1 at 378 K, 95% RH | — | — | SI Table Exact Reported | S13 · Table S2 · Table S2 |
| ionic conductivity at RH 95%, 383 K | 0.000264 S cm^-1 at 383 K, 95% RH | — | — | SI Table Exact Reported | S13 · Table S2 · Table S2 |
| ionic conductivity at RH 95%, 393 K | 0.0001 S cm^-1 at 393 K, 95% RH | — | — | SI Table Exact Reported | S13 · Table S2 · Table S2 |
| high-temperature conductivity caveat | non-Arrhenius variation attributed to iodine species release | — | — | Text Qualitative | 3 · Results · Figure S7 |
Ti-dobdc pristine · Pellet
Powder sample loaded into NMR tube; kept at 298 K, 95% RH for one day and capped; PFG strength varied in 16 steps from 0 to 25 T m^-1; unidirectional model selected by authors.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| 1H self-diffusion coefficient, unidirectional model, 213 K | 6.52e-12 m^2 s^-1 | — | 4.49e-13 m^2 s^-1 | SI Table Exact Reported | S25-S26 · Table S12 · Table S12 |
| 1H self-diffusion coefficient, unidirectional model, 233 K | 1.18e-11 m^2 s^-1 | — | 5.27e-13 m^2 s^-1 | SI Table Exact Reported | S25-S26 · Table S12 · Table S12 |
| 1H self-diffusion coefficient, unidirectional model, 253 K | 2.15e-11 m^2 s^-1 | — | 5.83e-13 m^2 s^-1 | SI Table Exact Reported | S25-S26 · Table S12 · Table S12 |
| 1H self-diffusion coefficient, unidirectional model, 273 K | 3.37e-11 m^2 s^-1 | — | 6.48e-13 m^2 s^-1 | SI Table Exact Reported | S25-S26 · Table S12 · Table S12 |
| 1H self-diffusion coefficient, unidirectional model, 293 K | 4.91e-11 m^2 s^-1 | — | 6.7e-13 m^2 s^-1 | SI Table Exact Reported | S25-S26 · Table S12 · Table S12 |
| 1H self-diffusion coefficient, unidirectional model, 298 K | 4.57e-11 m^2 s^-1 | — | 8.12e-13 m^2 s^-1 | SI Table Exact Reported | S25-S26 · Table S12 · Table S12 |
| 1H self-diffusion coefficient, unidirectional model, 303 K | 5.93e-11 m^2 s^-1 | — | 1.38e-12 m^2 s^-1 | SI Table Exact Reported | S25-S26 · Table S12 · Table S12 |
| 1H self-diffusion coefficient, unidirectional model, 313 K | 7.82e-11 m^2 s^-1 | — | 1.99e-12 m^2 s^-1 | SI Table Exact Reported | S25-S26 · Table S12 · Table S12 |
| 1H self-diffusion coefficient, unidirectional model, 323 K | 8.63e-11 m^2 s^-1 | — | 3.2e-12 m^2 s^-1 | SI Table Exact Reported | S25-S26 · Table S12 · Table S12 |
| 1H self-diffusion coefficient, unidirectional model, 333 K | 7.99e-11 m^2 s^-1 | — | 3.41e-12 m^2 s^-1 | SI Table Exact Reported | S25-S26 · Table S12 · Table S12 |
| 1H self-diffusion coefficient, unidirectional model, 353 K | 9.7e-11 m^2 s^-1 | — | 6.61e-12 m^2 s^-1 | SI Table Exact Reported | S25-S26 · Table S12 · Table S12 |
| 1H self-diffusion coefficient, unidirectional model, 373 K | 6.71e-11 m^2 s^-1 | — | 6.46e-12 m^2 s^-1 | SI Table Exact Reported | S25-S26 · Table S12 · Table S12 |
| 1H self-diffusion coefficient, unidirectional model, 393 K | 3.54e-11 m^2 s^-1 | — | 5.03e-12 m^2 s^-1 | SI Table Exact Reported | S25-S26 · Table S12 · Table S12 |
Ti-dobdc-LiBr (MOF:LiBr = 1:1) · Pellet
Powder sample loaded into NMR tube; kept at 298 K, 95% RH for one day and capped; PFG strength varied in 16 steps from 0 to 25 T m^-1; unidirectional model selected by authors.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| 1H self-diffusion coefficient, unidirectional model, 213 K | 1.02e-11 m^2 s^-1 | — | 9.44e-13 m^2 s^-1 | SI Table Exact Reported | S25-S26 · Table S14 · Table S14 |
| 1H self-diffusion coefficient, unidirectional model, 233 K | 1.74e-11 m^2 s^-1 | — | 1.46e-12 m^2 s^-1 | SI Table Exact Reported | S25-S26 · Table S14 · Table S14 |
| 1H self-diffusion coefficient, unidirectional model, 253 K | 2.63e-11 m^2 s^-1 | — | 2.48e-12 m^2 s^-1 | SI Table Exact Reported | S25-S26 · Table S14 · Table S14 |
| 1H self-diffusion coefficient, unidirectional model, 273 K | 4.83e-11 m^2 s^-1 | — | 4.5e-12 m^2 s^-1 | SI Table Exact Reported | S25-S26 · Table S14 · Table S14 |
| 1H self-diffusion coefficient, unidirectional model, 293 K | 7.53e-11 m^2 s^-1 | — | 7.84e-12 m^2 s^-1 | SI Table Exact Reported | S25-S26 · Table S14 · Table S14 |
| 1H self-diffusion coefficient, unidirectional model, 298 K | 8.35e-11 m^2 s^-1 | — | 8.9e-12 m^2 s^-1 | SI Table Exact Reported | S25-S26 · Table S14 · Table S14 |
| 1H self-diffusion coefficient, unidirectional model, 303 K | 8.28e-11 m^2 s^-1 | — | 5.75e-12 m^2 s^-1 | SI Table Exact Reported | S25-S26 · Table S14 · Table S14 |
| 1H self-diffusion coefficient, unidirectional model, 313 K | 1.31e-10 m^2 s^-1 | — | 1.61e-11 m^2 s^-1 | SI Table Exact Reported | S25-S26 · Table S14 · Table S14 |
| 1H self-diffusion coefficient, unidirectional model, 323 K | 2.06e-10 m^2 s^-1 | — | 3.16e-11 m^2 s^-1 | SI Table Exact Reported | S25-S26 · Table S14 · Table S14 |
| 1H self-diffusion coefficient, unidirectional model, 333 K | 2.16e-10 m^2 s^-1 | — | 2.37e-11 m^2 s^-1 | SI Table Exact Reported | S25-S26 · Table S14 · Table S14 |
| 1H self-diffusion coefficient, unidirectional model, 353 K | 2.66e-10 m^2 s^-1 | — | 3.75e-11 m^2 s^-1 | SI Table Exact Reported | S25-S26 · Table S14 · Table S14 |
| 1H self-diffusion coefficient, unidirectional model, 373 K | 1.6e-10 m^2 s^-1 | — | 1.58e-11 m^2 s^-1 | SI Table Exact Reported | S25-S26 · Table S14 · Table S14 |
| 1H self-diffusion coefficient, unidirectional model, 393 K | 2.47e-10 m^2 s^-1 | — | 5.06e-11 m^2 s^-1 | SI Table Exact Reported | S25-S26 · Table S14 · Table S14 |
| Table S25 DH comparison value at 298 K and 90% RH | 8.35e-11 m^2 s^-1 | — | — | SI Table Exact Reported | S31 · Table S25 · Table S25 |
Ti-dobdc-LiCl (MOF:LiCl = 1:1) · Pellet
Powder sample loaded into NMR tube; kept at 298 K, 95% RH for one day and capped; PFG strength varied in 16 steps from 0 to 25 T m^-1; unidirectional model selected by authors.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| 1H self-diffusion coefficient, unidirectional model, 213 K | 6.71e-12 m^2 s^-1 | — | 2.12e-13 m^2 s^-1 | SI Table Exact Reported | S25-S26 · Table S13 · Table S13 |
| 1H self-diffusion coefficient, unidirectional model, 233 K | 1.11e-11 m^2 s^-1 | — | 4.82e-13 m^2 s^-1 | SI Table Exact Reported | S25-S26 · Table S13 · Table S13 |
| 1H self-diffusion coefficient, unidirectional model, 253 K | 2.46e-11 m^2 s^-1 | — | 9.92e-13 m^2 s^-1 | SI Table Exact Reported | S25-S26 · Table S13 · Table S13 |
| 1H self-diffusion coefficient, unidirectional model, 273 K | 5.28e-11 m^2 s^-1 | — | 2.01e-12 m^2 s^-1 | SI Table Exact Reported | S25-S26 · Table S13 · Table S13 |
| 1H self-diffusion coefficient, unidirectional model, 293 K | 1e-10 m^2 s^-1 | — | 4.64e-12 m^2 s^-1 | SI Table Exact Reported | S25-S26 · Table S13 · Table S13 |
| 1H self-diffusion coefficient, unidirectional model, 298 K | 1.14e-10 m^2 s^-1 | — | 5.75e-12 m^2 s^-1 | SI Table Exact Reported | S25-S26 · Table S13 · Table S13 |
| 1H self-diffusion coefficient, unidirectional model, 303 K | 1.67e-10 m^2 s^-1 | — | 1.22e-11 m^2 s^-1 | SI Table Exact Reported | S25-S26 · Table S13 · Table S13 |
| 1H self-diffusion coefficient, unidirectional model, 313 K | 2.51e-10 m^2 s^-1 | — | 2.37e-11 m^2 s^-1 | SI Table Exact Reported | S25-S26 · Table S13 · Table S13 |
| 1H self-diffusion coefficient, unidirectional model, 323 K | 3.54e-10 m^2 s^-1 | — | 4.73e-11 m^2 s^-1 | SI Table Exact Reported | S25-S26 · Table S13 · Table S13 |
| 1H self-diffusion coefficient, unidirectional model, 333 K | 3.82e-10 m^2 s^-1 | — | 4.57e-11 m^2 s^-1 | SI Table Exact Reported | S25-S26 · Table S13 · Table S13 |
| 1H self-diffusion coefficient, unidirectional model, 353 K | 3.34e-10 m^2 s^-1 | — | 2.97e-11 m^2 s^-1 | SI Table Exact Reported | S25-S26 · Table S13 · Table S13 |
| Table S25 DH comparison value at 298 K and 90% RH | 1.14e-10 m^2 s^-1 | — | — | SI Table Exact Reported | S31 · Table S25 · Table S25 |
Ti-dobdc-LiI (MOF:LiI = 1:1) · Pellet
Powder sample loaded into NMR tube; kept at 298 K, 95% RH for one day and capped; PFG strength varied in 16 steps from 0 to 25 T m^-1; unidirectional model selected by authors.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| 1H self-diffusion coefficient, unidirectional model, 213 K | 8.25e-12 m^2 s^-1 | — | 3.82e-13 m^2 s^-1 | SI Table Exact Reported | S25-S26 · Table S15 · Table S15 |
| 1H self-diffusion coefficient, unidirectional model, 233 K | 2.02e-11 m^2 s^-1 | — | 2.17e-13 m^2 s^-1 | SI Table Exact Reported | S25-S26 · Table S15 · Table S15 |
| 1H self-diffusion coefficient, unidirectional model, 253 K | 3.26e-11 m^2 s^-1 | — | 1.01e-12 m^2 s^-1 | SI Table Exact Reported | S25-S26 · Table S15 · Table S15 |
| 1H self-diffusion coefficient, unidirectional model, 273 K | 4.29e-11 m^2 s^-1 | — | 1.78e-12 m^2 s^-1 | SI Table Exact Reported | S25-S26 · Table S15 · Table S15 |
| 1H self-diffusion coefficient, unidirectional model, 293 K | 6.3e-11 m^2 s^-1 | — | 2.27e-12 m^2 s^-1 | SI Table Exact Reported | S25-S26 · Table S15 · Table S15 |
| 1H self-diffusion coefficient, unidirectional model, 298 K | 7.04e-11 m^2 s^-1 | — | 2.57e-12 m^2 s^-1 | SI Table Exact Reported | S25-S26 · Table S15 · Table S15 |
| 1H self-diffusion coefficient, unidirectional model, 303 K | 1.29e-10 m^2 s^-1 | — | 3.22e-12 m^2 s^-1 | SI Table Exact Reported | S25-S26 · Table S15 · Table S15 |
| 1H self-diffusion coefficient, unidirectional model, 313 K | 2.16e-10 m^2 s^-1 | — | 1.34e-11 m^2 s^-1 | SI Table Exact Reported | S25-S26 · Table S15 · Table S15 |
| 1H self-diffusion coefficient, unidirectional model, 323 K | 2.89e-10 m^2 s^-1 | — | 3.06e-11 m^2 s^-1 | SI Table Exact Reported | S25-S26 · Table S15 · Table S15 |
| 1H self-diffusion coefficient, unidirectional model, 333 K | 3.58e-10 m^2 s^-1 | — | 4.2e-11 m^2 s^-1 | SI Table Exact Reported | S25-S26 · Table S15 · Table S15 |
| 1H self-diffusion coefficient, unidirectional model, 353 K | 4.73e-10 m^2 s^-1 | — | 5.73e-11 m^2 s^-1 | SI Table Exact Reported | S25-S26 · Table S15 · Table S15 |
| 1H self-diffusion coefficient, unidirectional model, 373 K | 3.62e-10 m^2 s^-1 | — | 4.75e-11 m^2 s^-1 | SI Table Exact Reported | S25-S26 · Table S15 · Table S15 |
| 1H self-diffusion coefficient, unidirectional model, 393 KMarked as a best value within this paper | 5.49e-10 m^2 s^-1 | — | 7.42e-11 m^2 s^-1 | SI Table Exact Reported | S25-S26 · Table S15 · Table S15 |
| Table S25 DH comparison value at 298 K and 90% RH | 7.04e-11 m^2 s^-1 | — | — | SI Table Exact Reported | S31 · Table S25 · Table S25 |
Ti-dobdc-LiBr (MOF:LiBr = 1:1) · Pellet
Powder sample loaded into NMR tube; kept at 298 K, 95% RH for one day and capped; PFG strength varied in 16 steps from 0 to 25 T m^-1; unidirectional model selected by authors.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| 7Li self-diffusion coefficient, unidirectional model, 253 K | 1.92e-11 m^2 s^-1 | — | 1.93e-12 m^2 s^-1 | SI Table Exact Reported | S30-S31 · Table S23 · Table S23 |
| 7Li self-diffusion coefficient, unidirectional model, 273 K | 4.09e-11 m^2 s^-1 | — | 3.04e-12 m^2 s^-1 | SI Table Exact Reported | S30-S31 · Table S23 · Table S23 |
| 7Li self-diffusion coefficient, unidirectional model, 293 K | 7.04e-11 m^2 s^-1 | — | 3.8e-12 m^2 s^-1 | SI Table Exact Reported | S30-S31 · Table S23 · Table S23 |
| 7Li self-diffusion coefficient, unidirectional model, 298 K | 8.42e-11 m^2 s^-1 | — | 4.16e-12 m^2 s^-1 | SI Table Exact Reported | S30-S31 · Table S23 · Table S23 |
| 7Li self-diffusion coefficient, unidirectional model, 303 K | 9.21e-11 m^2 s^-1 | — | 3.59e-12 m^2 s^-1 | SI Table Exact Reported | S30-S31 · Table S23 · Table S23 |
| 7Li self-diffusion coefficient, unidirectional model, 313 K | 1.15e-10 m^2 s^-1 | — | 4.89e-12 m^2 s^-1 | SI Table Exact Reported | S30-S31 · Table S23 · Table S23 |
| 7Li self-diffusion coefficient, unidirectional model, 323 K | 1.34e-10 m^2 s^-1 | — | 4.71e-12 m^2 s^-1 | SI Table Exact Reported | S30-S31 · Table S23 · Table S23 |
| 7Li self-diffusion coefficient, unidirectional model, 333 K | 1.51e-10 m^2 s^-1 | — | 8.26e-12 m^2 s^-1 | SI Table Exact Reported | S30-S31 · Table S23 · Table S23 |
| 7Li self-diffusion coefficient, unidirectional model, 353 K | 1.62e-10 m^2 s^-1 | — | 8.6e-12 m^2 s^-1 | SI Table Exact Reported | S30-S31 · Table S23 · Table S23 |
| 7Li self-diffusion coefficient, unidirectional model, 373 K | 1.55e-10 m^2 s^-1 | — | 7.78e-12 m^2 s^-1 | SI Table Exact Reported | S30-S31 · Table S23 · Table S23 |
| 7Li self-diffusion coefficient, unidirectional model, 393 K | 1.45e-10 m^2 s^-1 | — | 7.09e-12 m^2 s^-1 | SI Table Exact Reported | S30-S31 · Table S23 · Table S23 |
| Table S25 DLi comparison value at 298 K and 90% RH | 8.42e-11 m^2 s^-1 | — | — | SI Table Exact Reported | S31 · Table S25 · Table S25 |
Ti-dobdc-LiCl (MOF:LiCl = 1:1) · Pellet
Powder sample loaded into NMR tube; kept at 298 K, 95% RH for one day and capped; PFG strength varied in 16 steps from 0 to 25 T m^-1; unidirectional model selected by authors.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| 7Li self-diffusion coefficient, unidirectional model, 253 K | 1.21e-11 m^2 s^-1 | — | 3.59e-12 m^2 s^-1 | SI Table Exact Reported | S30-S31 · Table S22 · Table S22 |
| 7Li self-diffusion coefficient, unidirectional model, 273 K | 2.12e-11 m^2 s^-1 | — | 3.24e-12 m^2 s^-1 | SI Table Exact Reported | S30-S31 · Table S22 · Table S22 |
| 7Li self-diffusion coefficient, unidirectional model, 293 K | 1.97e-11 m^2 s^-1 | — | 2.58e-12 m^2 s^-1 | SI Table Exact Reported | S30-S31 · Table S22 · Table S22 |
| 7Li self-diffusion coefficient, unidirectional model, 298 K | 2.1e-11 m^2 s^-1 | — | 2.97e-12 m^2 s^-1 | SI Table Exact Reported | S30-S31 · Table S22 · Table S22 |
| 7Li self-diffusion coefficient, unidirectional model, 303 K | 2.06e-11 m^2 s^-1 | — | 2.11e-12 m^2 s^-1 | SI Table Exact Reported | S30-S31 · Table S22 · Table S22 |
| 7Li self-diffusion coefficient, unidirectional model, 313 K | 1.95e-11 m^2 s^-1 | — | 2.39e-12 m^2 s^-1 | SI Table Exact Reported | S30-S31 · Table S22 · Table S22 |
| 7Li self-diffusion coefficient, unidirectional model, 323 K | 2.17e-11 m^2 s^-1 | — | 1.9e-12 m^2 s^-1 | SI Table Exact Reported | S30-S31 · Table S22 · Table S22 |
| 7Li self-diffusion coefficient, unidirectional model, 333 K | 2.45e-11 m^2 s^-1 | — | 1.98e-12 m^2 s^-1 | SI Table Exact Reported | S30-S31 · Table S22 · Table S22 |
| 7Li self-diffusion coefficient, unidirectional model, 353 K | 3.31e-11 m^2 s^-1 | — | 2.48e-12 m^2 s^-1 | SI Table Exact Reported | S30-S31 · Table S22 · Table S22 |
| 7Li self-diffusion coefficient, unidirectional model, 373 K | 5.37e-11 m^2 s^-1 | — | 5.23e-12 m^2 s^-1 | SI Table Exact Reported | S30-S31 · Table S22 · Table S22 |
| 7Li self-diffusion coefficient, unidirectional model, 393 K | 7.36e-11 m^2 s^-1 | — | 6.95e-12 m^2 s^-1 | SI Table Exact Reported | S30-S31 · Table S22 · Table S22 |
| Table S25 DLi comparison value at 298 K and 90% RH | 2.1e-11 m^2 s^-1 | — | — | SI Table Exact Reported | S31 · Table S25 · Table S25 |
Ti-dobdc-LiI (MOF:LiI = 1:1) · Pellet
Powder sample loaded into NMR tube; kept at 298 K, 95% RH for one day and capped; PFG strength varied in 16 steps from 0 to 25 T m^-1; unidirectional model selected by authors.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| 7Li self-diffusion coefficient, unidirectional model, 253 K | 5.08e-11 m^2 s^-1 | — | 1.21e-11 m^2 s^-1 | SI Table Exact Reported | S30-S31 · Table S24 · Table S24 |
| 7Li self-diffusion coefficient, unidirectional model, 273 K | 8.13e-11 m^2 s^-1 | — | 1.15e-11 m^2 s^-1 | SI Table Exact Reported | S30-S31 · Table S24 · Table S24 |
| 7Li self-diffusion coefficient, unidirectional model, 293 K | 1.72e-10 m^2 s^-1 | — | 9.09e-11 m^2 s^-1 | SI Table Exact Reported | S30-S31 · Table S24 · Table S24 |
| 7Li self-diffusion coefficient, unidirectional model, 298 K | 1.19e-10 m^2 s^-1 | — | 9.45e-12 m^2 s^-1 | SI Table Exact Reported | S30-S31 · Table S24 · Table S24 |
| 7Li self-diffusion coefficient, unidirectional model, 303 K | 1.65e-10 m^2 s^-1 | — | 1.31e-11 m^2 s^-1 | SI Table Exact Reported | S30-S31 · Table S24 · Table S24 |
| 7Li self-diffusion coefficient, unidirectional model, 313 K | 1.58e-10 m^2 s^-1 | — | 1.5e-11 m^2 s^-1 | SI Table Exact Reported | S30-S31 · Table S24 · Table S24 |
| 7Li self-diffusion coefficient, unidirectional model, 323 K | 1.77e-10 m^2 s^-1 | — | 1.23e-11 m^2 s^-1 | SI Table Exact Reported | S30-S31 · Table S24 · Table S24 |
| 7Li self-diffusion coefficient, unidirectional model, 333 K | 1.86e-10 m^2 s^-1 | — | 1.08e-11 m^2 s^-1 | SI Table Exact Reported | S30-S31 · Table S24 · Table S24 |
| 7Li self-diffusion coefficient, unidirectional model, 353 KMarked as a best value within this paper | 2.5e-10 m^2 s^-1 | — | 1.69e-11 m^2 s^-1 | SI Table Exact Reported | S30-S31 · Table S24 · Table S24 |
| 7Li self-diffusion coefficient, unidirectional model, 373 K | 2.4e-10 m^2 s^-1 | — | 1.97e-11 m^2 s^-1 | SI Table Exact Reported | S30-S31 · Table S24 · Table S24 |
| 7Li self-diffusion coefficient, unidirectional model, 393 K | 2.49e-10 m^2 s^-1 | — | 3.71e-11 m^2 s^-1 | SI Table Exact Reported | S30-S31 · Table S24 · Table S24 |
| Table S25 DLi comparison value at 298 K and 90% RH | 1.19e-10 m^2 s^-1 | — | — | SI Table Exact Reported | S31 · Table S25 · Table S25 |
Ti-dobdc-LiBr (MOF:LiBr = 1:1) · Pellet
Approximate comparison assuming anion self-diffusion nearly zero; Figure S17 plots 1H and 7Li transference numbers vs temperature.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| 1H transference number near 298 K | about 0.50 | — | — | Visual Estimate Approximate | S20 · Figure S17 · Figure S17 |
| 7Li transference number near 298 K | about 0.50 | — | — | Visual Estimate Approximate | S20 · Figure S17 · Figure S17 |
Ti-dobdc-LiCl (MOF:LiCl = 1:1) · Pellet
Approximate comparison assuming anion self-diffusion nearly zero; Figure S17 plots 1H and 7Li transference numbers vs temperature.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| 1H transference number near 298 K | about 0.84 | — | — | Visual Estimate Approximate | S20 · Figure S17 · Figure S17 |
| 7Li transference number near 298 K | about 0.16 | — | — | Visual Estimate Approximate | S20 · Figure S17 · Figure S17 |
Ti-dobdc-LiI (MOF:LiI = 1:1) · Pellet
Approximate comparison assuming anion self-diffusion nearly zero; Figure S17 plots 1H and 7Li transference numbers vs temperature.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| 1H transference number near 298 K | about 0.27 | — | — | Visual Estimate Approximate | S20 · Figure S17 · Figure S17 |
| 7Li transference number near 298 K | about 0.73 | — | — | Visual Estimate Approximate | S20 · Figure S17 · Figure S17 |