ATR FT-IR spectroscopy
Ti-dobdc pristine · Pellet
Samples degassed and heated at 353 K for 24 h before ATR-IR measurement in an argon-filled glovebox.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|
Spectroscopy — Cooperative Proton and Li-ion Conduction in a 2D-Layered MOF via Mechanical Insertion of Lithium Halides
Measurement evidence
Spectroscopy
Cooperative Proton and Li-ion Conduction in a 2D-Layered MOF via Mechanical Insertion of Lithium Halides · Sarango-Ramirez M.K., Donoshita M., Yoshida Y. et al. · Angewandte Chemie - International Edition · 2023 · e202301284
8 measurement groups · 14 results
Reported values remain attached to the sample, method, conditions, extraction quality and source location that produced them.
ATR FT-IR spectroscopy
Ti-dobdc-LiBr (MOF:LiBr = 1:1) · Pellet
Samples degassed and heated at 353 K for 24 h before ATR-IR measurement in an argon-filled glovebox.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| C=O stretching band after LiX insertion | 1643 cm^-1 | — | — | Text Rounded Reported | 2 · Results · Figure S4 |
| OH stretching band shift | 3200 cm^-1 band shifted to lower frequency | — | — | Text Qualitative | 2 · Results · Figure S4 |
ATR FT-IR spectroscopy
Ti-dobdc-LiCl (MOF:LiCl = 1:1) · Pellet
Samples degassed and heated at 353 K for 24 h before ATR-IR measurement in an argon-filled glovebox.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| C=O stretching band after LiX insertion | 1643 cm^-1 | — | — | Text Rounded Reported | 2 · Results · Figure S4 |
| OH stretching band shift | 3200 cm^-1 band shifted to lower frequency | — | — | Text Qualitative | 2 · Results · Figure S4 |
ATR FT-IR spectroscopy
Ti-dobdc-LiI (MOF:LiI = 1:1) · Pellet
Samples degassed and heated at 353 K for 24 h before ATR-IR measurement in an argon-filled glovebox.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| C=O stretching band after LiX insertion | 1643 cm^-1 | — | — | Text Rounded Reported | 2 · Results · Figure S4 |
| OH stretching band shift | 3200 cm^-1 band shifted to lower frequency | — | — | Text Qualitative | 2 · Results · Figure S4 |
O 1s XPS
Ti-dobdc pristine · Pellet
O 1s XPS spectra for Ti-dobdc and Ti-dobdc-LiX samples.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| coordinated/dangling oxygen peak high BE | 533.61 eV | — | — | Visual Estimate Approximate | S7 · Figure S5 · Figure S5 |
| coordinated/dangling oxygen peak low BE | 531.84 eV | — | — | Visual Estimate Approximate | S7 · Figure S5 · Figure S5 |
O 1s XPS
Ti-dobdc-LiBr (MOF:LiBr = 1:1) · Pellet
O 1s XPS spectra for Ti-dobdc and Ti-dobdc-LiX samples.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| coordinated/dangling oxygen peak high BE | 533.6 eV | — | — | Visual Estimate Approximate | S7 · Figure S5 · Figure S5 |
| coordinated/dangling oxygen peak low BE | 531.77 eV | — | — | Visual Estimate Approximate | S7 · Figure S5 · Figure S5 |
O 1s XPS
Ti-dobdc-LiCl (MOF:LiCl = 1:1) · Pellet
O 1s XPS spectra for Ti-dobdc and Ti-dobdc-LiX samples.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| coordinated/dangling oxygen peak high BE | 533.54 eV | — | — | Visual Estimate Approximate | S7 · Figure S5 · Figure S5 |
| coordinated/dangling oxygen peak low BE | 531.71 eV | — | — | Visual Estimate Approximate | S7 · Figure S5 · Figure S5 |
O 1s XPS
Ti-dobdc-LiI (MOF:LiI = 1:1) · Pellet
O 1s XPS spectra for Ti-dobdc and Ti-dobdc-LiX samples.
| Property | Reported value | Normalised value | Uncertainty | Origin and quality | Source |
|---|---|---|---|---|---|
| coordinated/dangling oxygen peak high BE | 533.58 eV | — | — | Visual Estimate Approximate | S7 · Figure S5 · Figure S5 |
| coordinated/dangling oxygen peak low BE | 531.72 eV | — | — | Visual Estimate Approximate | S7 · Figure S5 · Figure S5 |