Cao L.-A., Wei M., Guo X. et al. · Ionics · 2024 · 2375-2385
Open a family to keep every result attached to its sample, method and conditions.
Paraphrased for this database from the authors’ stated interpretations — never quoted verbatim — and kept separate from reported measurements.
The island-like down-side surface film improves glucose sensing versus the flat up-side film.
Caveat: Sensor performance is for alkaline NaOH electrolyte and Ni3(HITP)2/ITO electrodes, not direct physiological media; SI 1 and 5 min calibration slopes are visual reads from rendered plots.
p006-p007 / 2380-2381 · Results and discussion · Fig. 4; Table 1 · Linked to 10 structured results
Although the paper describes Ni3(HITP)2 as conductive, it reports no first-hand electrical conductivity or charge-transport value for the films.
Caveat: Conductivity is discussed as background and motivation only.
p001 / 2375 · Abstract and Introduction
Long-term response retention decreases to 70.7% after 267 days, and the authors state further optimisation or device packaging is needed.
p007 / 2381 · Results and discussion · Fig. 5d · Linked to 3 structured results
The prepared film is assigned as pure Ni3(HITP)2 based on XRD, HR-TEM lattice fringes, and FT-IR comparison with powder.
Caveat: No CIF or full Rietveld refinement was provided in the assigned documents.
p004-p005 / 2378-2379 · Results and discussion · Fig. 3 · Linked to 5 structured results
Gas-liquid interface synthesis produces asymmetric Ni3(HITP)2 films with a flat up-side surface and rough island-like down-side surface.
Caveat: The 1 and 5 min side-specific morphologies are partly supported by SI rendered figures; some SI image values are visual reads from labels.
p004 / 2378 · Results and discussion · Fig. 2; Fig. S1-S4 · Linked to 7 structured results
Higher defective Ni content in DS-Ni-HITP is linked to stronger glucose adsorption and enhanced catalytic oxidation capacity.
Caveat: DFT adsorption energies support the mechanistic interpretation but do not by themselves prove the full glucose oxidation pathway.
p008 / 2382 · Results and discussion; Conclusions · Fig. 6 · Linked to 7 structured results
Names and aliases are kept exactly within the paper’s own identity model.
| Material | Composition | Structure context | Source |
|---|---|---|---|
| HITP ligand | HITP or HITP.6HCl2,3,6,7,10,11-hexaiminotriphenylene | 0D · UnknownOrganic linker precursor for Ni3(HITP)2 film synthesis. | p002 / 2376 · Preparation of HITP ligand |
| ITO substrate | ITO | unknown · UnknownCommercial indium tin oxide substrate used as bare control and support. | p003 / 2377 · Preparation of Ni3(HITP)2 film/ITO electrode |
| Ni3(HITP)2Browse family: Ni₃(HITP)₂ / Ni–HITP | Ni3(HITP)2Ni · HITP (2,3,6,7,10,11-hexaiminotriphenylene) | 2D · Pristine2D graphene-like honeycomb/kagome conductive MOF; XRD peaks assigned to (100), (200), and (002) planes. | p001 / 2375 · Abstract and Introduction |
| Ni3(HITP)2 slab modelBrowse family: Ni₃(HITP)₂ / Ni–HITP | Ni3(HITP)2Ni · HITP | 2D · Model SystemPeriodic slab model with saturated Ni, unsaturated defective Ni, and carbon adsorption sites. | p003 / 2377 · Computational methods |
Sample form, processing state and composition status define the context for measurements.
| Sample | Form and role | Processing and geometry | Source |
|---|---|---|---|
| bare ITOresearch_0743__mat__ito_control | Electrode · Pristine Control · Unknown | Commercial ITO substrate rinsed with acetone, isopropanol, and ethanol and dried under air.ITO | p003 / 2377 · Preparation of Ni3(HITP)2 film/ITO electrode |
| DS-Ni-HITP-1 min/ITO electroderesearch_0743__mat__ni3_hitp2 | Electrode · Target Sample · Composite | 1 min film transferred to ITO by stamping to expose the down-side surface.ITO · ~10 nm Ni3(HITP)2 film | p004 · Supporting Information · Fig. S6b,c |
| DS-Ni-HITP-3 minresearch_0743__mat__ni3_hitp2 | Thin Film · Target Sample · Pristine Framework | Down-side surface immersed in solution; obtained by stamping transfer.~20 nm film; side-specific surface roughness Ra = 52.2 nm | p003-p004 / 2377-2378 · Results and discussion · Fig. 2b,d |
| DS-Ni-HITP-3 min/ITO electroderesearch_0743__mat__ni3_hitp2 | Electrode · Target Sample · Composite | Ni3(HITP)2 film transferred to ITO by stamping to expose down-side surface.ITO · ~20 nm Ni3(HITP)2 film | p003 / 2377 · Preparation of Ni3(HITP)2 film/ITO electrode |
| DS-Ni-HITP-5 min/ITO electroderesearch_0743__mat__ni3_hitp2 | Electrode · Target Sample · Composite | 5 min film transferred to ITO by stamping to expose the down-side surface.ITO · ~100 nm Ni3(HITP)2 film | p004 · Supporting Information · Fig. S6e,f |
| HITP ligand productresearch_0743__mat__hitp_ligand | Powder · Paper Level Unspecified · Unknown | Product obtained by acid deprotection, centrifuging, washing, and drying. | p002 / 2376 · Preparation of HITP ligand |
| Ni3(HITP)2 glucose adsorption modelresearch_0743__mat__ni3_hitp2_model | Model · Model System · Model | Periodic slab model with glucose adsorbed at saturated Ni, unsaturated Ni, and carbon sites. | p003 and p008 / 2377 and 2382 · Computational methods; Results and discussion · Fig. 6c-e |
| Ni3(HITP)2 film-1 minresearch_0743__mat__ni3_hitp2 | Thin Film · Target Sample · Pristine Framework | Air-liquid interfacial growth for 1 min.~10 nm | p003 / 2377 · Results and discussion · Fig. S1-S2 |
| Ni3(HITP)2 film-3 minresearch_0743__mat__ni3_hitp2 | Thin Film · Target Sample · Pristine Framework | Air-liquid interfacial growth for 3 min.~20 nm | p003 / 2377 · Results and discussion · Fig. S2 |
| Ni3(HITP)2 film-5 minresearch_0743__mat__ni3_hitp2 | Thin Film · Target Sample · Pristine Framework | Air-liquid interfacial growth for 5 min.~100 nm | p003 / 2377 · Results and discussion · Fig. S1-S2 |
| Ni3(HITP)2 thin filmresearch_0743__mat__ni3_hitp2 | Thin Film · Target Sample · Pristine Framework | Gas-liquid interface self-assembled nanofilm.free-standing at air-liquid interface; transferred to substrates for use · controlled by reaction time, 1-5 min | p002-p003 / 2376-2377 · Preparation of Ni3(HITP)2 film · Fig. 1 |
| Ni3(HITP)2 powder referenceresearch_0743__mat__ni3_hitp2 | Powder · Pristine Control · Pristine Framework | Powder reference compared with the film by FT-IR. | p004-p005 / 2378-2379 · Results and discussion · Fig. 3d |
| US-Ni-HITP-1 min/ITO electroderesearch_0743__mat__ni3_hitp2 | Electrode · Target Sample · Composite | 1 min film transferred to ITO by salvaging to expose the up-side surface.ITO · ~10 nm Ni3(HITP)2 film | p004 · Supporting Information · Fig. S6a,c |
| US-Ni-HITP-3 minresearch_0743__mat__ni3_hitp2 | Thin Film · Target Sample · Pristine Framework | Up-side surface exposed to air; obtained by salvaging transfer.~20 nm film; side-specific surface roughness Ra = 5.01 nm | p003-p004 / 2377-2378 · Results and discussion · Fig. 2a,c |
| US-Ni-HITP-3 min/ITO electroderesearch_0743__mat__ni3_hitp2 | Electrode · Target Sample · Composite | Ni3(HITP)2 film transferred to ITO by salvaging to expose up-side surface.ITO · ~20 nm Ni3(HITP)2 film | p003 / 2377 · Preparation of Ni3(HITP)2 film/ITO electrode |
| US-Ni-HITP-5 min/ITO electroderesearch_0743__mat__ni3_hitp2 | Electrode · Target Sample · Composite | 5 min film transferred to ITO by salvaging to expose the up-side surface.ITO · ~100 nm Ni3(HITP)2 film | p004 · Supporting Information · Fig. S6d,f |